太平天国侍王府壁画制作材料的光谱学分析

doi:10.3964/j.issn.1000-0593(2024)02-0452-08

Abstract
References
Related Citation (15)

Download: PDF (46134 KB)
Export: BibTeX | EndNote (RIS)

Abstract The murals in Prince Shi's Palace are typical of the murals in southern China, and they are also the most complete and painted mural relics of the Taiping Heavenly Kingdom. Because it is located in a humid area in the south, under the influence of environmental factors, the murals of Prince Shi's Palace have appeared with various diseases, and the preservation status is not optimistic. In order to protect this important mural, it is necessary to conduct scientific research on the production materials of murals. The nondestructive analysis was carried out by p-XRF and Raman spectroscopy. It was found that cinnabar (HgS) and hematite (Fe₂O₃) were used as the red pigments for the murals, and the white pigments were mainly calcite (CaCO₃). Analytical conditions limit other pigments, and no color components are detected. Several trace pigment and ground samples were obtained by sampling, and spectroscopic analysis techniques such as microscopic infrared spectroscopy (μ-FTIR), X-ray diffraction (XRD), micro-Raman spectroscopy (μ-Raman) and pyrolysis-gas chromatography/mass spectrum(Py-GC/MS) were used in the laboratory to analyze the blue-green pigments, ground components, binding material, types of fibers, etc. The results show that blue pigment is the first modern synthetic pigment prussianblue (Fe₄[Fe(CN)₆]₃), introduced into China and widely used in the middle and late Qianlong period. There are three kinds of green pigments, including synthetic atacamite, lavendulan, green discoloration product of paris green, and cumengite, first discovered in China. However, the current research has not seen the case of the use of cumengite as a pigment, and there is no report of such minerals in China. It is believed that the cumengite found in the murals is the product of the discoloration of other copper containing pigments. The results of Py-GC/MS show that there are proline and hydroxyproline in the pigment layer of the murals in prince Shi's Palace, which are the main components of animal glue, so animal glue is used as the cementing material for the murals. By calculating the infrared spectral characteristic peak ratios (I_{1 595}/I_{1 105}) and R₂ (I_{1 595}/I_{2 900}) of the fibers in the mural mud ground and lime ground, it is concluded that the fibers in the mural mud ground are ramie fibers and the fibers in the lime ground are cotton fibers. The research provides a scientific basis for pigment identification, restoration materials selection and scientific conservation of murals in Prince Shi's Palace of the Taiping Heavenly Kingdom.

Key words：Spectral analysis; Mural; Pigment; Fiber

Received: 2022-07-07 Accepted: 2022-10-29

ZTFLH:

K878.2

Corresponding Authors: YU Zong-ren E-mail: 13588975@qq.com

Cite this article:

SHUI Bi-wen,SUN Man-li,YU Zong-ren, et al. Spectroscopic Analysis of the Mural's Materials in Prince Shi's Palace of the Taiping Heavenly Kingdom[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(02): 452-459.

URL:

https://www.gpxygpfx.com/EN/10.3964/j.issn.1000-0593(2024)02-0452-08 OR https://www.gpxygpfx.com/EN/Y2024/V44/I02/452

[1] LI Qian, ZHANG Bing-jian, HE Shi-yang(李倩, 张秉坚, 何士扬). Cultural Relics of the East(东方博物), 2019, (3): 117.
[2] CAO Zhen-yu(曹振宇). History of Chinese Dye Industry(中国染料工业史). Beijing: China Light Industry Press(北京: 中国轻工业出版社), 2009.
[3] WANG Zhuo, SU Bo-min, YU Zong-ren, et al(王卓, 苏伯民, 于宗仁，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2020, 40(2): 356.
[4] Franquelo M L, Duran A, Herrera L L, et al. Journal of Molecular Structure, 2009, 924-926: 404.
[5] Bailey K. Studies in Conservation, 2012, 57(2): 116.
[6] XIA Yin(夏寅). WenBo(文博), 2009, (6): 342.
[7] Frost R, Weier M, Williams P, et al. Journal of Raman Spectroscopy, 2007, 38: 574.
[8] Li Zhimin, Wang Lele, Ma Qinglin, et al. Heritage Science, 2020, 8(1): 64.
[9] Frost R L, Williams P A, Martens W. Mineralogical Magazine, 2003, 67: 103.
[10] Cruciani G, Orlandi P, Pasero M, et al. Mineralogical Magazine, 2005, 69(6): 1037.
[11] Scott D. Copper and Bronze in Art: Corrosion, Colorants, Conservation(艺术品中的铜和青铜：腐蚀产物，颜料，保护). Translated by MA Qing-lin, PAN Lu, et al(马清林，潘路，等译). Beijing: Science Press(北京：科学出版社)，2009，115.
[12] ZHAO Jin-li, SU Bo-min, YU Zong-ren, et al(赵金丽，苏伯民，于宗仁，等). Journal of Northwest Normal University (Natural Science)[西北师范大学学报(自然科学版)], 2019, 55(3): 72.
[13] YAN Hui-na, ZHAO Feng, XING Meng-yang, et al(闫惠娜, 赵丰, 邢梦阳，等). Journal of Zhejiang Sci-Tech University(Natural Sciences)[浙江理工大学学报(自然科学版)], 2017, 37(2): 185.
[14] Garside P, Wyeth P. Studies in Conservation, 2003, 48(4): 269.
[15] WANG Cheng-yun, LIU Cai-ming, LI Li-xia, et al(王成云，刘彩明，李丽霞，等). China Fiber Inspection(中国纤检), 2007, (8): 38.
[16] ZHU Rui, YANG Fei, ZHOU Bo, et al(朱睿，杨飞，周波，等). Chinese Agricultural Science Bulletin(中国农学通报), 2014, 30(12): 258.