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Nondestructive Identification of Green Tea Based on Near Infrared Spectroscopy and Chemometric Methods |
LI Pao1, 2, SHEN Ru-jia1, LI Shang-ke1, SHAN Yang2, DING Sheng-hua2, JIANG Li-wen1, LIU Xia1, DU Guo-rong1, 3* |
1. College of Food Science and Technology, Hunan Provincial Key Laboratory of Food Science and Biotechnology, Hunan Agricultural University, Changsha 410128, China
2. Hunan Agricultural Product Processing Institute, Hunan Academy of Agricultural Sciences, Changsha 410125, China
3. Beijing Work Station, Technology Center, Shanghai Tobacco Group Co., Ltd., Beijing 101121, China |
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Abstract Green tea is the most popular type of tea in China. The differences of green tea leaves from different categories are very small, and it is hard to distinguish them for non-experts by appearances. Traditional chemical methods are complicated in operation and are destructive to samples and it is difficult to achieve fast and nondestructive analysis. Near infrared spectroscopy (NIR) is a new technology, which is simple, fast, non-destructive, good in reproducibility and can be used for on-line analysis. The differences in the composition and content of the organic components in tea samples would be formed due to different growing environments and panting patterns, which can be measured by the NIR spectra. With the help of NIR spectra, the characteristic information of hydrogen groups can be obtained. The difference information of green tea leaves from different categories can be obtained, and the identification of green tea samples can be achieved. In this study, NIR was applied for nondestructive analysis of green tea leaves from different categories with the aid of chemometric methods. The dataset consists of eight brands of green tea samples. A relation has been established between the spectra and the tea varieties. The data was analyzed with principal component analysis. Furthermore, baseline elimination by continuous wavelet transform was used for improving the accuracy of the method. The wavenumber selection based on standard deviation and relative standard deviation was used to further improve the accuracy. The results show that the total variance explained by the first two principal components in principal component analysis was over 90% and they were enough for further analysis. The result of classification analysis using the original data was poor and cannot be used for the real application. The baseline interference can be eliminated with continuous wavelet transform method and the classification results were improved. The wavenumber selection method based on standard deviation and relative standard deviation consists of two steps. At first, the wavenumbers with standard deviation below 0.005 and the average below 0.01 were removed. Then, the wavenumbers that have large value of relative standard deviation were selected as informative ones, because the larger value of the relative standard deviation, the more variation between the samples. It was found that acceptable classification results can be obtained when several or several tens informative wavenumbers are used. It was found that, the main differences between varieties of tea are polyphenols, amides and amino acids. The results show the classification of different brands of green tea samples can be achieved by the proposed method, which provides a new idea for the rapid analysis of tea samples.
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Received: 2018-06-19
Accepted: 2018-10-27
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Corresponding Authors:
DU Guo-rong
E-mail: nkchem09@mail.nankai.edu.cn
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[1] Kumar P V S, Basheer S, Ravi R, et al. Journal of Food Science & Technology, 2011, 48(4): 440.
[2] Lin G, Meng X B, Rui F M, et al. International Journal of Food Science and Technology, 2016, 51(6): 1338.
[3] Senanayake S P J N. Journal of Functional Foods, 2013, 5(4): 1529.
[4] Miyauchi S, Yonetani T, Yuki T, et al. Journal of Bioscience and Bioengineering, 2017, 123(2): 197.
[5] Wu C Y, Xu H R, Héritier J, et al. Food Chemistry, 2012, 132(1): 144.
[6] Zhi R C, Zhao L, Zhang D Z. Sensors, 2017, 17(5): 1007.
[7] He W, Hu X S, Zhao L, et al. Food Research International, 2009, 42(10): 1462.
[8] ZHANG Yi-ting, WANG Cui-cui, FAN Meng-li, et al(张伊挺,王翠翠,樊梦丽,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2016, 36(12): 4100.
[9] Wang C C, Cai W S, Shao X G. Analytical Letters, 2017, 51(4): 537.
[10] Wei H Y, Li H, Liu P, et al. Spectroscopy Letters, 2017, 50(7): 470.
[11] CHU Xiao-li, YUAN Hong-fu, LU Wan-zhen(褚小立,袁洪福,陆婉珍). Progress Chemistry(化学进展), 2004, 16(4): 528.
[12] Tan Z, Lou T T, Huang Z X, et al. Journal of Agricultural and Food Chemistry, 2017, 65: 6274.
[13] Han X, Huang Z X, Chen X D, et al. Fuel, 2017, 207: 146.
[14] Zhang C X, Bian X H, Liu P, et al. Chemometrics and Intelligent Laboratory Systems, 2016, 161: 43.
[15] CHEN Quan-sheng, ZHAO Wen-jie, ZHANG Hai-dong, et al(陈全胜, 赵文杰, 张海东, 等). Food Science(食品科学), 2006, 27(4): 186.
[16] ZHANG Long, PAN Jia-rong, ZHU Cheng(张 龙, 潘家荣, 朱 诚). Food Science(食品科学), 2012, 33(20): 149.
[17] Chen D, Shao X, Hu B, et al. Analytica Chimica Acta, 2004, 511(1): 37.
[18] Cai W S, Li Y K, Shao X G. Chemometrics and Intelligent Laboratory Systems, 2008, 90(2): 188.
[19] Xu H, Liu Z C, Cai W S, et al. Chemometrics and Intelligent Laboratory Systems, 2009, 97(2): 189.
[20] Li H D, Liang Y Z, Xu Q S, et al. Analytica Chimica Acta, 2009, 648(1): 77.
[21] Han X, Tan Z, Huang Z X, et al. Analytical Methods,2017, 9: 3720.
[22] Li P, Du G R, Ma Y J, et al. Chemometrics and Intelligent Laboratory Systems, 2018, 176:157.
[23] Li P, Du G R, Cai W S, et al. Journal of Pharmaceutical and Biomedical Analysis, 2012, 70:288.
[24] Kennard R W, Stone L A. Technometrics, 1969, 11: 137. |
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