光谱学与光谱分析 |
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Study of Ferric Species Distribution in Polymeric Phosphate Ferric Sulfate (PPFS) |
ZHENG Huai-li, JIAO Shi-jun, HE Qiang, CHEN Rong, ZHANG Peng, FANG Hui-li |
Faculty of Urban Construction and Environmental Engineering, Chongqing University, Chongqing 400045, China |
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Abstract Based on the strong polymeric role of phosphate (PO3-4) on the PFS, PO3-4 was introduced in the ferric sulfate (PFS), and a new type of composite flocculant polymeric phosphate ferric sulfate (PPFS) was developed. The study includes the preparation of PPFS,and erric species distribution in PFSS was investigated by ultraviolet-visible spectrum method, infrared spectrum method and Fe-ferron complexation timed spectrophotometry method. The ultraviolet-visible spectrum showed that the change in the spectral curve of the different pH polymer ferric sulfate flocculants is corresponding to the flocculation morphology. Infrared spectra showed that the —P—O or PO vibration exists in the PPFS, certificated the ferric ion in PFS and phosphate caused the reaction, and produced the phosphate ferric polymer; and Fe-ferron complexation timed spectrophotometry showed that the amount of Fe(c) in polymeric phosphate ferric sulfate (PPFS) flocculants was the most in the three species, while the amount of Fe(a) and Fe(b) was small, that is PPFS mainly exists in the form of phosphate ferric polymer.
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Received: 2010-05-17
Accepted: 2010-09-30
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Corresponding Authors:
ZHENG Huai-li
E-mail: zhl@cqu.edu.cn;zhenghl@cta.cq.cn
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[1] Voegelin A, Kaegi R, Frommer J, et al. Geochimicaet Cosmochimica Acta, 2010, 74(1): 164. [2] SHI Tai-hong, WANG Jing-wen, GUO Ai-yi, et al(石太宏,王靖文,郭蔼仪,等). Chinese Environmental Science(中国环境科学), 2001, 21(2): 161. [3] ZHENG Huan-li, SHU Xing-wu, LIU Ming-chong, et al(郑怀礼,舒型武,刘名崇,等). Technology Water Treatment(水处理技术), 2001, 27(5): 274. [4] Wei J C, Gao B Y, Yue Q Y, et al. J. Hazard. Mater., 2009, 165(1-3): 789. [5] Joo D J, Shin W S, Choi J H, et al. Dyes and Pigments, 2007, 73(1): 59. [6] Moussas P A, Zouboulis A I. Separation and Purification Technology, 2008, 63(2): 475. [7] Dmytrenko G, Conti M I, Olivera M I, et al. BONE, 2009, 45(6): S152. [8] LI Feng-ting(李风亭). Industrial Water Treatment(工业水处理), 2002, 22(1): 5. [9] Jordan Jacqueline A, Verhoff Ashley M, Morgan Julie E, et al. In Vitro Cellular & Developmental Biology-Animal, 2009, 45(10): 602. [10] Petala M, Samaras P, Kungolos A, et al. Chemosphere, 2006, 66(6): 1007. [11] Lei G Y, Ma J, Guan X H, et al. Desalination, 2009, 247(1-3): 518. [12] Liang Z, Wang Y X, Zhou Y, et al. Water Science and Technology, 2009, 59 (6): 1129. [13] Xu Xin-yang, Li Li-jun, Li Ru. Journal of Northeastern University(Natural Science), 2009, 30(1): 137. [14] JIAO Shi-jun, ZHENG Huai-li, CHEN Rong et al. Journal of Central South University of Technology, 2009, 16(s1): 345. [15] Gregory J. Journal of Environmental Sciences-China, 2009, 21(1): 2. [16] WANG Dong-sheng, TANG Hong-xiao(王东升,汤鸿霄). Environmental Science(环境科学), 2001, 22(1): 94. [17] Gao Y X, Wang D S, Zhang Y, et al. Environmental Technology, 2009, 30(14): 1585. [18] YUAN Zong-xuan, ZHENG Huai-li, SHU Xing-wu(袁宗宣, 郑怀礼, 舒型武). Journal of Chongqing University(Natural Science Edintion)(重庆大学学报·自然科学版), 2001, 24(2): 141.
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