| 光谱学与光谱分析 |
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| Application of ICP-MS to Detecting Ten Kinds of Heavy Metals in KCl Fertilizer |
| RUI Yu-kui, SHEN Jian-bo, ZHANG Fu-suo*,YAN Yun, JING Jing-ying, MENG Qing-feng |
| College of Resources and Environmental Sciences, China Agricultural University, Key Laboratory of Plant Nutrition, MOA, Key Laboratory of Plant-Soil Interactions, MOE，Beijing 100193, China |
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Abstract With the rapid development of society, more and more attention has been focused on environmental safety, especially on the pollutions of heavy metals, pesticides, persistent organic pollutants and deleterious microorganism. Heavy metals are difficult to metabolize in human body are quite harmful, so research on the pollution of heavy metals is increasingly important. There are many pollution sources of heavy metals, including waste residue, waste water and exhaust gas from industry and automobile, and garbage from human life. The contents of 10 kinds of heavy metals (Cr, Ni, Cu, As, Cd, Sn, Sb, Hg, Tl and Pb) in potassium fertilizer (KCl) from Russia were analyzed by ICP-MS. The results showed that potassium fertilizer (KCl) contained less heavy metals than organic-inorganic compound fertilizer; the content of heavy metals Cr, Ni, Cu, As, Cd, Sn, Sb, Hg, Tl and Pb is 0.00, 65.54,238.85, 190.60, 0.98, 14.98,2.97, 10.04, 1.28 and 97.42 ng·g-1,respectively, which accords with the correlative standards. All the data showed that if potassium fertilizer (KCl) is manufactured through normal channel, the content of heavy metals should be little and safe.
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Received: 2007-04-28
Accepted: 2007-08-02
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Corresponding Authors:
ZHANG Fu-suo
E-mail: ruiyukui@163.com
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[1] YANG Xiao-e, YU Jian-dong, NI Wu-zhong, et al(杨肖娥, 余剑东, 倪吾钟, 等). Review of China Agricultural Science and Technology(中国农业科技导报),2002, 4(4): 3.
[2] LIANG Ji-dong, ZHOU Qi-xing(梁继东, 周启星). Acta Scientiae Circumstantiae(环境科学学报),2004,24(3): 474.
[3] William H Blake, Rory P D. Walsh, Jane M Reed, et al. Environmental Pollution,2007, 148(1): 268.
[4] Anna Farkas, Claudio Erratico, Luigi Viganò. Chemosphere,2007, 68(4): 761.
[5] Wang Shaobin, Ang H M, Moses O Tade. Environment International,2007, 33(5): 694.
[6] Lorena M Rios, Charles Moore, Patrick R Jones. Marine Pollution Bulletin,2007, 148(1-2): 267.
[7] Lisa M Avery, Paul Hill, Ken Killham, et al. Jones. Soil Biology and Biochemistry,2004, 36(12): 2101.
[8] WANG Zhi-ping, WANG Feng-ying, WU Ri-na(王志平, 王凤英, 乌日娜). Journal of Jining Teachers College(集宁师专学报),2006,28(4): 70.
[9] ZHOU Wen-bin, QIU Bao-sheng(周文彬, 邱保胜). Journal of Lake Science(湖泊科学),2004, 16(3): 265.
[10] Martyn V Twigg. Applied Catalysis B: Environmental,2007, 70(1-4): 2.
[11] Polat H, Erdogan D. Journal of Hazardous Materials,2007, 148(1-2): 267.
[12] Samecka-Cymerman A, Kempers A J. Ecotoxicology and Environmental Safety,2004, 59(1): 64.
[13] GUO Yu-wen, PU Li-mei, QIAO Wei, et al(郭玉文, 蒲丽梅, 乔 玮, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006,26(8): 1540.
[14] WANG Li-ao, YUE Jian-hua, HUANG Chuan, et al(王里奥, 岳建华, 黄 川, 等). Acta Scientiae Circumstantiae(环境科学学报),2006,26(2): 246.
[15] WANG Cheng, QIE Guang-fa, YANG Ying, et al(王 成, 郄光发, 杨 颖, 等). Scientia Silvae Sinicae(林业科学),2007, 43(3): 1.
[16] HUANG Guo-qin, WANG Xing-xiang, QIAN Hai-yan, et al(黄国勤, 王兴祥, 钱海燕, 等). Ecology and Environment(生态环境),2004, 13(4): 656.
[17] RUI Yu-kui, GUO Jing, HUANG Kun-lun, et al(芮玉奎, 郭 晶, 黄昆仑, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2007,27(4): 796.
[18] WANG Qi-chao, MA Zhuang-wei(王起超, 麻壮伟). Rural Eco-Environment(农村生态环境),2004,20(2): 62.
[19] CHEN Hai-yan, GAO Xue, HAN Feng(陈海燕, 高 雪, 韩 峰). Planting with Culture(耕作与栽培),2006, (4): 18.
[20] GB 18877—2002，有机-无机复混肥料. |
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