Application of Near-Field Raman Spectroscopy to Nano-Structure Characterization
WANG Yang1, WU Xiao-bin1, WANG Jia1*, YU Jian-yuan2
1. State Key Laboratory of Precision Measurement Technology and Instruments, Department of Precision Instruments, Tsinghua University, Beijing 100084, China 2. Analysis Center, Tsinghua University, Beijing 100084, China
Abstract:Near-field Raman spectroscopy is a novel technology in the near-field optics, and attracts much attention of scientists because of the realization of spectral characterization of nano-structure. The technical advantage of Raman spectroscopy is described in the present review. The principle and practical technical scheme of near-field Raman spectroscopy systems are introduced. Several applications of near-field Raman spectroscopy are mentioned in detail, including carbon nanotube characterization, biological specimen imaging, thermoelectric crystal characterization, dye single molecule detection etc., revealing a broad prospect of the development of near-field Raman spectroscopy in various scientific research fields.
[1] ZHANG Peng-xiang, GUO Wei-li, LI Xiu-ying(张鹏翔,郭伟力,李秀英). Spectroscopy and Spectral Analysis(光谱学与光谱分析),1987,17(3):1. [2] LUO Zhi-xun, FANG Yan(骆智训,方 炎). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006, 26(2): 358. [3] ZHU Xing(朱 星). Modern Scientific Instruments(现代科学仪器), 1998, 36(1-2):84. [4] ZHANG Shu-lin(张树霖). Near-Field Scanning Optical Microscopy and Its Application(近场光学显微镜及其应用). Beijing: Science and Technology Press(北京: 科学技术出版社), 2000. [5] Bert Heate, Beate Sick, Urs Wild P. Journal of Chemical Physics, 2000,112(18): 7761. [6] Norihiko Hayazawa, Alvarado Tarun, Yasushi Inouye, et al. Journal of Applied Physics, 2002,92(12): 6983. [7] Achim Hartschuh, Andweson N, Novotny L. Journal of Microscopy, 2003,210: 234. [8] Achim Hartschuh, Erik J. Sa'nchez, Xie X Sunney, et al. Physical Review Letters, 2003,90(99): 095503. [9] Norihiko Hayazawa, Takaaki Yano, Hiroyuki Watanabe, et al. Chemical Physics Letters, 2003,376: 174. [10] Achim Hartschuh, Andweson N, Novotny L. International Journal of Nanoscience, 2004,3(3): 371. [11] Mark S Anderson, Stephen D Gaimari. Journal of Structural Biology, 2003,142: 364. [12] Hiroyuki Watanabe, Yasuhito Ishida, Narihiko Hayazawa, et al. Physical Review B, 2004,69: 155418. [13] Steven R Emory, Shuming Nie. Anal. Chem., 1997,69: 2631. [14] Norihiko Hayazawa, Yasushi Inouye, Satoshi Kawata. Journal of Chemical Physics, 2002,117: 1296. [15] ZHOU Zeng-hui, LIU Li, XIAO Fan-rong, et al(周增会,刘 力,肖繁荣,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005,25(12):1986. [16] GUO Li-jun, ZHANG Xiang-tang, DU Zu-liang, et al(郭立俊,张兴堂,杜祖亮,等),Spectroscopy and Spectral Analysis(光谱学与光谱分析),2001,21(1):16. [17] Akira Sakai, Naoto Sasaki. Ferroelectrics, 2003,284: 15. [18] Hallen H D, Jahncke C L. Journal of Raman Spectroscopy, 2003,34: 655.