XPS Analysis of Chromium Element in Chromate Passivation Film Formed on Tinplate in Different Surface State
SUN Jie1,2,AN Cheng-qiang2,YU Xiao-zhong2,TAN Yong2
1. School of Environmental and Chemical Engineering, Shenyang Ligong University, Shenyang 110168, China 2. Research Center for Corrosion and Protection of Metal, Northeast University, Shenyang 110014, China
Abstract：X-ray photoelectron spectroscopy (XPS) was used to investigate the content and chemical valence of chromium element, and the content of compounds in chromate passive film formed on commercial tinplate via a cathodic electrolytical treatment. The effect of the content and chemical valence for different surface state was studied by using ultrasonic process. From the results, it was shown that there existed Cr, O and Sn in the passivation film. The chromium element in the film was mainly in the forms of Cr(OH)3,Cr2O3,and Cr in the natural surface. The Cr(Ⅵ) changed to lower value in the process of cathodic electrolytical treatment. A small quantity of Cr(Ⅵ) was found in the defective surface besides Cr(OH)3 and Cr2O3. The content of chromium element in the defective surface was lower than that in the natural surface. When ultrasonic process was added, the content of chromium element in the defective surface was obviously lower than that when no ultrasonic process was added. When ultrasonic process was used, the small quantity of Cr(Ⅵ) originally adsorbed on the defective surface disappeared because of the strong elution produced by ultrasonic.
孙杰1,2,安成强2,于晓中2,谭勇2. 不同表面状态镀锡钢板铬酸盐钝化膜中铬元素的XPS分析[J]. 光谱学与光谱分析, 2009, 29(02): 544-547.
SUN Jie1,2,AN Cheng-qiang2,YU Xiao-zhong2,TAN Yong2 . XPS Analysis of Chromium Element in Chromate Passivation Film Formed on Tinplate in Different Surface State. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(02): 544-547.
[1] Azzerri N, Bruno R, Ferrari V, et al. Materials Chemistry, 1982, 7(2): 221. [2] Ammar I A, Darwish S, Khalil M W, et al. Materials Chemistry and Physics, 1989, 21(1): 1. [3] Boustead I, Hancock G F. Resources and Conservation, 1981, 6(1): 29. [4] Catala R, Cabanes J M, Bastidas J M. Corrosion Science, 1998, 40(9): 1455. [5] Bellezze T, Roventi G, Fratesi R. Surface and Coatings Technology, 2002, 155: 221. [6] QI Guo-chao, GONG Xue-nan, SUN De-en, et al(齐国超, 贡雪南, 孙德恩, 等). Journal of Northeastern University(东北大学学报), 2006, 27(8): 875. [7] LIU Chang-fu, GUO Yu-hua(柳长福, 郭玉华). Reseach on Iron and Steel(钢铁研究)，2000, (3): 38. [8] SHA Ren, HAN Ming-mei(莎 仁, 韩明梅). Metallurgical Analysis(冶金分析), 2005, 25(3): 48. [9] CHEN Lan-hua, LI San-yang(陈兰华, 李三阳). Metallurgical Analysis(冶金分析), 2005, 25(3): 37. [10] KANG Wei-jun, SUN Han-wen(康维钧, 孙汉文). Metallurgical Analysis(冶金分析), 2005, 25(1): 27. [11] LIU Shi-hong, WANG Dang-han, PAN Cheng-haung(刘世宏, 王当憨, 潘承璜). Analysis of X-ray Photoelectron Spectroscopy(X射线光电子能谱分析). Beijing: Science Press(北京：科学出版社), 1988. [12] BAI Yu-lan, XU Hong-bin, ZHANG Yi(白玉兰, 徐红彬, 张 懿). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(4): 675. [13] FENG Shao-bin, SHANG Shi-bo, FENG Li-ting, et al(冯绍彬, 商士波, 冯丽婷, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(1): 166. [14] OU Gu-ping, SONG Zhen, GUI Wen-ming, et al(欧谷平, 宋 珍, 桂文明, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(4): 753. [15] Arenas M A, Garcia I, de Damborenea J. Corrosion Science, 2004, 46(4): 1033. [16] Hanawa T, Hiromoto S, Yamamoto, et al. Materials Transactions, 2002, 43 (12): 3088. [17] Mora N, Cano E, Polo J L, et al. Corrosion Science, 2004, 46: 563. [18] Long Z L, Zhou Y C, Xiao L. Applied Surface Science, 2003, 218: 123. [19] Zhang X, Van den Bos C, Sloof W G, et al. Surface & Coatings Technology, , 2005, 199(1): 92. [20] Simon P, Bui N, Dabosi F, et al. Journal of Power Sources, 1994, 52: 31. [21] Rammanauskas R, Gudaviciute L, Diaz-ballote L, et al. Surface and Coatings Technology, 2001, 140: 109. [22] Azzerri N, Ingo G, Battistoni C, et al. Surface Technology, 1984, 21(4): 391. [23] SUN Jie, QI Guo-chao, YU Xiao-zhong, et al(孙 杰, 齐国超, 于晓中, 等). Metallurgical Analysis(冶金分析), 2007, 27(1)：17.
