| 光谱学与光谱分析 |
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| Study on Influence of pH on Interaction of Cucurbit[n=7,8]uril with Two Naphthylamine Isomers |
| ZENG Qi-hua,TAO Zhu*,XUE Sai-feng,ZHU Qian-jiang,MU Lan |
| Institute of Applied Chemistry，Guizhou University，Guiyang 550025, China |
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Abstract The interaction of cucurbit[n=7, 8]urils(Q[7], Q[8]) with two naphthylamine isomers and the influence of pH on the interaction were studied by using UV-Vis spectroscopy and 1H NMR technique. The experimental results revealed that Q[7] always forms a 1∶1 complex with the naphthylamine isomers respectively in the pH range (-0.3＜pH＜8) and the interaction of Q[7] with the title guests was not observed in the 8＜pH＜14 range. However, there are five interaction stages for Q[8]-naphthylamine isomer systems, no obvious interaction between the host Q[8] and the title naphthylamine guest(s) at the “highest” and the “lowest” pH (pH＞14 and pH＜-0.3 respectively); the Q[8] could include the guest with a 1∶1 ratio between the “highest” and a “higher” pH or the “lowest” and a “lower” pH (-0.3＜pH＜4 and 9.5＜pH＜14); between the higher and the lower pH (4＜pH＜9.5), the Q[8] includes the guest and forms a inclusion complex with 1∶2 ratio of host to guest.
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Received: 2006-06-16
Accepted: 2006-10-08
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Corresponding Authors:
TAO Zhu
E-mail: gzutao@263.net
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| Cite this article: |
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ZENG Qi-hua,TAO Zhu,XUE Sai-feng, et al. Study on Influence of pH on Interaction of Cucurbit[n=7,8]uril with Two Naphthylamine Isomers [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(09): 1826-1829.
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https://www.gpxygpfx.com/EN/Y2007/V27/I09/1826 |
[1] Freeman W A, Mock W L, Shih N Y. J. Am. Chem. Soc., 1981, 103(24): 7367.
[2] Kim J, Jung I S, Kim S Y, et al. J. Am. Chem. Soc., 2000, 122(3): 540.
[3] Day A I, Arnold A P. WO 0068232, 2000, 8.
[4] Day A I, Blanck R J, Amold A P, et al. Angew. Chem. Int. Ed., 2002, 41(2): 275.
[5] Jon S Y, Selvapalam N, Oh D H, et al. J. Am. Chem. Soc., 2003, 125(34): 10186.
[6] Lagona J, Fettinger J C, Isaacs L. Org. Letter, 2003, 5(20): 3745.
[7] Sindelar V, Moon K, Kaifer A E. Org. Letter, 2004, 6(16)∶2665.
[8] Wheate N, Day A I, Blanch R J, et al. Chem. Commun., 2004, (12): 1424.
[9] DU Ying, XUE Sai-feng, MU Lan, et al(杜 莹，薛赛凤，牟 兰，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2005，25(8)，1281.
[10] MU Lan, CHEN Xiao-kang, XUE Sai-feng, et al(牟 兰，陈小康，薛赛凤，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2004，24(11)，231.
[11] WANG Qiu-li, XUE Sai-feng, MU Lan, et al(王秋丽，薛赛凤，牟 兰，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2006，26(3)，499.
[12] Mitkina T V, Gerasko O A, Sokolov M N, et al. Russian Chemical Bulletin, 2004, 53(1): 80.
[13] Rita H M, Maxim S, Pedro E, et al. Dalton Transactions, 2004, (6): 847.
[14] Ko Y H, Kim K, Kang K K, et al. J. Am. Chem. Soc., 2004, 126(7): 1932.
[15] Kwangyul M, Jodi G, David S, et al. Angew. Chem. Int. Ed, 2004, 43: 5496.
[16] Park K M, Lee E, Roh S G, et al. Bulletin of the Korean Chemical Society, 2004, 25(11): 1711.
[17] Lee J W, Kim Kyungpim, Kim Kimoon. Chem. Commun., 2001, (11)：1042.
[18] Xu L, Liu S M, Wu C T, et al. Electrophoresis, 2004, 25(18-19): 3300.
[19] Rankin M A, Wagner B D. Supramolecular Chemistry, 2004, 16(7): 513. |
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