光谱学与光谱分析 |
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Application of ICP-MS to Determination of Heavy Metal Content of Heavy Metals in Two Kinds of N Fertilizer |
RUI Yu-kui, SHEN Jian-bo, ZHANG Fu-suo* |
College of Resources and Environmental Sciences, China Agricultural University, Key Laboratory of Plant Nutrition, MOA, Key Laboratory of Plant-Soil Interactions, MOE, Beijing 100193, China |
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Abstract Environmental safety has been the focus worldwide, where involved are the pollutions of heavy metals, pesticides and persistent organic pollutants. Fertilizer has become one of the polluting sources of heavy metals, which are very deleterious to human health and environmental safety. Heavy metals are difficult to metabolize in human body and very harmful, so research on the pollution of heavy metals is considered increasingly important. The pollution sources of heavy metals include waste residue, waste water and exhaust gas from industry and automobile, and garbage from human life. The heavy metals in fertilizer can endanger the human body by the crop containing heavy metals. Two kinds of nitrogen fertilizer were analyzed in terms of the content of heavy metals by ICP-MS, and the results showed that the content of 10 kinds of heavy metals (Al, Ti, Cr, Ni, Cu, Zn, As, Cd, Hg and Pb) in (NH4)2SO4 was 1 345.13, 35.12,2 539.27,287.26, 674.05,270.79, 42.54,22.13,27.20 and 123.87 ng·g-1 respectively; and in CO(NH2)2 it is 71.59, 5.36, 1 167.71, 188.60, 7.46, 64.45, 10.55, 0.00, 0.09 and 3.71 ng·g-1 respectively. All the data showed that CO(NH2)2 contained much less heavy metals than (NH4)2SO4,so we should select CO(NH2)2 as the nitrogen fertilizer in agricultural production.
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Received: 2007-05-28
Accepted: 2007-08-29
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Corresponding Authors:
ZHANG Fu-suo
E-mail: ruiyukui@163.com
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