| 光谱学与光谱分析 |
|
|
|
|
|
| Study on Chemical Kinetic Effect of Dielectric Barrier Discharge Plasma |
| ZHANG Peng, HONG Yan-ji*, SHEN Shuang-yan, DING Xiao-yu, MADi |
| State Key Laboratory of Laser Propulsion & Application, Equipment Academy, Beijing 101416, China |
|
|
|
|
Abstract To reveal the mechanism of plasma (assisted the ignition process of methane/air further, schematic of dielectric barrier discharge plasma system with atmospheric air was designed and set up, the emission spectrum of dielectric barrier discharge plasma with atmospheric air was measured, and the active particles produced by the interaction of dielectric barrier discharge plasma with atmospheric air were analyzed with the spectrum technology, the ignition model and calculation methods of sensitivity analysis and reaction path analysis were given, effects of NO and O3 on the ignition delay time were simulated, and the chemical kinetics mechanism of NO andO3 assisted ignition was revealed via sensitivity analysis and reaction path analysis. The results show that main excited particles of N2 and O3 are generated via effect of plasma on the atmospheric air, which are converted into active particles of NOx and O3 in the end, the life of which are longer than any other active particles, effects of plasma on the ignition is simplified as effects of NOx and O3on the ignition; NOand O3 could reduce the ignition delay time significantly, but the amplitudedecrease with increase of the initial temperature, this is because the rate ofignition is decided by the oxidation rate of CH3, the oxidized pathway of CH3 is R155 and R156 for auto-ignition and their rates are slower whentemperature is low, so the ignition delay time of methane/air is longer; NO could reduce the ignition delay time significantly because of the oxidized pathway of CH3 is changed to R327 CH3O2+NO=CH3O+NO2, R328 CH3+NO2=CH3O+NO for NOx(assisted ignition process from R155 and R156 for auto-ignition; and the chemical kinetic effect is the dominating factor of O3 on the ignition and which change the reaction path.
|
|
Received: 2014-01-06
Accepted: 2014-04-26
|
|
|
|
Corresponding Authors:
HONG Yan-ji
E-mail: hongyanji@vip.sina.com
|
|
[1] Dumitrasc U. Plasma Sources Science and Technology, 2002, 11(2): 125.
[2] GAO Xu-dong, SUN Bao-min, XIAO Hai-ping, et al(高旭东, 孙保民, 肖海平, 等). Proceedings of the CSEE(中国电机工程学报), 2010, 30(11): 27.
[3] Laroussi M, Alexeff I, Kang W L. IEEE Trams. Plasma Sci., 2000, 28(1): 184.
[4] Starikovskii A Yu. Superfast Homogeneous Plasma Ignition of Hydrogen and Air-Fuel Supersonic Flows by High-Voltage Ionization Wave. First Stage Report, 01.01.1999-15.12.1999.
[5] Starikovskaia S M. Kinetics in Gas Mixtures for Problem of Plasma Assisted Combustion. AFRL-AFOSR-UK-TR-2010-0009.
[6] Inomata T, Okazaki S, Moriwaki T, et al. Combustion and Flame, 1983, 50: 361.
[7] Starikovskaya S M, Kukaev E N, Kuksin A Y. Combustion and Flame, 2004, 139(3): 177.
[8] Starik A M, Titova N S. Combustion, Explosion, and Shock Waves, 2005, 40(5): 499.
[9] Randonnier A V, Larigaldie S, Magre P, Nikov V S. IEEE Transactions on Plasmas Science, 2007, 35(2): 223.
[10] XIE Wei-jie, LI Long-hai, ZHOU Bao-xue, et al(谢维杰, 李龙海, 周保学, 等). Acta Phys.-Chim. Sin.(物理化学学报), 2008, 24(5): 827.
[11] Dieke G H, Babcock H D. Proceedings of the National Academy of Sciences of the United States of America, 1927, 13(9): 670.
[12] Ombrello T, Won S H, Ju Y G, et al. 47th AIAA paper, 2009-689.
[13] Kee R J, Rupley F M, Miller J A. CHEMKIN-Ⅲ: A Fortran ChemicalKinetics Package for the Analysis of Gas-Phase Chemical and Plasma Kinetics. 1996, UC-405, SAND96-8216.
[14] Brown P D, Byrne G D, Hindmarsh A C. SIAM Journal on Scientific and Statistical Computing, 1989, 10(5): 1038.
[15] Takita K, Abe N, Masuya G, et al. Proceedings of the Combustion Institute, 2007, 31(2): 2489.
[16] Ombrello T, Won S H, Ju Y G, et al. Combustion and Flame, 2010, 157: 1906.
[17] Ibraguimova L B, Smekhov G D, Shatalov O P. Institute of Mechanics of Lomonosov Moscow State University, Moscow, 2003.
[18] GUO Peng, CHEN Zheng(郭 鹏, 陈 正). Journal of Combustion Science and Technology(燃烧科学与技术), 2010, 16(5): 472. |
| [1] |
FAN Ping-ping，LI Xue-ying，QIU Hui-min，HOU Guang-li，LIU Yan*. Spectral Analysis of Organic Carbon in Sediments of the Yellow Sea and Bohai Sea by Different Spectrometers[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 52-55. |
| [2] |
YANG Chao-pu1, 2, FANG Wen-qing3*, WU Qing-feng3, LI Chun1, LI Xiao-long1. Study on Changes of Blue Light Hazard and Circadian Effect of AMOLED With Age Based on Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 36-43. |
| [3] |
BAO Hao1, 2，ZHANG Yan1, 2*. Research on Spectral Feature Band Selection Model Based on Improved Harris Hawk Optimization Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 148-157. |
| [4] |
LIANG Shou-zhen1, SUI Xue-yan1, WANG Meng1, WANG Fei1, HAN Dong-rui1, WANG Guo-liang1, LI Hong-zhong2, MA Wan-dong3. The Influence of Anthocyanin on Plant Optical Properties and Remote Sensing Estimation at the Scale of Leaf[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 275-282. |
| [5] |
TIAN Fu-chao1, CHEN Lei2*, PEI Huan2, BAI Jie-qi1, ZENG Wen2. Study of Factors Influencing the Length of Argon Plasma Jets at
Atmospheric Pressure With Needle Ring Electrodes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3682-3689. |
| [6] |
LI Qi-chen1, 2, LI Min-zan1, 2*, YANG Wei2, 3, SUN Hong2, 3, ZHANG Yao1, 3. Quantitative Analysis of Water-Soluble Phosphorous Based on Raman
Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3871-3876. |
| [7] |
LIANG Jin-xing1, 2, 3, XIN Lei1, CHENG Jing-yao1, ZHOU Jing1, LUO Hang1, 3*. Adaptive Weighted Spectral Reconstruction Method Against
Exposure Variation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3330-3338. |
| [8] |
LIU Hong-wei1, FU Liang2*, CHEN Lin3. Analysis of Heavy Metal Elements in Palm Oil Using MP-AES Based on Extraction Induced by Emulsion Breaking[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3111-3116. |
| [9] |
LIU Pan1, 2, 3, DU Mi-fang1*, LI Bin1, LI Jing-bin1, ZENG Lei1, LIU Guo-yuan1, ZHANG Xin-yao1, 4, ZHA Xiao-qin1, 4. Determination of Trace Tellurium Content in Aluminium Alloy by
Inductively Coupled Plasma-Atomic Emission Spectrometry Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3125-3131. |
| [10] |
ZHU Yu-qi1, 2, ZHANG Xin2, DU Pan-pan2, LIU Shu1, ZHANG Gui-xin1, 2, GUAN Song-lei2*, ZHENG Zhong1*. Infrared Spectroscopy and X-Ray Spectroscopy Combined With
Inductively Coupled Plasma Mass Spectrometry for Quality
Control of Mongolian Medicine Yu Grain Soil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3163-3169. |
| [11] |
MA Qian1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, CHENG Hui-zhu1, 2, ZHAO Yan-chun1, 2. Research on Classification of Heavy Metal Pb in Honeysuckle Based on XRF and Transfer Learning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2729-2733. |
| [12] |
HUANG Chao1, 2, ZHAO Yu-hong1, ZHANG Hong-ming2*, LÜ Bo2, 3, YIN Xiang-hui1, SHEN Yong-cai4, 5, FU Jia2, LI Jian-kang2, 6. Development and Test of On-Line Spectroscopic System Based on Thermostatic Control Using STM32 Single-Chip Microcomputer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2734-2739. |
| [13] |
YANG Fan1, HAO Liu-cheng1, KE Wei2, LIU Qing1, WANG Jun1, CHEN Min-yuan2, YUAN Huan2*, YANG Ai-jun2, WANG Xiao-hua2, RONG Ming-zhe2. Research on Effect of Laser Incident Angle on Laser-Induced Plasma at Low Pressure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2740-2746. |
| [14] |
ZHENG Yi-xuan1, PAN Xiao-xuan2, GUO Hong1*, CHEN Kun-long1, LUO Ao-te-gen3. Application of Spectroscopic Techniques in Investigation of the Mural in Lam Rim Hall of Wudang Lamasery, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2849-2854. |
| [15] |
WANG Jun-jie1, YUAN Xi-ping2, 3, GAN Shu1, 2*, HU Lin1, ZHAO Hai-long1. Hyperspectral Identification Method of Typical Sedimentary Rocks in Lufeng Dinosaur Valley[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2855-2861. |
|
|
|
|
