|
|
|
|
|
|
| Fabrication of Gold Nanoparticle Array Substrate by Chemical Replacement and Its Surface Enhanced Raman Scattering Properties |
| LI Yu, HUANG Xiao-ping*, WANG Ying, HOU Yu-meng, CHEN Tao, ZHANG Pei-feng, HUANG Qiu-ying, ZHAO Qing |
| School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054, China |
|
|
|
|
Abstract Surface enhanced Raman Spectroscopy (SERS), as an analytical method, has the notable advantages of high sensitivity, high selectivity, high reproducibility and non-destructivity. It has been widely used in component characterization, environmental science, biomedicine, biosensors and other fields in the recent decades. Among them, gold and silver and other noble metal nanoparticles-based films have been widely used for SERS active substrates. A key factor in SERS is how to design and fabricate SERS substrates with large size, high enhancement, high repeatability, and recyclability. In general, the combined effect of the electromagnetic enhancement of the noble nanoparticles in a regular array and the enhancement of the electromagnetic coupling among the nanoparticles enhance the detection performance of the SERS substrate. However, the surface roughness of the nanostructures prepared by conventional methods such as photolithography and electron beam lithography is not enough. In this paper, we developed a method for the fabrication of gold nanoparticles tetragonal array pore structure by the combination of photolithography and chemical replacement methods. And, the electromagnetic enhancement properties SERS signal of the fabricated Au nanoparticles array substrates were investigated. The regular round holes array were etched with a tetragonal lattice structure on the silicon by photolithography. Then, the Fe film was deposited on the holes array by magnetron sputtering. After that, the chloroauric acid liquid membrane with a concentration of 1.893 8 mol·L-1 was spin-coated into the holes array on the substrate. The Fe film was then replaced with Au nanoparticles array in the iron holes array. Thus, the fabrication of SERS substrate with gold nanoparticles square lattice was completed. Based on the scanning electron microscopy (SEM) of the microstructure of the substrate, the gold nanoparticles deposited on the substrate were more and larger with the increasing reaction time between the iron film and the chloroauric acid solution. In order to verify the difference in nanostructure caused by different replacement time, the electromagnetic enhancement properties of the prepared gold nanoparticles array was characterized with SERS measurements. The SERS spectra of Au nanostructured substrate were measured by using rhodamine 6G (R6G) as probe molecule. The experimental results showed that the gold nanoparticles were more compact and order with a longer replacement time, and we can get the corresponding stronger SERS signal.
|
|
Received: 2017-01-03
Accepted: 2017-05-12
|
|
|
|
Corresponding Authors:
HUANG Xiao-ping
E-mail: xphuang@uestc.edu.cn
|
|
[1] Miyaucii Y H, Chiashi S H, Murakami Y, et al. Chemical Physics Letters, 2004, 386: 89.
[2] Demefitte T, Kanchanapally R, Fan Z, et a1. Analyst, 2012, 137(21): 5041.
[3] Das G, Mecarini F, Gentile F, et a1. Biosensors and Bioelectronics, 2009, 24(6): 1693.
[4] Fleischmann M, Hill I, Robinson J. Chemical Physics Letters, 1983, 97(4): 441.
[5] Jeanmaire D L, Van Duyne R P. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1977, 84(1): 1.
[6] Albrecht M G, Creighton J A. Journal of the American Chemical Society, 1977, 99(15): 5215.
[7] Moskovits M. The Journal of Chemical Physics, 1978, 69(9): 4159.
[8] Wrobel P, Antosiewicz T J, Stefaniuk T. Proc. of SPIE, 2015, 9502: 1.
[9] Aslan K, Leonenko Z, Joseph R. Journal of Fluorescence, 2005, 15: 643.
[10] Chen L，Zhai T，Zhang X，et al. Nanotechnology, 2014, 25: 265302.
[11] Lim D K, Jeon K S, Kim H M, et al. Nature Materials, 2010, 9(1): 60.
[12] Hao E, Li S, Bailey R C, et al. The Journal of Physical Chemistry B, 2004, 108(4): 1224.
[13] ZHANG Xiao-lei，ZHANG Jie，REN Wen-jie, et al(张晓蕾，张 洁，任文杰，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2015, 36(6): 1567.
[14] JIANG Jiao-lai, ZHANG Jing, JIA Jian-ping, et al(姜交来，张 靖，贾建平，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2016, 36(11): 3563.
|
| [1] |
LAI Chun-hong*, ZHANG Zhi-jun, WEN Jing, ZENG Cheng, ZHANG Qi. Research Progress in Long-Range Detection of Surface-Enhanced Raman Scattering Signals[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2325-2332. |
| [2] |
LI Jia-jia, XU Da-peng *, WANG Zi-xiong, ZHANG Tong. Research Progress on Enhancement Mechanism of Surface-Enhanced Raman Scattering of Nanomaterials[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1340-1350. |
| [3] |
SUN Zhi-ming1, LI Hui1, FENG Yi-bo1, GAO Yu-hang1, PEI Jia-huan1, CHANG Li1, LUO Yun-jing1, ZOU Ming-qiang2*, WANG Cong1*. Surface Charge Regulation of Single Sites Improves the Sensitivity of
Raman Detection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1075-1082. |
| [4] |
YIN Xiong-yi1, SHI Yuan-bo1*, WANG Sheng-jun2, JIAO Xian-he2, KONG Xian-ming2. Quantitative Analysis of Polycyclic Aromatic Hydrocarbons by Raman Spectroscopy Based on ML-PCA-BP Model[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 861-866. |
| [5] |
SUN Nan, TAN Hong-lin*, ZHANG Zheng-dong, REN Xiang, ZHOU Yan, LIU Jian-qi, CAI Xiao-ming, CAI Jin-ming. Raman Spectroscopy Analysis and Formation Mechanism of Carbon
Nanotubes Doped Polyacrylonitrile/Copper Cyclized to Graphite
at Room Temperature[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2983-2988. |
| [6] |
WANG Zi-xiong, XU Da-peng*, ZHANG Yi-fan, LI Jia-jia. Research Progress of Surface-Enhanced Raman Scattering Detection Analyte Molecules[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 341-349. |
| [7] |
WAN Xiao-ming1, 2, ZENG Wei-bin1, 2, LEI Mei1, 2, CHEN Tong-bin1, 2. Micro-Distribution of Elements and Speciation of Arsenic in the Sporangium of Pteris Vittata[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 470-477. |
| [8] |
HUANG Hui1, 2, TIAN Yi2, ZHANG Meng-die1, 2, XU Tao-ran2, MU Da1*, CHEN Pei-pei2, 3*, CHU Wei-guo2, 3*. Design and Batchable Fabrication of High Performance 3D Nanostructure SERS Chips and Their Applications to Trace Mercury Ions Detection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3782-3790. |
| [9] |
FU Xing-hu, WANG Zhen-xing, MA Shuang-yu, ZHAO Fei, LU Xin, FU Guang-wei, JIN Wa, BI Wei-hong. Preparation and Properties of Micro-Cavity Silver Modified Fiber SERS Probe[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2800-2806. |
| [10] |
GUI Bo1, 2, YANG Yu-dong1, ZHAO Qian1, 2, SHI Meng1, MAO Hai-yang1, 3*, WANG Wei-bing1, CHEN Da-peng1, 3. A SERS Substrate for On-Site Detection of Trace Pesticide Molecules Based on Parahydrophobic Nanostructures[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2499-2504. |
| [11] |
SUN Ning, CHEN Jun-fan, ZHANG Jie*, ZHU Yong. The Forming Mechanism of Surface Morphology of Nanostructures and Its Effect on Graphene Raman Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1821-1827. |
| [12] |
ZHANG Can, ZHANG Jie*, DOU Xin-yi, ZHU Yong. Connection of Absorption and Raman Enhancement Characteristics of Different Types of Ag Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1816-1820. |
| [13] |
DOU Xin-yi, ZHANG Can, ZHANG Jie*. Effects of Process Parameters on Double Absorption Resonance Peaks of Au Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1446-1451. |
| [14] |
ZHANG Lei, ZHANG Xia*, WENG Yi-jin, LIU Xiao. Preparation and Properties of Ag/PANI Multifunction Nanozymes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3399-3403. |
| [15] |
TIAN Hui-yan1，LIU Yu1, HUANG Jiao-qi1, XIE Feng-xin1, HUANG Guo-rong1, LIAO Pu1, FU Wei-ling1, ZHANG Yang2*. Research Progress and Application of Surface-Enhanced Raman Scattering Technique in Nucleic Acid Detection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3021-3028. |
|
|
|
|
