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| Origin Traceability of Atractylodes Macrocephala Koidz. by Using Three-Way Fluorescence Coupled With Chemometrics |
| CHEN Wei1, WU Hai-long1*, WANG Tong1*, CHANG Yue-yue1, CHEN Yao2, YANG Jian3, FU Hai-yan4, YANG Xiao-long4, LI Xu-fu5, YU Ru-qin1 |
1. State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
2. Hunan Key Lab of Biomedical Materials and Devices, College of Life Sciences and Chemistry, Hunan University of Technology, Zhuzhou 412008, China
3. National Resource Center for Chinese Materia Medica, China Academy of Chinese Medical Sciences, State Key Laboratory Breeding Base of Dao-di Herbs, Beijing 100700, China
4. The Modernization Engineering Technology Research Center of Ethnic Minority Medicine of Hubei Province, School of Pharmaceutical Sciences, South-Central University for Nationalities, Wuhan 430074, China
5. Beijing Tongrentang Pingjiang Atractylodes Macrocephala Koidz. Co., Ltd., Pingjiang 414500, China
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Abstract Atractylodes macrocephala Koidz. (AM) is a famous traditional Chinese medicine, the quality of AM is directly related to the producing area, so it is urgent to find a method to quickly identify the quality of AM and trace its origin. AM contains various endogenous fluorescent substances, which can provide a basis for identifying the origin of AM by three-way fluorescence technology. In this paper, the three-way fluorescence spectrum of AM was characterized by alternating trilinear decomposition (ATLD), and then three-way fluorescence was combined with partial least squares discriminant analysis (PLS-DA) and k-Nearest Neighbors (kNN) to trace the origin of AM samples. The results show that the classification models established by PLS-DA and kNN could effectively distinguish samples from the three major AM production areas (Anhui, Hunan, and Zhejiang), and the classificationaccurate rate (CCR) of Zhejiang AM, a Dao-di AM herbs, is as high as 80% and 90 in the prediction set, respectively. The proposed method provides a novel and rapid solution for the origin traceability of AM, which is conducive to maintaining the order of AM market and its industrial development.
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Received: 2021-05-25
Accepted: 2021-08-24
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Corresponding Authors:
WU Hai-long, WANG Tong
E-mail: hlwu@hnu.edu.cn; wangtong@hnu.edu.cn
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