| 光谱学与光谱分析 |
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| Spectrophotometric Study on the Color Reaction of Multicomponent Complex of Tungsten-3,5-Dibromosalicyl Fluorone-CTMAB-Tween80 |
| WANG Jun, WEI Xian-jun, LI Quan-min*，YANG Lin |
| College of Chemistry and Environmental Science, Key Laboratory of Environmental Pollution Control Technology of Henan Province, Henan Normal University, Xinxiang 453002, China |
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Abstract In the presence of mixed surfactant cetyl trimethyl ammonium bromide(CTMAB) and Tween80, the photometric analysis properties of color reaction of 3,5-dibronosalicyl fluorone (DBSAF) with tungsten(Ⅵ) were studied. The experimental result showed that tungsten(Ⅵ) reacted with DBSAF to form a micelle complex with a maximum absorption at 527 nm in a 0.60 mol·L-1 hydrochloric acid medium. The mixed surfactant remarkably improved the sensitivity of the method and the dissolubility of the complex. The apparent molar absorptivity of the complex is 2.64×105 L·mol-1·cm-1 at 527 nm. Tungsten (Ⅵ) reacted with DBSAF to form a complex with a stoichiometric ratio of 1∶2, which was determined by mole ratio method and continual method of transformation, respectively. Beer’s law was obeyed in the range of 0-400 μg tungsten(Ⅵ) per L. The proposed method has been applied to the determination of trace amount of tungsten in alloy steel samples.
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Received: 2004-02-28
Accepted: 2004-06-06
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Corresponding Authors:
LI Quan-min
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| Cite this article: |
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WANG Jun,WEI Xian-jun,LI Quan-min, et al. Spectrophotometric Study on the Color Reaction of Multicomponent Complex of Tungsten-3,5-Dibromosalicyl Fluorone-CTMAB-Tween80 [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(08): 995-998.
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http://www.gpxygpfx.com/EN/Y2004/V24/I08/995 |
[1] HUANG Huo-ping, CAI Ru-xiu(黄厚评，蔡汝秀). Chem. J. Chinese Universities(高等学校化学学报), 1992, 13(12): 1513.
[2] HUANG Huo-ping, CAI Ru-xiu(黄厚评，蔡汝秀). Chem. J. Chinese Universities(高等学校化学学报), 1995, 16(1): 47.
[3] LONG Wen-qing, QIU Cheng-quan(龙文清，邱澄铨). Chinese Journal of Analytical Chemistry(分析化学)，1996，24(4)：411.
[4] ZHANG Heng(张 珩). Chinese Journal of Analytical Laboratory(分析试验室)，1996, 15(3): 39.
[5] SHENG Han-xi, WANG Zhen-qing(沈含熙，王振清). Chinese Journal of Analytical Chemistry(分析化学)，1981，9(6)：665.
[6] SAI Yin, ZHANG Jing(赛 音, 张 静). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001, 21(6)：843.
[7] HUANG Ying-ping, CAI Ru-xiu，HUANG Huo-ping(黄应平，蔡汝秀，黄厚评). Journal of Analytical Science(分析科学学报)，1999，15(4): 345.
[8] CAI Ru-xiu, HUANG Hou-ping, LIU He-chun(蔡汝秀，黄厚评，刘和春). Chinese Journal of Analytical Chemistry(分析化学)，1997，25(4): 476.
[9] HUANG Ying-ping, ZHANG Hua-shan(黄应平，张华山). Chinese Journal of Analytical Chemistry(分析化学)，2000，28(3): 160.
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