增强型太阳能电池用Ce<SUP>3+</SUP>/Tb<SUP>3+</SUP>掺杂碱土硼酸盐玻璃

doi:10.3964/j.issn.1000-0593(2015)12-3291-05

Abstract
References
Related Citation (15)

Download: PDF (2099 KB)
Export: BibTeX | EndNote (RIS)

Abstract Ce³⁺ and Tb³⁺ doped alkaline earth borate (LKZBSB) glasses and the photoluminescence properties of glass system have been fabricated and investigated, and the observed violet and green fluorescences are originated from Ce³⁺ and Tb³⁺ emitting centers, respectively. Four emission bands peaked at 487, 543, 586 and 621 nm are attributed to the emission transitions ⁵D₄→⁷F₆, ⁵D₄→⁷F₅, ⁵D₄→⁷F₄ and ⁵D₄→⁷F₃ of Tb³⁺, respectively, and consists of a broad emission band peaking at 389 nm attributed to 5d→4f electric dipole allowed transition of Ce³⁺. With the introduction of Ce³⁺, the effective excitation wavelength range of Tb³⁺ in LKZBSB glasses are remarkably expanded, and the enhanced factor of green fluorescence of Tb³⁺ in Ce³⁺/Tb³⁺ co-doped LKZBSB glasses is up to 73 times in medium-wavelength ultraviolet (UVB) excitation region, compared with that in Tb³⁺ single-doped case. The results show that the conversion from ultraviolet (UV) radiation to visible light is efficient in Ce³⁺/Tb³⁺ doped LKZBSB glasses, demonstrating that the glasses have potential values in developing enhanced solar cell as a conversion layer.

Key words：Ce³⁺/Tb³⁺ doping;alkaline earth borate glasses;radiation conversion;enhanced solar cell

Received: 2014-09-16 Accepted: 2014-12-20

ZTFLH:	O433
	TQ171

Corresponding Authors: YANG Peng E-mail: lhai@dlpu.edu.cn

Cite this article:

YANG Peng,ZHAO Xin,WANG Zhi-qiang, et al. Ce³⁺/Tb³⁺ Doped Alkaline-Earth Borate Glasses Employed in Enhanced Solar Cells [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(12): 3291-3295.

URL:

https://www.gpxygpfx.com/EN/10.3964/j.issn.1000-0593(2015)12-3291-05 OR https://www.gpxygpfx.com/EN/Y2015/V35/I12/3291

[1] Liu L, Peter Y Y, Chen X B, et al. Phys. Rev. Lett., 2013, 111(6): 065505.
[2] Liu Y, Wang H, Shen H, et al. Appl. Energ., 2010, 87(2): 436.
[3] Gao C T, Li X D, Wang Y Q, et al. J. Power Sources, 2013, 239: 458.
[4] Liu C Y, Chen H, Zhao D, et al. Appl. Phys. Lett., 2014, 105(5): 053301.
[5] Tian Y, Tian B N, Chen B J, et al. Mater. Res. Bull., 2014, 53(0): 38.
[6] Liu L L, Wang Q, Gao C J, et al. J. Phys. Chem. C , 2014, 118(26): 14511.
[7] Qi J N, Xu Y S, Huang F, et al. J. Am. Ceram. Soc., 2014, 97(5): 1471.
[8] Xue H Y, Xu Z Q, Zhang M Q, et al. J. Plast. Film Sheet., 2015, 31(3): 233.
[9] Tian Q W, Wang G, Zhao W G, et al. Chem. Mater., 2014, 26(10): 3098.
[10] Liu Y L, Song F, Liu J D, et al. Chem. Phys. Lett., 2013, 565: 98.
[11] Lian H Z, Hou Z Y, Shang M M, et al. Energy, 2013, 57: 270.
[12] Liu J, Yao Q, Li Y. Appl. Phys. Lett., 2006, 88(17): 17311.
[13] Liu R, Qiang L S, Yang W D, et al. J. Power Sources, 2013, 223: 254.
[14] Zhang Y, Wang R Z, Xiao S G, et al. J. Lumin., 2014, 145: 351.
[15] Jia S J, Huang L H, Ma D L, et al. J. Lumin., 2014, 152: 241.
[16] Xiang G T, Zhang J H, Hao Z D, et al. Phys. Chem. Chem. Phys., 2014, 16(20): 9289.
[17] Zhou J J, Teng Y, Ye S, et al. Chem. Phys. Lett., 2010, 486: 116.
[18] Zhang M, Zhang J, Fan Y, et al. Energy Environ. Sci., 2013, 6(10): 2939.
[19] Zhang C M, Li C X, Peng C, et al. Chem. Eur. J., 2010, 16(19): 5672.
[20] Wang Y H, Brik M G, Dorenbos P, et al. J. Phys. Chem. C, 2014, 118(13): 7002.
[21] Xue X J, Wang L L, Huang L J, et al. Cryst. Eng. Comm., 2013, 15(15): 2897.
[22] Zhou J J, Chen G X, Wu E, et al. Nano. Lett., 2013, 13(5): 2241.
[23] Lin H, Chen D Q, Yu Y L, et al. Appl. Phys. Lett., 2013, 103(9): 091902.
[24] Shen Y L, Zhang Q, Cheng J M, et al. Mater. Lett., 2013, 97: 151.
[25] Li Y, Yu Q L, Huang L, et al. Opt. Mater. Express, 2014, 4(2): 227.
[26] Yuan J L, Zeng X Y, Zhao J T, et al. J. Phys. D: Appl. Phys., 2008, 41(10): 105406.
[27] Chen D Q, Yu Y L, Huang P, et al. Appl. Phys. Lett., 2009, 94(4): 041909.
[28] Xia Z G, Liu R S. J. Phys. Chem. C, 2012, 116(29): 15604.
[29] He D B, Yu C L, Cheng J M, et al. J. Alloys Compd., 2011, 509(5): 1906.