光谱学与光谱分析 |
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Determination of Enoxacin in Urine by Synchronous Fluorimetry |
DAI Gang, AODENG Gao-wa* |
College of Chemistry and Chemical Engineering, Neimongol University, Hohhot 010021, China |
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Abstract The effect of metal ions on uhe fluorescence spectra of enoxacin was studied in detail. It has been found that aluminum can enhance the fluorescence intensity of enoxacin remarkably in the buffer solution of NaH2PO4-Na2B4O7 with pH 6.3. A new method using synchronous fluorimetry has been developed for the determination of enoxacin in human urine. The synchronous fluorescence intensity of Al/ENX system is linearly proportional to the concentration of ENX in the concentration range of 0.04-1.0 μg·mL-1. The detection limit, calculated according to IUPAC recommendations, was 0.018 μg·mL-1. The precision of the method was established by repeated assays (n=12) using 0.4 μg·mL-1 solution of ENX, and the relative standard deviation was 3.1%. The method was satisfactorily applied to the determination of enoxacin in human urine samples. The recovery was within the range of 95%-105%.
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Received: 2004-06-06
Accepted: 2004-09-08
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Corresponding Authors:
AODENG Gao-wa
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[1] Henwood J M, Monk J P. Drugs, 1988, 36: 32. [2] LIU Yi-pin, YANG Xiao-gang, LI Chang-sheng(刘一品, 杨小钢, 李常胜). Medical Journal of Wuhan University(武汉大学学报医学版), 2001, 22(4): 367. [3] LI Bin,WANG Hai-yi,WU Fan-hong(李 彬, 王海意, 吴范鸿). Journal of Tianjin Medical University(天津医科大学学报),1995,1(1):30. [4] WANG Xu,ZHAO Hui-chun(王 旭, 赵慧春). Acta Pharmaceutical Sinica(药学学报),2001,36(8):613. [5] LI Yuan-guang,YUAN Zuo-bin(李元光, 袁作斌). Journal of China University of Science and Technology(中国科学技术大学学报),1996,26(3):404. [6] You F T, Jin L P, Zhao H C. Anal. Commun., 1999, 36: 231. [7] Predrag T D, Milena Jelikic-Stankov, Dejan Stankov. Anal. Chim. Acta, 1995, 300: 253. [8] Anargiros I D, Pinelopi C I. Anal. Chim. Acta, 1997, 354: 197. [9] Gary L Long, Winefordner J D. Anal. Chem. A, 1983, 55: 712. [10] HE Li-fang, LIN Dan-li, LI Yao-qun(何立芳,林丹丽,李耀群). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2004,24(11):1384.
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