光谱学与光谱分析 |
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The Thiacalix[4]arene-Coumarin Fluorescence Probe Recognition for Fe3+ and Bovine Hemoglobin |
LI Yan-qin1, MU Lan1, ZENG Xi1*, LI Jun1, Takehiko Yamato2 |
1. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China 2. Department of Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi 1, Saga 840-8502, Japan |
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Abstract 1,3-alternate coumarin substituted thiacalix[4]arene fluorescent probe 1 was synthesised from 1,3-alternate diethyl thiacalix[4]arene and 7-hydroxycoumarin by-step reactions. In DMSO/H2O (φ, 3/7, pH 7) solution, the strong fluorescence emission and UV absorption of probe 1 can be selectively quenched or significantly enhanced by Fe3+ ion. The probe 1 showed high Fe3+ selective fluorescence quenching or absorption enhancement over commonly coexistent metal ions in neutral aqueous media, and the limit of detections were obtained as low as 10-8 mol·L-1 of Fe3+ by fluorescence and absorption spectrometry. Spectral titration, isothermal titration calorimetry and mass spectrometry were showed that probe and Fe3+ form 1∶1 complexes, the constant up to 105 L·mol-1 and coordinate process was spontaneous by the mole binding free energy and entropy of probe with Fe3+. In addition, the probe can identification bovine hemoglobin (BHb) over other proteins through quenched its fluorescence in DMSO/H2O (φ,1/9,Tris-HCl,pH 7,0.1 mol·L-1 NaCl) media. The limit of detection was obtained as 0.12 μg·mL-1 of BHb, as well as a linearity of 0.2~3.0 μg·mL-1, indicating the probe of high sensitivity and quantitation range. It can be used as a selective recognition Fe3+ and BHb of thiacalix[4] arene fluorescent probe.
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Received: 2014-06-13
Accepted: 2014-11-22
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Corresponding Authors:
ZENG Xi, Takehiko Yamato
E-mail: sci.lmou@gzu.edu.cn
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