|
|
|
|
|
|
Rapid Diagnosis of Surface Water Salt Content (WSC) in Ebinur Lake Watershed Based on 3-D Fluorescence Technology |
WANG Xiao-ping1,2, ZHANG Fei1,2,3*, YANG Sheng-tian4,AYINUER·Yushanjiang1,2,CHEN Yun5 |
1. College of Resources and Environment Science, Xinjiang University, Urumqi 830046,China
2. Key Laboratory of Oasis Ecology, Xinjiang University, Urumqi 830046, China
3. Key Laboratory of Xinjiang Wisdom City and Environment Modeling,Urumqi 830046, China
4. School of Geography, Beijing Normal University, Beijing 100875
5. CSIRO, Land and Water, Canberra 2601, Australia |
|
|
Abstract How to make the water quality monitoring under the influence of high levels of salt, is the key to the effective management of water quality in oases in arid areas. The author takes Ebinur lake watershed as the study area, combining three-dimensional fluorescence excitation-emission matrices (3-DEEM) with parallel factor analysis (PARAFAC), extracting three -dimensional fluorescent components of surface water in Ebinur lake watershed, constructing the index of three-dimensional fluorescence spectrum, which is fit surface water in arid area, using linear regression were establishing diagnosis model of water salt content based on the technique of three-dimensional fluorescence spectrum. The results showed that: (1) The four fluorescence components were successfully extrapolated by the parallel factor analysis modeling from the fluorescence EEM data including microbial humic-like (Component 1), terrestrial humic-like organic substances (Component 2, Component 4), and protein-like organic substances (Component 3); (2) Three-dimensional fluorescence index analysis showed that terrigenous organic pollution was the main organic pollution type in the watershed. This study indicates that the watershed is subject to human disturbance, gives the large variation of organic pollution in the water body, and the correlation between three-dimensional fluorescence index, fluorescent components and water salt content is significant; There is a significant relationship between W2,W4,W7,F355,HIX, BIX and salt water content. The correlation coefficients r in the range of 0.516 and 0.915, is a negative relationship between BIX and water salt content, and the correlation coefficient r is -0.57. (3) The application of three-dimensional fluorescence index and fluorescence component to establish salt water content produced a model fitting coefficient (r) that is greater than 0.7 and residual predictive deviation (RPD) that is greater than 1.4, the model has a high predictive ability, which demonstrated that the accuracy of the model was in line with monitoring requirements in practice. Therefore, based on the three dimensional fluorescence spectrum technology, the realization of Ebinur Lake Watershed surface water salinity diagnosis research is effective. This study not only explores the three-dimensional fluorescence characteristics of the surface water of the Ebinur Lake Watershed, but may also be applied to three-dimensional fluorescence extraction of other surface waters in arid regions of Central Asia.
|
Received: 2017-06-06
Accepted: 2017-10-29
|
|
Corresponding Authors:
ZHANG Fei
E-mail: zhangfei3s@163.com
|
|
[1] LIANG Bian-bian, SHI Pei-ji, WANG Wei, et al(梁变变, 石培基, 王 伟, 等). Chinese Journal of Applied Ecology(应用生态学报), 2017, 28(1): 199.
[2] ZHU Chun, XIE Xin, ZHAO Jin-chen, et al(朱 纯, 谢 心, 赵金辰, 等). Spectroscopy and Spectral analysis(光谱学与光谱分析), 2017, 37(1): 141.
[3] Bourgeois W, Burgess J E, Stuetz R M. Journal of Chemical Technology and Biotechnology, 2001, 76(4): 337.
[4] YAO Yi-liang, ZHAO Wei-hong, MIAO Hui(药怡良, 赵卫红, 苗 辉). Spectroscopy and Spectral analysis(光谱学与光谱分析), 2016, 36(8): 2532.
[5] Baker A, Cumberland S A, Bradley C, et al. Science of the Total Environment, 2015, 532: 14.
[6] Hudson N, Baker A, Ward D, et al. Science of the Total Environment, 2008, 391(1): 149.
[7] Guo X J, Zhu N M, Chen L, et al. Journal of Soils & Sediments, 2015, 15(7): 1473.
[8] WANG Juan, ZHANG Fei, WANG Xiao-ping, et al(王 娟, 张 飞, 王小平, 等). Acta Optica Sinica(光学学报), 2017, 37(7): 0730003.
[9] Cui Yanrui, Wu Qing, Yang Mengsi. Environ. Sci. Pollut. Res., 2016, 23(1): 793.
[10] Wang Xiaoping, Zhang Fei, Hsiang-te Kung, et al. Catena, 2017, (155): 62.
[11] Birdwell J E, Engel A S. Organic Geochemistry, 2010, 41(3): 270.
[12] Du Yingxun, Zhang Yuanyuan, Chen Feizhou, et al. Science of the Total Environment, 2016, (568): 216.
[13] Huguet L,Vacher S,Relexans S. et al. Organic Geochemistry, 2009, (40): 706.
[14] Zhao Ying, Song Kaishan, Li Sijia, et al. Environ Sci Pollut Res., 2016, (23): 15381.
[15] Cuss C W, Gueguen C, et al. Water Research, 2015, (68): 487.
[16] AN Ying, WANG Zhi-wei, LI Bin, et al(安 莹, 王志伟, 李 彬, 等). China Environmental Science(中国环境科学), 2014, 34(7): 1754. |
[1] |
WANG Yu-tian, WANG Jun-zhu*, SHANG Feng-kai, BIAN Xu. Method for Detecting Pesticide Content of Carbofuran by Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(09): 2843-2846. |
[2] |
WU Xi-jun, CUI Yao-yao, PAN Zhao*, LIU Ting-ting, YUAN Yuan-yuan. 3D Fluorescence Spectra Combined with Zernike Image Moments for Rapid Identification of Doping Sesame Oil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(08): 2456-2461. |
[3] |
WANG Shu-tao, LIU Ting-ting*, SHANG Feng-kai, CUI Yao-yao, YANG Zhe, WANG Yu-tian. Three-Dimensional Fluorescence Spectroscopy Combined with Wavelet Compression and Alternate Penalty Quad Linear Decomposition for Environmental Analysis: Determination of Polycyclic Aromatic Hydrocarbons[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(08): 2441-2450. |
[4] |
GU Jiao1, 2, CHEN Guo-qing1, 2*, ZHANG Xiao-he1, 2, LIU Huai-bo1, 2, MA Chao-qun1, 2, ZHU Chun1, 2, LIAO Cui-cui1, 2. Classification and Year Prediction of Chinese Liquors Based on Wavelet Decomposition and Factor Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(08): 2511-2515. |
[5] |
LÜ Jing-jing1, 2, 3, YU Shui-li1, ZHANG Lie-yu3, XI Bei-dou3, DOU Yan-yan2, HOU Li-an1, 4. Vertical Distribution Characteristics of DOM in Soil Infiltration System Based on 3D-EEMs and PARAFAC[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(08): 2549-2555. |
[6] |
TAN Ai-ling1, WANG Si-yuan1, ZHAO Yong2, ZHOU Kun-peng1, LU Zhang-jian1. Research on Vinegar Brand Traceability Based on Three-Dimensional Fluorescence Spectra and Quaternion Principal Component Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2163-2169. |
[7] |
LIU Huan, LIU Wen, HAN Dong-hai*, WANG Shi-ping*. Three-Dimensional Fluorescence Fingerprint Technique for Milk Quality Evaluation: Antibiotic Residual Detection and Heat-Treated Evaluation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1633-1639. |
[8] |
FAN Gong-duan1*, LIN Xiu-yong1,2, WANG Shu-min1,2*, LUO Jing1, XIE Zhi-gang2, LI Qiang2. Compositional Characteristics of Interstitial Water Dissolved Organic Matter in Bioretention Systems with Different Filling[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1139-1145. |
[9] |
OUYANG Heng1,2*, XIAO Jian-ren3, LIN Xiu-yong4, FAN Gong-duan4*. Compositional Characteristics of Dissolved Organic Matter in Water Treatment Systems of Water Source Heat Pump Based on Three-Dimensional Fluorescence Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1146-1152. |
[10] |
HU Le-qian, MA Shuai, YIN Chun-ling, LIU Zhi-min. Modeling Excitation-Emission Fluorescence Matrices with Multidimensional Pattern Recognition Algorithms for Classification of Raisin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1153-1159. |
[11] |
WANG Yu-tian, LIU Ting-ting*, LIU Ling-fei, YANG Zhe, CUI Yao-yao. Determination of Polycyclic Aromatic Hydrocarbons in Water Based on Three Dimensional Fluorescence Spectroscopy Combined with Wavelet Compression and APTLD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1171-1177. |
[12] |
ZHOU Yan-lei1, ZHOU Fei-fei1, JIANG Cong-cong1, SHI Xiao-yong1,2*, SU Rong-guo1. Research of Identification Method for the Oil Spills Species Based on Fluorescence Excitation-Emission Matrix and Parallel Factor Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 475-480. |
[13] |
ZHANG Xian-long1, 2, ZHANG Fei1, 2, 3*, ZHANG Hai-wei1, 2, HAI Qing4, CHEN Li-hua5. The Preliminary Study on the Relationship between Two Dimensional Fluorescence Peak Value of Surface Water and Water Quality Indexes in Ebinur Lake Basin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 481-487. |
[14] |
XIE Zhi-yong1,2, XIE Li-qin1,2, JIANG Shen-hua1,2,3*, QU Wen-juan1,3, ZHANG Xiao-xia1,2, ZHANG Hua-hao1,2, HAO Shu1,2, ZHANG Liang-hui1,2, MA Hai-le1,3, SHEN Yong-gen1,4. The Comparison of Inhibition on LDL Non-Enzymatic Glycosylation and Oxidation between Ethyl Acetate Extracts of Clove and Clove Bud Oil Based on Spectroscopy Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 518-527. |
[15] |
WANG Bi1, 2, XI Hong-bo2, ZHOU Yue-xi1, 2*, CHEN Xue-min1, FU Xiao-yong1. Effects of Different Substituents on Three Dimensional Fluorescence Properties of BTEX[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3763-3770. |
|
|
|
|