| 光谱学与光谱分析 |
|
|
|
|
|
| Speciation of Iron Using Capillary Electrophoresis Inductively Coupled Plasma Atomic Emission Spectrometry |
| DENG Bi-yang1, ZENG Chu-jie1, CHAN Wing-Tat2 |
1. College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, China
2. Department of Chemistry, the University of Hong Kong, Hong Kong, China |
|
|
|
|
Abstract The separation of iron species, e.g. Fe2+-Fe3+, Fe2+-Fe(phen)2+3, and Fe2+-Fe3+, by mixing with complexing reagents of o-phenanthroline and EDTA, and Fe2+-Fe3+ with o-phenanthroline was developed by capillary electrophoresis inductively coupled plasma atomic emission spectrometry(CE-ICP-AES). The effects of electrophoresis conditions such as voltage, buffer solution pH, and complex concentration on iron species are discussed. Satisfactory separation conditions for iron speciation have been acquired. Cations and anions, containing complexing agents, do not interfere in the separation of iron species. The method has advantage to CE-UV.
|
|
Received: 2004-09-23
Accepted: 2005-03-18
|
|
|
|
Corresponding Authors:
DENG Bi-yang
|
|
| Cite this article: |
|
DENG Bi-yang,ZENG Chu-jie,CHAN Wing-Tat. Speciation of Iron Using Capillary Electrophoresis Inductively Coupled Plasma Atomic Emission Spectrometry [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(11): 1868-1871.
|
|
|
|
| URL: |
|
https://www.gpxygpfx.com/EN/Y2005/V25/I11/1868 |
[1] Yamauchi H. Fowler B A. In Arsenic, In The Environment, Part Ⅱ, New York: Wiley, 1994. 35.
[2] Olesick J W, Kinzer J A, Olesick S V. Anal. Chem., 1995, 67：1.
[3] YE Mei-ying, YIN Xue-feng, FANG Zhao-lun(叶美英, 殷学锋, 方肇伦). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003，23(1)：89.
[4] YAN Xiu-ping, NI Zhe-ming(严秀平, 倪哲明). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003，23(5)：945.
[5] KANG Jian-zhen, DUAN Tai-cheng，LIU Jie，et al(康建珍, 段太成, 刘 杰, 等). Chinese J. Anal. Chem.(分析化学)，2003，31(11)：1385.
[6] LI Yu, DONG De-ming, YANG Fan, et al(李 鱼, 董德明, 杨 帆, 等). Journal of Jilin University(吉林大学学报), 2003, 41(3)：374.
[7] LIU Er-bao, WEI Hong-qing, CHENG Jie-ke(刘二保, 卫洪请, 程介克). Chinese Journal of Analytical Science(分析科学学报)，2002, 18(4): 344.
[8] Deng B Y，Chan W T. J. Chromatogr. A, 2000, 891: 139.
[9] Sillen L G. Martell A E. Stability Constants of Metal-Ion Complexes. London: Chemical Society, 1964. 665; 636.
[10] Christian G D. Analytical Chemistry (Fourth Edition). New York: John Wiley & Sons, 1994. 646.
[11] Xu J, Che P, Ma Y. J. Chromatogr. A, 1996, 749: 287.
[12] Arce L, Ríos A, Valcárcel M J. Chromatogr. A, 1997, 791: 279. |
| [1] |
LIU Jia1, 2, GUO Fei-fei2, YU Lei2, CUI Fei-peng2, ZHAO Ying2, HAN Bing2, SHEN Xue-jing1, 2, WANG Hai-zhou1, 2*. Quantitative Characterization of Components in Neodymium Iron Boron Permanent Magnets by Laser Induced Breakdown Spectroscopy （LIBS）[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 141-147. |
| [2] |
LIU Shu-hong1, 2, WANG Lu-si3*, WANG Li-sheng3, KANG Zhi-juan1, 2，WANG Lei1, 2，XU Lin1, 2，LIU Ai-qin1, 2. A Spectroscopic Study of Secondary Minerals on the Epidermis of Hetian Jade Pebbles From Xinjiang, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 169-175. |
| [3] |
LIU Shu1, JIN Yue1, 2, SU Piao1, 2, MIN Hong1, AN Ya-rui2, WU Xiao-hong1*. Determination of Calcium, Magnesium, Aluminium and Silicon Content in Iron Ore Using Laser-Induced Breakdown Spectroscopy Assisted by Variable Importance-Back Propagation Artificial Neural Networks[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3132-3142. |
| [4] |
LIU Liang-yu, YIN Zuo-wei*, XU Feng-shun. Spectral Characteristics and Genesis Analysis of Gem-Grade Analcime From Daye, Hubei[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2799-2804. |
| [5] |
CHENG Xiao-xiang1, WU Na2, LIU Wei2*, WANG Ke-qing2, LI Chen-yuan1, CHEN Kun-long1, LI Yan-xiang1*. Research on Quantitative Model of Corrosion Products of Iron Artefacts Based on Raman Spectroscopic Imaging[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2166-2173. |
| [6] |
WANG Ke-qing1, 2*, WU Na1, 2, CHENG Xiao-xiang3, ZHANG Ran1, 2, LIU Wei1, 2*. Use of FTIR for the Quantitative Study of Corrosion Products of Iron
Cultural Relics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1846-1853. |
| [7] |
ZHOU Wu-bang1, QIN Dong-mei2, WANG Hao-tian1, CHEN Tao1, WANG Chao-wen1*. The Gemological, Mineralogical, and Spectral Characteristics of Indian Longdan Stone[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1895-1899. |
| [8] |
GUO Feng1, ZHAO Dong-e1*, YANG Xue-feng1, CHU Wen-bo2, ZHANG Bin1, ZHANG Da-shun3MENG Fan-jun3. Research on Hyperspectral Image Recognition of Iron Fragments[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 997-1003. |
| [9] |
CAO Yue1, BAO Ni-sha1, 2*, ZHOU Bin3, GU Xiao-wei1, 2, LIU Shan-jun1, YU Mo-li1. Research on Remote Sensing Inversion Method of Surface Moisture Content of Iron Tailings Based on Measured Spectra and Domestic Gaofen-5 Hyperspectral High-Resolution Satellites[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1225-1233. |
| [10] |
WANG Wen-xuan1, WEN Rui1*, ZHANG Yue2, JIANG Jian-xin3. The Microstructure of “Iron Spot” on Blue-and-White Porcelain From Jingdezhen Imperial Kiln in Yongle and Xuande Period of Ming Dynasty[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 190-197. |
| [11] |
ZHANG Jian1, LIU Ya-jian2, CAO Ji-hu3. Raman Spectral Characteristics of Pyrite in Luyuangou Gold Deposit, Western Henan Province and Its Indicative Significance for Multiphase Metallogenesis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3770-3774. |
| [12] |
LIU Pan1, 2, DU Mi-fang1, LI Zhi-ya1, GAO Ling-qing1, 3, HAN Hua-yun4, ZHANG Xin-yao1, 3. Determination of Trace Tellurium Content in Steel by Hydride Generation Atomic Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3103-3108. |
| [13] |
GUO Xiao-hua1, ZHAO Peng1, WU Ya-qing1, TANG Xue-ping3, GENG Di2*, WENG Lian-jin2*. Application of XRF and ICP-MS in Elements Content Determinations of Tieguanyin of Anxi and Hua’an County, Fujian Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3124-3129. |
| [14] |
WANG Yang-ping1, 2, HAN Shu-mei1*, YANG Jing-yu1, 2, DANG Jian-wu1, 2, ZHANG Zhan-ping1. Improved YOLOv4 Remote Sensing Image Detection Method of Ground Objects Along Railway[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3275-3282. |
| [15] |
ZHANG Li-qian1, 2, LIU Yang-jie2, 3. Comparative Study on Mineralogical Identification and Spectral
Characteristics of Four Iron-Containing Mineral Medicines[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2884-2889. |
|
|
|
|
