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| Chemical Effect Analyses of 3d Elements by Study of X-Ray Fluorescence Spectra |
| Sevil(Porikli) DURDAĞI |
| Faculty of Arts and Sciences, Department of Physics, Erzincan University, Erzincan 24030, Turkey |
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Abstract Spectra of K X-rays emitted from pure 3d transition metals and their oxide and sulfate compounds were measured using a single crystal wavelength dispersive X-ray spectroscopy (WDXRF). The measurements were performed using a ZSX-100e sequential spectrometer equipped with an Rh X-ray tube operated. An accurate analytical representation of each line was obtained by a fit to a Lorentz function. The spectra were analyzed in order to examine the K X-ray peak parameters such as asymmetry index, peak energy and relative intensity ratios. The energy shifts and relative intensities weredetermined tobetter understand the chemical effect.
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Received: 2016-02-01
Accepted: 2016-07-16
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[1] Porikli S, Demir D, Kurucu Y. Eur. Phys. J, 2008, D47: 315.
[2] Porikli S, Han İ, Yalçın P, et al. Spectros. Lett., 2011, 44: 38.
[3] Söğüt , Büyükkasap E, Erdoğan H. Radia. Phys. Chem.，2002，64：343.
[4] Apaydın G, Aylıkcı V, Cengiz E, et al. Radiat. Phys. Chem., 2008，77：923.
[5] Ito Y, Tochio T, Fukushima S, et al. Journal of Quan. Spect.& Rad. Tran., 2015, 151: 295.
[6] Dagistanli H, Kalayci Y, Mutlu R H. Rad. Phys. and Chem., 2010, 79: 938.
[7] Ceppi S, Tirao G, Stutz G, et al. Chem. Phys.，2008，354：80.
[8] Krishnananda, Santosh Mirji, Badiger N M, et al. J. of Elec. Spec. and Rel. Phen., 2012, 184: 556.
[9] Kumar A, Chauhan Y, Sanjiv P. At. Data Nucl. Data Tables, 2010, 96: 567.
[10] Kumar A, Sanjiv P. Rad. Phys. and Chem., 2011, 80: 1166.
[11] Deluigi M T, Tirao G, Stutz G, et al. Chemical Physics, 2006，325：477.
[12] Durdağı S P. Microchemical Journal, 2017, 130: 27.
[13] Tirao G, Ceppi S, Cappelletti A L, et al. J. of Phys. and Chem. of Solids, 2010，71：199.
[14] Porikli S, Kurucu Y. Instr. Sci. and Techn., 2008, 36: 341.
[15] Rebohle L, Lehnert U, Zschornack G. X-Ray Spectr.，1996，25：295.
[16] Küçükönder A, Şahin Y, Büyükkasap E, et al. J. Phys. B，1993，26：101.
[17] Porikli S, Kurucu Y. J. Radioanal. Nucl. Chem., 2011, 289: 739.
[18] Porikli S, Demir D, Kurucu Y. Balcan Phys. Lett. 24th Inter. Phys. Cong., 2008. 431.
[19] Porikli S, Kurucu Y. Appl. Rad. and Isot., 2008, 66: 1381. |
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