|
|
|
|
|
|
The Synthesis, Crystal Structure and Fluorescence Properties of Zinc Complex with 2-(3’,4’-Dicarboxyphenoxy) Benzoate |
LUO Li-lin, WANG Qiu-shuang, XIE Mei-ting, XI Yu-xin, LI Xia* |
Department of Chemistry, Capital Normal University, Beijing 100048, China |
|
|
Abstract In this paper, Zn (DPBA) (bpp) complex was synthesized with 2-(3’,4’-dicarboxyphenoxy) benzoate (DPBA) as the first ligand, and 1,3-bis (4-pyridyl)-propane (bpp) as the second ligand. The complex shows a one-dimensional chain structure, and its asymmetric unit includes one Zn(Ⅱ), one DPBA ligand and one bpp ligand. Zn(Ⅱ) ion is coordinated with four oxygen atoms and one nitrogen atom. The complex has good fluorescence property with a wide emission band appearing at 375 nm, which is the π*—π transition of the ligand. Compared with the fluorescence emission of the ligands, the emission peak of the complex is blue shifted, and the emission intensity is greatly enhanced. The fluorescence properties of the complex in common solvents and metal cations were also studied. Experimental results show that the influence of different small organic molecules or different metal cations on the fluorescence of the complex, small organic molecule nitrobenzene and Fe3+ make the fluorescence quenching of the complex. Thus, the complex can be used for the detection of nitrobenzene and Fe3+ ion in the water and ethanol system.
|
Received: 2017-03-24
Accepted: 2017-06-28
|
|
Corresponding Authors:
LI Xia
E-mail: xiali@cnu.edu.cn
|
|
[1] Coronado E, Minguez Espallargas G. Chem. Soc. Rev., 2013,42(4): 1525.
[2] Canivet J, Fateeva A, Guo Y, et al. Chem. Soc. Rev., 2014,43(16): 5594.
[3] Devic T, Serre C. Chem. Soc. Rev., 2014, 43(16): 6097.
[4] Ramaswamy P, Wong N E, Shimizu G K. Chem. Soc. Rev., 2014, 43(16): 5913.
[5] Liu K, Zhang X, Meng X, et al. Chem. Soc. Rev., 2016, 45(9): 2423.
[6] Gao R C, Guo F S, Bai N N, et al. Inorg. Chem., 2016, 55(21): 11323.
[7] Hao Jina, Yan Bing. Advanced Functional Materials, 2017, 27(6): 1603856.
[8] Chen L, Ye J W, Wang H P, et al. Nat. Commun., 2017,8: 15985.
[9] Tan Aidong, Wang Yifang, Fu Zhiyong, et al. Applied Catalysis B: Environmental, 2017,218: 260.
[11] Qu X L, Gui D, Zheng X L, et al. Dalton. Trans., 2016,45(16): 6983.
[12] LI Rui, FAN Ting-ting, QU Xiang-long, et al(李 睿, 樊婷婷, 屈相龙, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2016,36(8): 2522.
[13] Zhang L P, Ma J F, Yang J, et al. Inorg. Chem., 2010, 49: 1535.
[14] Guo J, Ma J F, Liu B, et al. Cryst. Growth. Des., 2011, 11: 3609. |
[1] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
[2] |
XIA Ming-ming1, 2, LIU Jia3, WU Meng1, 2, FAN Jian-bo1, 2, LIU Xiao-li1, 2, CHEN Ling1, 2, MA Xin-ling1, 2, LI Zhong-pei1, 2, LIU Ming1, 2*. Three Dimensional Fluorescence Characteristics of Soluble Organic Matter From Different Straw Decomposition Products Treated With Calcium Containing Additives[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 118-124. |
[3] |
GU Yi-lu1, 2,PEI Jing-cheng1, 2*,ZHANG Yu-hui1, 2,YIN Xi-yan1, 2,YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
[4] |
WANG Cai-ling1,ZHANG Jing1,WANG Hong-wei2*, SONG Xiao-nan1, JI Tong3. A Hyperspectral Image Classification Model Based on Band Clustering and Multi-Scale Structure Feature Fusion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 258-265. |
[5] |
HAN Xue1, 2, LIU Hai1, 2, LIU Jia-wei3, WU Ming-kai1, 2*. Rapid Identification of Inorganic Elements in Understory Soils in
Different Regions of Guizhou Province by X-Ray
Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 225-229. |
[6] |
LI He1, WANG Yu2, FAN Kai2, MAO Yi-lin2, DING Shi-bo3, SONG Da-peng3, WANG Meng-qi3, DING Zhao-tang1*. Evaluation of Freezing Injury Degree of Tea Plant Based on Deep
Learning, Wavelet Transform and Visible Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 234-240. |
[7] |
TIAN Fu-chao1, CHEN Lei2*, PEI Huan2, BAI Jie-qi1, ZENG Wen2. Study of Factors Influencing the Length of Argon Plasma Jets at
Atmospheric Pressure With Needle Ring Electrodes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3682-3689. |
[8] |
WANG Ling-juan, OU Quan-hong, YAN Hao, TANG Jun-qi*. Preparation and Catalytic Properties of Gold Nanoflowers[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3747-3752. |
[9] |
WANG Hong-jian1, YU Hai-ye1, GAO Shan-yun1, LI Jin-quan1, LIU Guo-hong1, YU Yue1, LI Xiao-kai1, ZHANG Lei1, ZHANG Xin1, LU Ri-feng2, SUI Yuan-yuan1*. A Model for Predicting Early Spot Disease of Maize Based on Fluorescence Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3710-3718. |
[10] |
CHENG Hui-zhu1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, MA Qian1, 2, ZHAO Yan-chun1, 2. Genetic Algorithm Optimized BP Neural Network for Quantitative
Analysis of Soil Heavy Metals in XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3742-3746. |
[11] |
SONG Yi-ming1, 2, SHEN Jian1, 2, LIU Chuan-yang1, 2, XIONG Qiu-ran1, 2, CHENG Cheng1, 2, CHAI Yi-di2, WANG Shi-feng2,WU Jing1, 2*. Fluorescence Quantum Yield and Fluorescence Lifetime of Indole, 3-Methylindole and L-Tryptophan[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3758-3762. |
[12] |
WANG Zhi-qiang1, CHENG Yan-xin1, ZHANG Rui-ting1, MA Lin1, GAO Peng1, LIN Ke1, 2*. Rapid Detection and Analysis of Chinese Liquor Quality by Raman
Spectroscopy Combined With Fluorescence Background[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3770-3774. |
[13] |
YI Min-na1, 2, 3, CAO Hui-min1, 2, 3*, LI Shuang-na-si1, 2, 3, ZHANG Zhu-shan-ying1, 2, 3, ZHU Chun-nan1, 2, 3. A Novel Dual Emission Carbon Point Ratio Fluorescent Probe for Rapid Detection of Lead Ions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3788-3793. |
[14] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
[15] |
LI Xiao-dian1, TANG Nian1, ZHANG Man-jun1, SUN Dong-wei1, HE Shu-kai2, WANG Xian-zhong2, 3, ZENG Xiao-zhe2*, WANG Xing-hui2, LIU Xi-ya2. Infrared Spectral Characteristics and Mixing Ratio Detection Method of a New Environmentally Friendly Insulating Gas C5-PFK[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3794-3801. |
|
|
|
|