Spectroscopic Study on the Performance of 1,3-Thiacalix [4] Rhodamine Ethyldiamine Amide Derivatives to Fe3+ Ion
ZHANG Wen-juan1, ZHENG Xiang-yong1, ZENG Xi1, MU Lan1*, Takehiko Yamato2
1. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province; School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China 2. Department of Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machil, Saga-shi, Saga 840-8502, Japan
Abstract：The two di-substituted rhodamine-based thiacalix[4]arene ethyldiamine amide derivative were synthesized from thiacalix[4]arene and rhodamine B ethyldiamine by acylation. Under the experimental conditions, the derivatives and Fe3+ are able to form a 1∶1 complex. The formation of complex leaded to the moiety opening of rhodamine, and showed the good fluorescent and colorimetric performance. Among them, the selectivity of 1,3-thiacalix[4] rhodamine ethylenediamine amide-2,4-ester to Fe3+ is higher than 1,3-thiacalix [4] rhodamine ethylenediamine amide-2,4-acid. The analysis feature of the probes response to Fe3+ was studied by spectroscopy, and synthetic samples were determinec.
Key words：1;3-thiacalix[4]rhodamine ethylenediamine amide derivatives;Fluorescence and colorimetric probes;Fe3+
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