摘要: Spectra of K X-rays emitted from pure 3d transition metals and their oxide and sulfate compounds were measured using a single crystal wavelength dispersive X-ray spectroscopy (WDXRF). The measurements were performed using a ZSX-100e sequential spectrometer equipped with an Rh X-ray tube operated. An accurate analytical representation of each line was obtained by a fit to a Lorentz function. The spectra were analyzed in order to examine the K X-ray peak parameters such as asymmetry index, peak energy and relative intensity ratios. The energy shifts and relative intensities weredetermined tobetter understand the chemical effect.
Abstract:Spectra of K X-rays emitted from pure 3d transition metals and their oxide and sulfate compounds were measured using a single crystal wavelength dispersive X-ray spectroscopy (WDXRF). The measurements were performed using a ZSX-100e sequential spectrometer equipped with an Rh X-ray tube operated. An accurate analytical representation of each line was obtained by a fit to a Lorentz function. The spectra were analyzed in order to examine the K X-ray peak parameters such as asymmetry index, peak energy and relative intensity ratios. The energy shifts and relative intensities weredetermined tobetter understand the chemical effect.
基金资助: the Scientific and Technological Research Council of Turkey (TUBITAK), under the project No. 106T045
作者简介: sporikli@gmail.com
引用本文:
Sevil(Porikli) DURDAĞI. Chemical Effect Analyses of 3d Elements by Study of X-Ray Fluorescence Spectra[J]. 光谱学与光谱分析, 2018, 38(08): 2630-2637.
Sevil(Porikli) DURDAĞI. Chemical Effect Analyses of 3d Elements by Study of X-Ray Fluorescence Spectra. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(08): 2630-2637.
[1] Porikli S, Demir D, Kurucu Y. Eur. Phys. J, 2008, D47: 315.
[2] Porikli S, Han İ, Yalçın P, et al. Spectros. Lett., 2011, 44: 38.
[3] Söğüt , Büyükkasap E, Erdoğan H. Radia. Phys. Chem.,2002,64:343.
[4] Apaydın G, Aylıkcı V, Cengiz E, et al. Radiat. Phys. Chem., 2008,77:923.
[5] Ito Y, Tochio T, Fukushima S, et al. Journal of Quan. Spect.& Rad. Tran., 2015, 151: 295.
[6] Dagistanli H, Kalayci Y, Mutlu R H. Rad. Phys. and Chem., 2010, 79: 938.
[7] Ceppi S, Tirao G, Stutz G, et al. Chem. Phys.,2008,354:80.
[8] Krishnananda, Santosh Mirji, Badiger N M, et al. J. of Elec. Spec. and Rel. Phen., 2012, 184: 556.
[9] Kumar A, Chauhan Y, Sanjiv P. At. Data Nucl. Data Tables, 2010, 96: 567.
[10] Kumar A, Sanjiv P. Rad. Phys. and Chem., 2011, 80: 1166.
[11] Deluigi M T, Tirao G, Stutz G, et al. Chemical Physics, 2006,325:477.
[12] Durdağı S P. Microchemical Journal, 2017, 130: 27.
[13] Tirao G, Ceppi S, Cappelletti A L, et al. J. of Phys. and Chem. of Solids, 2010,71:199.
[14] Porikli S, Kurucu Y. Instr. Sci. and Techn., 2008, 36: 341.
[15] Rebohle L, Lehnert U, Zschornack G. X-Ray Spectr.,1996,25:295.
[16] Küçükönder A, Şahin Y, Büyükkasap E, et al. J. Phys. B,1993,26:101.
[17] Porikli S, Kurucu Y. J. Radioanal. Nucl. Chem., 2011, 289: 739.
[18] Porikli S, Demir D, Kurucu Y. Balcan Phys. Lett. 24th Inter. Phys. Cong., 2008. 431.
[19] Porikli S, Kurucu Y. Appl. Rad. and Isot., 2008, 66: 1381.