Abstract:Raman spectroscopy was used to investigate the order-disorder phase transition of n-eicosane for real-time cooling run. At the phase transition temperature, the integrated intensity of the 1 300 cm-1 spectra range changes greatly, which requires further consideration of 1 300 cm-1 as a reference in the research on polymer and biomembrane using Raman spectroscopy. The experiment support was provided for doubt about order parameter based on 1 130 cm-1 that it did not refer to generally accepted interpretation of an order parameter and it proved that the order definition could just be used as a relative measure method for disorder.
金元浩, 陈羿廷, 杜为民* . 烷烃相变过程的拉曼光谱研究[J]. 光谱学与光谱分析, 2009, 29(06): 1562-1565.
JIN Yuan-hao,CHEN Yi-ting,DU Wei-min*. Study of Reference and Order Parameter of Raman Spectroscopy Research on Alkane Phase Transition . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(06): 1562-1565.
[1] Dirand M, Bouroukba M, Chevallier V, et al. J. Chem. Eng. Data, 2002, 47: 115. [2] Yang Xiaozhen, Kang Shuhui, Yang Yuning, et al. Polymer, 2004, 45: 4241. [3] ZU En-dong, CHEN Da-peng, ZHANG Peng-xiang(祖恩东,陈大鹏,张鹏翔). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(1): 64. [4] YU Duo-wei, ZHU Jing-ning, KE Wei-zhong(余多慰,朱景宁,柯惟中). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(4): 734. [5] Zheng M, Du W. Vib. Spectrosc., 2006, 40: 219. [6] Manohar R, Gupta M, Shukla J. J. Phys. Chem. Solids, 2000, 61: 1465. [7] Tarazona A, Koglin E, Meier R J, et al. Vib. Spectrosc., 1997, 14: 159. [8] QIAO Er-wei, ZHENG Hai-fei(乔二伟,郑海飞). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(1): 78. [9] Strobl G R, Hagedorn W. J. Polym. Sci., 1978, 16: 1181. [10] LIAO Yu-bo, MENG Yao-yong, LEI Hao-dong, et al(廖昱博,孟耀勇,雷浩东, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(5): 940. [11] LIU Hui-jun, XU Wei-jian, LIU Yao-chi, et al(刘慧君,徐伟箭,刘耀驰, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(8): 1596. [12] Koglin K, Meier R J. Computational Theoredical Polymer Science, 1999, 9: 327. [13] Garber B P, Peticolas W L. Biochim. Biophys. Acta, 1977, 465: 260. [14] Meier R J, Csiszar A, Klumpp E. J. Phys. Chem. B, 2006, 110: 5842. [15] CHEN Hui, JIANG Guo-chang, YOU Jing-lin, et al(陈 辉,蒋国昌,尤静林, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(12): 2464. [16] Suranga P, Wickramarachchi R, Spells S, et al. J. Phys. Chem. B, 2007, 111: 1604.