| 光谱学与光谱分析 |
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| Study on Preparation Mechanism of Decanoic Acid-Palmitic Acid/SiO2 Phase Change and Humidity Storage Composite Materials by Fourier Transform Infrared Spectrum |
| SHANG Jian-li，ZHANG Hao*，XIONG Lei，MA Xiang-long |
| College of Materials & Mineral Resources, Xi’an University of Architecture and Technology, Xi’an 710055, China |
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Abstract According to the research achievements of phase change and humidity storage composite materials preparation in early stage, SiO2-based phase change and humidity storage composite materials were made by sol-gel method with SiO2 as the carrier and decanoic acid-palmitic acid as a phase change material in this paper. Synthetic materials in every stage of preparation process of decanoic acid-palmitic acid/SiO2 phase change and humidity storage composite materials were measured by Fourier transform infrared spectrum，such as phase change material preparation stage, SiO2 carrier material preparation stage and decanoic acid-palmitic acid/SiO2 phase change and humidity storage composite materials preparation stage. In the process of decanoic acid-palmitic acid/SiO2 phase change and humidity storage composite materials preparation, SiO2 network structure forming mechanism, decanoic acid-palmitic acid embed mode, chimeric mechanism of SiO2 and decanoic acid-palmitic acid were researched, respectively, in order to explain the mechanism of how to prepare decanoic acid-palmitic acid/SiO2 phase change and humidity storage composite materials by sol-gel method. Meanwhile, material composition and micro topography of decanoic acid-palmitic acid/SiO2 phase change and humidity storage composite materials were tested by X-ray diffracmeter and scanning electron microscope, so as to provide evidence about preparation mechanism of decanoic acid-palmitic acid/SiO2 phase change and humidity storage composite materials. The results showed that decanoic acid-palmitic acid is packed in a large number of closed pores or cages which were formed through breaking and restructuring of Si—O—Si groups; then, decanoic acid-palmitic acid/SiO2 phase change and humidity storage composite materials can be prepared based on those mentioned above. Decanoic acid-palmitic acid and SiO2 are only physical chimeric to each other, without any chemical reaction in the preparation process of decanoic acid-palmitic acid/SiO2 phase change and humidity storage composite materials. A large number of closed pores or cages are formed by SiO2 in acid-palmitic acid/SiO2 phase change and humidity storage composite materials, of which one part is used for coating decanoic acid-palmitic acid with phase change thermal control performance, and the other part is used for network space structure with humidity storage humidity control performance, in order to achieve the purpose of adjusting indoor temperature and humidity at the same time.
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Received: 2015-04-13
Accepted: 2015-08-10
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Corresponding Authors:
ZHANG Hao
E-mail: fengxu19821018@163.com
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[1] Rao Z H, Wang S F, Zhang Z G. Renewable and Sustainable Energy Reviews, 2012, 16(5): 3136.
[2] Deng A Z, Li S B, Zhuang C L, et al. Journal of Building Materials, 2008, 11(5): 541.
[3] Li B X, Liu T X, Hu L Y, et al. Acs Sustainable Chemistry & Energy, 2013, 1(3): 374.
[4] Fang G Y, Chen Z, Li H. Chemical Engineering Journal, 2010, 163(1-2): 154.
[5] ZHANG Hong, WU Xiao-hua, WANG Xiao-lei, et al(张 鸿，武晓华，王晓磊，等). Journal of Materials Science and Engineering(材料科学与工程学报), 2010, 28(5): 672.
[6] ZHANG Yi, ZHANG Xiao-song(张 奕，张小松). Acta Energiae Solaris Sinica(太阳能学报), 2006, 27(7): 725.
[7] WU Fang, XU Ren-chong, YANG Chang-hui(吴 芳，徐仁崇，杨长辉). Journal of Wuhan University of Technology(武汉理工大学学报)，2009, 31(7): 134.
[8] SHANG Jian-li, ZHANG Hao, DONG Li, et al(尚建丽，张 浩，董 莉，等). Chinese Journal of Materials Research(材料研究学报), 2015, 29(2): 135.
[9] SHANG Jian-li, ZHANG Hao, DONG Li, et al(尚建丽，张 浩，董 莉，等). Functional Materials(功能材料), 2015, 46(2): 2084.
[10] SHANG Jian-li, ZHANG Hao, XIONG Lei, et al(尚建丽，张 浩，熊 磊，等). Journal of Materials Engineering(材料工程), 2015, 43(9): 94.
[11] MENG Duo, WANG Li-jiu(孟 多，王立久). Journal of Building Materials(建筑材料学报), 2013, 16(1): 91.
[12] FU Lu-jun, DONG Fa-qin, YANG Yu-shan, et al(付路军，董发勤，杨玉山，等). Functional Materials(功能材料), 2013, 44(4): 1. |
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