| 光谱学与光谱分析 |
|
|
|
|
|
| Application of Two FTIR Pattern Recognition Methods to the Zanthoxylum nitidum Geographical Origins Determination |
| MAO Xiao-li1,2, ZHENG Juan-mei1,2, LI Zi-da1,3, LEI Xin-chao2, HUANG Shu-shi1*, LIU Hua-gang4* |
1. Biophysics Laboratory, Guangxi Academy of Sciences, Nanning 530007, China
2. Guangxi Traditional Chinese Medical University, Nanning 530001, China
3. College of Physics Sciences and Technology, Guangxi Normal University, Guilin 541004, China
4. Department of Pharmacology, Guangxi Medical University, Nanning 530021, China |
|
|
|
|
Abstract In the present work, the authors explored a rapid method of the Zanthoxylum nitidum geographical origins determination. Based on Fourier transform infrared spectroscopy (FTIR) technology, the band of 1 800～400 cm-1 which is the IR fingerprint of Zanthoxylum nitidum, the Fisher ratio and the soft independent modeling of class analogies (SIMCA) were used to build a classification model. Respectively, four kinds of Zanthoxylum nitidum in the Guangxi region were detected by the model, and the model was verified by calculating their recognition rate and rejection rate. The results show that the authors can accurately extract the overall information of Chinese herbal medicines by using the FTIR, also established a pattern recognition model to predict unknown samples, and obtained satisfactory recognition rate and rejection rate, indicating that the model has stronger ability of identification. The detection on real time was carried out rapidly with the Fisher model, suggesting that the model has more practical value.
|
|
Received: 2010-12-31
Accepted: 2011-03-08
|
|
|
|
Corresponding Authors:
HUANG Shu-shi, LIU Hua-gang
E-mail: hshushi@yahoo.com.cn; lhg@gxfda.gov.cn
|
|
[1] The Pharmacopoeia Committee of the People’s Republic of China(国家药典委员会). Pharmacopoeia of the People’s Republic of China PartⅠ(中华人民共和国药典(一部)). Beijing: Chemical Industry Press(北京：化学工业出版社), 2010. 157.
[2] HU Xi-ming(胡熙明). Chinese Materia Medica(中华本草). Shanghai: China Science and Technology Press(上海：上海科学技术出版社), 1999. 991.
[3] WANG Xi-bin, LIU Hua-gang, YANG Bin, et al(王希斌，刘华钢，杨 斌，等).Chinese Pharmacological Bulletin(中国药理学通报), 2009, 25(9): 1256.
[4] WANG Heng-shan, OU Shang-yao, PAN Ying-ming, et al(王恒山，欧尚瑶，潘英明，等). Natural Product Research and Development(天然产物研究与开发), 2006, 18(2): 251.
[5] LIU Li-min, LIU Hua-gang, LUO Dan(刘丽敏，刘华钢，罗 丹). Chinese Journal Pharmacology and Toxicology(中国药理学与毒理学杂志), 2009, 23(3): 214.
[6] SUN Su-qin, ZHOU Qun, CHEN Jian-bo(孙素琴，周 群，陈建波). Analysis of Traditional Chinese Medicine by Infrared Spectroscopy(中药红外光谱分析与鉴定). Beijing: Chemical Industry Press(北京：化学工业出版社), 2010. 31.
[7] HUANG Dong-lan, CHEN Xiao-kang, XU Yong-qun, et al(黄冬兰，陈小康，徐永群，等). Journal of Instumental Analysis(分析测试学报), 2009, 28(12): 1440.
[8] Hu J, Zhang W, Shen Y,et al. Biochemical Systematics and Ecology, 2007, 35(2): 114.
[9] Liang M, Zhang M, Hu J, et al. Pharm. Biomed. Anal., 2006, 42(2): 178.
[10] LU Wan-zhen, YUAN Hong-fu, XU Guang-tong, et al(陆婉珍，袁洪福，徐广通，等). Modern Near Infrared Spectroscopy Analytical(现代近红外光谱分析), Beijing: China Petrochemical Press(北京:中国石化出版社), 2000. 188.
[11] DU Yi-ping, PAN Tie-ying, ZHANG Yu-lan(杜一平，潘铁英，张玉兰). Chemometrics Application(化学计量学应用). Beijing: Chemical Industry Press(北京：化学工业出版社), 2008. 63.
[12] Candolfi A, De Maesschalck R, Massart D L, et al. J. Pharm. Biomed. Anal., 1999, 19(6): 923.
[13] LI Ding-xiang, MIN Zhi-da(李定祥，闵知大). Chinese Journal of Natural Medicines(中国天然药物), 2004, 2(5): 285. |
| [1] |
XU Rong1, AO Dong-mei2*, LI Man-tian1, 2, LIU Sai1, GUO Kun1, HU Ying2, YANG Chun-mei2, XU Chang-qing1. Study on Traditional Chinese Medicine of Lonicera L. Based on Infrared Spectroscopy and Cluster Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3518-3523. |
| [2] |
LI Chen-xi1, SUN Ze-yu1, 2, ZHAO Yu2*, YIN Li-hui2, CHEN Wen-liang1, 3, LIU Rong1, 3, XU Ke-xin1, 3. The Research Progress of Two-Dimensional Correlation Spectroscopy and Its Application in Protein Substances Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 1993-2001. |
| [3] |
WANG Chu-biao1, 2, YANG Yan3, BAI Wei-guo4, LIN Yan1, XIE Yao-jian1, LU Wan-hong1*, LUO Jian-zhong1. The Relationship Between Genetic Variations and NIRs Differences of Eucalyptus Pellita Provenances[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3399-3404. |
| [4] |
ZHAO Zhong1*, LI Bin1, WU Yan-xian1, YUAN Hong-fu2. Edible Oil Classification Based on Molecular Spectra Analysis With SIMCA-SVDD Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(08): 2651-2656. |
| [5] |
SUN Yan-hua1, 2, FAN Yong-tao1, 2*. Correction of Temperature Influence in Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(06): 1690-1695. |
| [6] |
WEI Gang1, GU Zheng-ye1, GONG Shui-shui1, GUANG Shan-yi2, KE Fu-you1, XU Hong-yao1*. Determination of the Oxidizability on the Surface of the Graphene Oxide Layer by Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(06): 1722-1727. |
| [7] |
LU Wan-hong, LI Peng*, WANG Chu-biao, LIN Yan, LUO Jian-zhong. Identifying Eucalypt Hybrids and Cross Parents by Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(03): 873-877. |
| [8] |
CAO Hai-qing, HAN Tong-shuai, LIU Xue-yu, LIU Jin*. Extracting Linear Attenuance of Analyte in Turbid Scattering Media and Prediction Model Transfer Based Thereon[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(12): 3711-3717. |
| [9] |
FU Sai1, LIN Long-fei1, LIU Yu-ling1, SONG Ji-zheng1, SHAO Jin-xin2, ZHONG Ming3, XIE Tang-gui3, LI Hui1*. Rapid Determination of Water Content in Refined Honey Used as Key Excipient to Form Pills Based on Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(08): 2590-2594. |
| [10] |
LU Wan-hong, QI Jie*, LUO Jian-zhong. Application of NIRs for Discrimination of Eucalyptus Hybrids[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1451-1457. |
| [11] |
LIU Yan-de, YE Ling-yu, TANG Tian-yi, OUYANG Ai-guo, SUN Xu-dong, ZHANG Yu. Determination of Performance of Different Concentration Ethanol Diesel Oil Based on Mid Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(09): 2741-2748. |
| [12] |
ZHANG Xiao-yan, YANG Bing-nan, CAO You-fu, LI Shao-ping, ZHAO Qing-liang, XING Li*. SIMCA Discrimination of Ring Rot Potatoes Based on Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(08): 2379-2385. |
| [13] |
ZHANG Hai-liang1, CHU Bing-quan2, YE Qing1, LIU Xue-mei1, LUO Wei1*. Classification of Fishness Based on Hyperspectra Imaging Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 559-563. |
| [14] |
SUN Cui-ying, HAN Tong-shuai, GUO Chao, SHENG Wei-nan, LIU Jin*. The Correction Methods for Near Infrared Spectrum of Glucose Aqueous Solution to Reduce the Influence from Temperature[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(11): 3391-3398. |
| [15] |
YE Song1，ZHANG Bing-ke1, 2，YANG Hui-hua1，ZHANG Wen-tao1，DONG Da-ming2*. Identification of Beef Spoilage Processes Using the Infrared Spectrum of Volatiles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2751-2755. |
|
|
|
|
