| 光谱学与光谱分析 |
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| Research on Scattering in the THz Quantitative Analysis |
| LI Zhi1, 2, LIAN Fei-yu1, 2 |
| 1. College of Information Science and Engineering, Henan University of Technology, Zhengzhou 450001, China2. Key Laboratory of Grain Information Processing and Control(Henan University of Technology), Ministry of Education, Zhengzhou 450001, China |
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Abstract Quantitative analysis of mixture samples’ components based on terahertz absorption spectra is one of the most important applications of THz technology. As is known to all, when the THz wave irradiates into samples, it will be scattered by the sample particles in the microscale, which is known as scattering. So THz absorption spectra of the experimental obtained samples are basically composed of two parts, samples’ intrinsic absorption of THz wave and the scattering. Especially when particles’grain size of the samples is near or comparable to the THz wavelength, the scattering is so significant that it cannot be ignored. However, the scattering was always not taken into account while only the Lambert-Beer law was used in THz quantitative analysis, in which the absorption of light was described as linearly related with the material’s concentration. As a result, the accuracy was restricted. In this paper, the scattering in THz band was analyzed and absorption spectrum model of mixed sample’s THz was proposed. A series of quantitative analysis experiments proved the validity of this model. Through the comparision with the traditional method, the accuracy of the quantitative analysis was improved and the errors were basically below 3%. This research proved that scattering is important to improve the accuracy of THz quantitative analysis.
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Received: 2015-03-11
Accepted: 2015-07-23
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Corresponding Authors:
LI Zhi
E-mail: lizhi@haut.edu.cn
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[1] Busch S F, Weidenbach M, Fey M, et al. Journal of Infrared Millimeter and Terahertz Waves, 2014, 35(12): 993.
[2] Neumaier P F X, Schmalz K, Borngraeber J, et al. Analyst, 2015, 140(1): 213.
[3] Bawuah P, Silfsten P, Ervasti T, et al. International Journal of Pharmaceutics, 2014, 476(1-2): 16.
[4] Reid C B, Reese G, Gibson A P, et al. IEEE Transactions on Terahertz Science and Technology, 2013, 3(4): 363.
[5] ZHANG Zhao-hui, Lü Luo-dong, YIN Yi-xin, et al(张朝晖，吕洛冬，尹怡欣，等). Journal of Analytical Science(分析科学学报), 2007, 23(6): 651.
[6] CHEN Tao, LI Zhi, MO Wei, et al(陈 涛, 李 智, 莫 玮, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2014, 34(12): 3241.
[7] Spangenberg B, Poole C F, Weins C. Quantitative Thin-Layer Chromatography: a Practical Survey. Berlin: Springer Verlag Berlin Heideberg, 2011.
[8] Franz M, Fischer B M, Walther M. Applied Physics Letters, 2008, 92: 021107.
[9] Kaushik M, Ng B W H, Fischer B M, et al. Applied Physics Letters, 2012, 100: 011107.
[10] Schecklman S, Zurk L M, Henry S, et al. Journal of Applied Physics, 2011, 109: 094902.
[11] LI Zhi, ZHANG Zhao-hui, Zhao Xiao-yan, et al(李 智, 张朝晖, 赵小燕, 等). Applied Optics, 2012, 51(20): 4879. |
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