一批古代玻璃玦的化学成分和制作工艺科学研究

doi:10.3964/j.issn.1000-0593(2025)05-1403-13

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Abstract Wearing ornaments is a traditional custom that has been popular from ancient to present. As a type of ornament, Jue is one of the traditional types of jade artifacts in ancient China, which profoundly influenced Southeast Asia. Jue has diverse materials and shapes, has significant historical and regional characteristics, and is one of the important carriers for technological and cultural exchange. Up until now, research on ancient Asian ornaments has mainly involved gemstones and glass beads, while there are few reports on glass Jue. Studying the chemical compositions and trace element characteristics of glass Jue is expected to provide scientific references for the production era of glass Jue found in Southeast Asia and cultural exchanges along the Maritime Silk Road. In this paper, 44 glass Jue found in Southeast Asia have been scientifically analyzed using energy dispersive X-ray fluorescence spectroscopy (EDXRF), laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS), optical coherence tomography (OCT), optical microscopy (OM) and confocal laser Raman microspectroscopy. The Jue samples ' chemical compositions, phase components, internal physical structures, and surface micromorphology are obtained. According to the main flux content of these glass Jue samples, they can be classified into three glass types: potash glass, soda-alumina glass, and potash-lead glass. 42 samples belong to potash glass, and the 2 samples left belong to soda-alumina glass and potash-lead glass, respectively. Two subgroups, the m-K-Al subgroup and the m-K-Ca-Al subgroup, are found for potash glass. Only 4 potash glass samples belong to the m-K-Ca-Al subgroup; the others are the m-K-Al subgroup potash glass. Drawing, casting, and cold-working techniques were applied during glass making. Most of the blue-green, green, and yellow-green glass Jue samples are mainly colored with iron ions, and some of them are colored with both iron and copper ions. The blue and blue-black samples are colored with cobalt ions; the black sample SEAG-005 is colored with manganese ions. The potash-lead glass SEAG-031 is opacified by lead-tin yellow. Combining the glass types, trace element characteristics，shapes, and distributions of Jue, the origins of the raw materials, and production centers for the glass Jue samples are discussed. These glass Jue samples in Southeast Asia witnessed the spread of traditional Chinese culture to Southeast Asia through the Maritime Silk Road and its integration with local technology and culture between 500 BCE and 500 CE. The results of this paper provide a preliminary basis for the cooperation research between China and other countries along the Maritime Silk Road.

Key words：Ancient glass Jue; Southeast Asia; Chemical composition; Glass-making process; Maritime Silk Road

Received: 2024-06-07 Accepted: 2024-09-10

ZTFLH:

K883

Corresponding Authors: LI Qing-hui E-mail: qinghuili@siom.ac.cn

Cite this article:

HUANG Jue-wei,DONG Jun-qing,LIU Song, et al. Scientific Research on the Chemical Composition and Making Process of a Batch of Ancient Glass Jue[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2025, 45(05): 1403-1415.

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https://www.gpxygpfx.com/EN/10.3964/j.issn.1000-0593(2025)05-1403-13 OR https://www.gpxygpfx.com/EN/Y2025/V45/I05/1403

[1] CHEN Xing-can(陈星燦). East Asian Jade: Symbol of Excellence, Volume 1(东亚玉器: 上册). Hong Kong: Chinese Archaeological Art Research Center at The Chinese University of Hong Kong(香港: 香港中文大学中国考古艺术研究中心), 1998. 61.
[2] TANG Chung(邓聪). Journal of Cultural Heritage(文物), 2000, 2: 35.
[3] YANG Jian-fang(杨建芳). International Symposium on the Integration of Chinese Archaeology and Historiography, Volume 2(中国考古学与历史学之整合研究: 下册). Chinese Taiwan: Institute of History and Language, Academia Sinica, Taipei(中国台湾: 中研院历史语言研究所), 1997. 919.
[4] HUA Yu-bing(华玉冰). Chinese Archaeology: Trans-Century Retrospection and Projection(中国考古学跨世纪的回顾与前瞻). Beijing: Science Press(北京: 科学出版社), 2000. 327.
[5] LI Ying-kui, GAO Bo(李英魁, 高波). Archaeology(考古), 1996, (2): 1.
[6] ZHONG Xue(钟雪). Relics Museology(文博), 2022, (5): 54.
[7] CHEN Tian-ran, QIN Ling, WU Wei-hong, et al(陈天然，秦岭，吴卫红，等). Cultural Relics in Southern China(南方文物), 2020, 3: 151.
[8] Song S. Museologia Scientifica e Naturalistica, 2010, 6: 43.
[9] GAN Xiao-li(干小莉). Cultural Relics in Southern China(南方文物), 2008, 2: 109.
[10] TANG Chung(邓聪). East Asian jade: Symbol of Excellence, Volume 2(东亚玉器: 中册). Hong Kong: Chinese Archaeological Art Research Center at The Chinese University of Hong Kong(香港: 香港中文大学中国考古艺术研究中心), 1998.
[11] SUN Zhou-yong(孙周勇). Stone JueEarrings and the Western Zhou Craft Production System(玦出周原: 西周手工业生产形态管窥). Shanghai: Classics Press(上海: 古籍出版社), 2022.
[12] ZHU Qin-wen(朱勤文). Journal of Gems & Gemmology(宝石和宝石学杂志), 2022, 24(5): 14.
[13] Carter A K. Bulletin of the Indo-Pacific Prehistory Association, 2010, 30: 178.
[14] Insoll T, Polya D A, Bhan K, et al. Journal of Archaeological Science, 2004, 31: 1161.
[15] Dussubieux L, Walder H. The Elemental Analysis of Glass Beads: Technology, Chronology and Exchange. Leuven: Leuven University Press, 2022.
[16] Pearce N J G, Perkins W T, Westgate J A, et al. Geostandards Newsletter, 1997, 21: 115.
[17] Liu Y, Hu Z, Gao S, et al. Chemical Geology, 2008, 257(1): 34.
[18] Dong J Q, Li Q H, Hu Y Q. Chinese Optics Letters, 2020, 18(9): 5.
[19] Liu S, Li Q H, Gan F X, et al. X-Ray Spectrometry, 2013, 42(6): 470.
[20] DONG Jun-qing, LI Qing-hui, GAN Fu-xi, et al(董俊卿, 李青会, 干福熹, 等). Materials China(中国材料进展), 2012, 31(11): 9.
[21] Dussubieux L. Ancient Glass of South Asia: Archaeology, Ethnography and Global Connections. Springer, 2021. 489.
[22] LI Qing-hui, ZUO Jun, LIU Qi, et al(李青会, 左骏, 刘琦, 等). Research on the Hepu Port of the Han Dynasty from the Perspective of Cultural Exchange(文化交流视野下的汉代合浦港). Guangxi: Science and Technology Press(广西: 科学技术出版社), 2019.
[23] Sun S S, McDonough W F. Geological Society, 1989, 42: 313.
[24] Xu S, Qiao B, Yang Y. Journal of Archaeological Science: Reports, 2022, 42: 103383.
[25] Ma Q, Pollard A M, Yu Y F, et al. Heritage Science, 2022, 10: 29.
[26] Borell B, Dussubieux L. Journal of Glass Studies, 2022, 64: 33.
[27] LIU Song, LÜ Liang-bo, LI Qing-hui, et al(刘松, 吕良波, 李青会, 等). Sciences of Conservation and Archaeology(文物保护与考古科学), 2019, 31(4): 18.
[28] DONG Jun-qing, LIU Song, LI Qing-hui, et al(董俊卿, 刘松, 李青会, 等). Collection of Commemorative Articles on the 20th Anniversary of the Establishment of the Archaeology Major at Anhui University(安徽大学考古专业成立二十周年纪念文集). Beijing: Science Press(北京: 科学出版社), 2023. 383.
[29] Rolland J. Le verre de l' Europe celtique. Leiden: Sidestone Press, 2021.
[30] Wang A, Jolliff B L, Haskin L A, et al. American Mineralogist, 2001, 86: 790.
[31] Tomomi T, Daisuke N, Chien T D. Papers of Nara National Research Institute for Cultural Properties, 2021, 2: 125.
[32] GAN Fu-xi(干福熹). Development History of Ancient Chinese Glass Technology(中国古代玻璃技术发展史). Shanghai: Science and Technology Press(上海: 科学技术出版社), 2016.
[33] Guangzhou Municipal Institute of Cultural Heritage and Archaeology(广州市文物考古研究院). Study on the Beads and Pendants of Han Dynasties Unearthed from Guangzhou(广州出土汉代珠饰研究). Beijing: Science Press(北京: 科学出版社), 2020.