|
|
|
|
|
|
Study on Pollution Source Identification of Composite Polluted River Based on Aqueous Fluorescence Fingerprint Technology |
XIONG Qiu-ran1, 2, SHEN Jian1, 2, HU Yuan2, 3, CHAI Yi-di1, 2, 3, GU Yi-qin2, 3, LENG Xiao-ting2, 3, CHENG Cheng1, 2, WU Jing1, 2* |
1. Research Center of Environmental Technology in Water Pollution Source Identification and Precise Supervision, School of Environment, Tsinghua University, Beijing 100084, China
2. Research and Development Center of Advanced Environmental Supervision Technology and Instrument, Research Institute for Environmental Innovation (Suzhou) Tsinghua, Suzhou 215163, China
3. Suzhou G-Seeker Technology Co., Ltd., Suzhou 215011, China
|
|
|
Abstract The analysis of pollution source composition of composite polluted water bodies is currently a challenge in water pollution source identification. The aqueous fluorescence fingerprint technology based on the fluorescence excitation-emission matrix is the key method to solve this problem. This study applied aqueous fluorescence fingerprint technology to perform the pollution source identification analysis of Y River in southern Jiangsu region. The fluorescence signal of textile printing and dyeing wastewater in the Y River derived from allochthonous upstream inputs, which was effectively identified by parallel factor analysis and aqueous fluorescence fingerprint comparison.Heavily contaminated regions were divided by ammonia nitrogen concentration. 109 outlets in the Y River Basin were screened by aqueous fluorescence fingerprint. 35 main responsible units were accurately located through the pollution path tracking method. After implementing the rectification requirements, the water quality of Y River was rapidly improved from below Class Ⅴ to Class Ⅲ and steadily met the standards. The Y River regulation project was cancelled, significantly reducing costs and improving efficiency. In this work, a new model of precise pollution source identification and minimally invasive control was proposed for composite polluted rivers based on aqueous fluorescence fingerprint technology, which is of great significance for realizing pollution control in a precise, science-based, and lawful way.
|
Received: 2023-06-08
Accepted: 2023-09-17
|
|
Corresponding Authors:
WU Jing
E-mail: wu_jing@mail.tsinghua.edu.cn
|
|
[1] Shen J, Song Y M, Cheng C, et al. Water Research, 2023, 229: 119408.
[2] Khan M F S, Akbar M, Wu J, et al. Methods and Applications in Fluorescence, 2022, 10(1): 012001.
[3] Shen J, Liu B, Wu J, et al. Chemosphere, 2020, 239: 124703.
[4] Shen J, Deng S B, Wu J. Journal of Chemical Education,2022, 99(2): 932.
[5] Murphy K R, Stedmon C A, Graeber D, et al. Analytical Methods,2013, 5(23): 6557.
[6] Bieroza M, Baker A, Bridgeman J. Education for Chemical Engineers, 2012, 7(1): e22.
[7] WANG Ying-jun, SHEN Jian, WANG Wen-xia, et al(王英俊,沈 鉴,王文霞,等). Environmental Monitoring and Forewarning(环境监控与预警), 2023, 15(2): 1.
[8] XU Jin-gou, WANG Zun-ben(许金钩,王尊本). Fluorescence Analysis Method(荧光分析法). Bejing: Science Press(北京:科学出版社), 2006.
[9] National Environmental Protection Standard of the People's Republic of China(中华人民共和国国家环境保护标准). HJ 535-2009. Water Quality—Determination of Ammonia Nitrogen—Nessler's Reagent Spectrophotometry(水质 氨氮的测定纳氏试剂分光光度法). Issued by Ministry of Environmental Protection of the People's Republic of China(中华人民共和国环境保护部发布), 2009.
[10] Ohno T. Environmental Science & Technology,2002, 36(4): 742.
[11] Murphy K R, Stedmon C A, Wenig P, et al. Analytical Methods,2014, 6(3): 658.
[12] Lorenzo-Seva U, ten Berge J M F. Methodology-European Journal of Research Methods for the Behavioral and Social Sciences, 2006, 2(2): 57.
[13] Shen J, Liu B, Chai Y D, et al. Environmental Research,2021, 194: 110713.
[14] A Feature Extraction and Matching Method for Two-Dimensional Single-Mapped Surface Data(一种二维单射曲面数据的特征提取与匹配方法). Chinese Patent(中国专利):ZL 201010500552.0, 2012.
[15] A Water Pollution Discharge Source Database and Its Establishment Method(一种水污染排放源数据库及其建立方法). Chinese Patent(中国专利):ZL 201910197655.5, 2021.
[16] Carstea E M, Bridgeman J, Baker A, et al. Water Research,2016, 95: 205.
[17] LIU Chuan-yang, CHAI Yi-di, XU Xian-gen, et al(刘传旸,柴一荻,徐宪根,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2021, 41(7): 2142.
[18] Shen J, Liu C Y, Lv Q, et al. Water Research,2021, 193: 116873.
[19] Mukaka M M. Malawi Medical Journal, 2012, 24(3): 69.
[20] Cheng C, Wu J, You L D, et al. Chemical Engineering Journal,2018, 335: 13.
|
[1] |
WU Zhuo-hui1, 3, HUANG Bing-jia1, 3, LI Xue-qin1, 3, WANG Xiao-ping1, 2, 3*. A Self-Adapting Method for Removing Scatterings in the
Excitation-Emission Matrix Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(04): 969-976. |
[2] |
CHENG Peng-fei1,ZHU Yan-ping2*,PAN Jin-yan1,CUI Chuan-jin2,ZHANG Yi2. Classification of Oil Pollutants by Three-Dimensional Fluorescence
Spectroscopy Combined With IGOA-SVM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(04): 1031-1038. |
[3] |
ZHANG Jing, WANG Hong-hui, JIN Liang, LIAO Ying-min, LI Heng. Effects of 9-Hydroxyphenanthrene on α-Glucosidase Activity and Their Binding Interactions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(02): 398-405. |
[4] |
WANG Hai-zhen1, 2, 3, GUO Jian-fen1, 2, 3*, ZHANG Lei1, 2, 3, LIN Hao1, 2, 3, LIN Jing-wen1, XIONG De-cheng1, 2, 3, CHEN Shi-dong1, 2, 3, YANG Yu-sheng1, 2, 3. Composition and Spectral Characteristics of Soil Dissolved Organic Matter Leachate From Different Planted Tree Species[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(02): 490-496. |
[5] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
[6] |
GU Yi-lu1, 2,PEI Jing-cheng1, 2*,ZHANG Yu-hui1, 2,YIN Xi-yan1, 2,YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
[7] |
SONG Yi-ming1, 2, SHEN Jian1, 2, LIU Chuan-yang1, 2, XIONG Qiu-ran1, 2, CHENG Cheng1, 2, CHAI Yi-di2, WANG Shi-feng2,WU Jing1, 2*. Fluorescence Quantum Yield and Fluorescence Lifetime of Indole, 3-Methylindole and L-Tryptophan[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3758-3762. |
[8] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
[9] |
XUE Fang-jia, YU Jie*, YIN Hang, XIA Qi-yu, SHI Jie-gen, HOU Di-bo, HUANG Ping-jie, ZHANG Guang-xin. A Time Series Double Threshold Method for Pollution Events Detection in Drinking Water Using Three-Dimensional Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3081-3088. |
[10] |
JIA Yu-ge1, YANG Ming-xing1, 2*, YOU Bo-ya1, YU Ke-ye1. Gemological and Spectroscopic Identification Characteristics of Frozen Jelly-Filled Turquoise and Its Raw Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2974-2982. |
[11] |
YANG Xin1, 2, XIA Min1, 2, YE Yin1, 2*, WANG Jing1, 2. Spatiotemporal Distribution Characteristics of Dissolved Organic Matter Spectrum in the Agricultural Watershed of Dianbu River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2983-2988. |
[12] |
ZHU Yan-ping1, CUI Chuan-jin1*, CHENG Peng-fei1, 2, PAN Jin-yan1, SU Hao1, 2, ZHANG Yi1. Measurement of Oil Pollutants by Three-Dimensional Fluorescence
Spectroscopy Combined With BP Neural Network and SWATLD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2467-2475. |
[13] |
QIU Cun-pu1, 2, TANG Xiao-xue2, WEN Xi-xian4, MA Xin-ling2, 3, XIA Ming-ming2, 3, LI Zhong-pei2, 3, WU Meng2, 3, LI Gui-long2, 3, LIU Kai2, 3, LIU Kai-li4, LIU Ming2, 3*. Effects of Calcium Salts on the Decomposition Process of Straw and the Characteristics of Three-Dimensional Excitation-Emission Matrices of the Dissolved Organic Matter in Decomposition Products[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2301-2307. |
[14] |
SHI Chuan-qi1, LI Yan2, HU Yu3, YU Shao-peng1*, JIN Liang2, CHEN Mei-ru1. Fluorescence Spectral Characteristics of Soil Dissolved Organic Matter in the River Wetland of Northern Cold Region, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1517-1523. |
[15] |
LI Yuan-jing1, 2, CHEN Cai-yun-fei1, 2, LI Li-ping1, 2*. Spectroscopy Study of γ-Ray Irradiated Gray Akoya Pearls[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1056-1062. |
|
|
|
|