| 光谱学与光谱分析 |
|
|
|
|
|
| Study on Styrene Derivatives with Stilbene-Like Pendant: Synthesis and the Fluorescence Properties |
| YE Zhen-xing,XIA Xue-wei*,LU Jian-mei |
| Chemistry Department of Suzhou University, Suzhou 215123, China |
|
|
|
|
Abstract A series of styrene derivatives with stilbene-like pendant were synthesized through heterogeneous Wittig reaction of triphenyl-(4-vinyl)-benzylphosphornium chloride with aromatic aldehydes. The substituted styrenic monomer, 4-(2-aryl)-vinyl-styrene, was strongly photoluminescent in solution and in solid state. Introduced electron-pushing substituents and lengthened conjugation both enhanced the emission intensity and led to a red shift of emission bands, with the maximum emission wavelength shifted from 378 to 494 nm. The fluorescece quantum efficiencies were determined by employing quinine sulfate as reference; and 4-(2-anthryl)-vinyl-styrene (AVS) possessed the highest quantum efficiency(λ=494 nm, Фf=0.635).
|
|
Received: 2007-03-06
Accepted: 2007-06-12
|
|
|
|
Corresponding Authors:
XIA Xue-wei
E-mail: xiaxuewei@suda.edu.cn
|
|
[1] Adachi C, Tokito S, Tsutsui T, et al. Jpn. J. Appl. Phys., 1988, 27(2): L269.
[2] Adachi C, Tsutsui T, Saito S. Appl. Phys. Lett., 1989, 55(15): 1489.
[3] Adachi C, Tsutsui T, Saito S. Appl. Phys. Lett., 1990, 56(9): 799.
[4] Tang C W, Van Slyke S A. Appl. Phys. Lett., 1987, 51(12): 913.
[5] Kido J, Khoda M, Okuyama K, et al. Appl. Phys. Lett., 1992, 61(7): 761.
[6] Kido J, Hongavwa K, Khoda M, et al. Jpn. J. Appl. Phys., 1992, 31(7B): L960.
[7] Leni Akcelrud. Prog. Polym. Sci., 2003, 28: 875.
[8] Andersson M R, Heeger A J, Yu G. Synth. Metals, 1997, 85(1-3): 1275.
[9] Byun H Y, Chung I J, Shim H K. Macromolecules, 2004, 37(18): 6945.
[10] Yang Z, Hu B, Karasz F E. J. Macromol. Sci., Part A: Pure Appl. Chem., 1998, 35(2): 233.
[11] Hu B, Yang Z, Karasz F E. J. Appl. Phys., 1994, 76(4): 2419.
[12] Willner I, Nakhmanovich G, Gorelik V, et al. J. Appl. Phys., 1993, 74(5): 3584.
[13] Hu B, Morton D C, Sokolik I, et al. J. Lumin., 1994, 60-61: 919.
[14] Hochfilzer C, Tasch S, Winkler B, et al. Synth. Metal, 1997, 85: 1271.
[15] Aguiar M, Hu B, Karasz F E, et al. Macromolecules, 1996, 29(9): 3161.
[16] Hesemann P, Vestweber H, Pommerehne J, et al. Adv. Mater., 1995, 7(4): 388.
[17] Sander R, Stumpflen V, Wendorff J H, et al. Macromolecules, 1996, 29(24): 7705.
[18] Bouche' C M, Berdague' P, Facoetti H, et al. Synth. Metals, 1996, 81: 191.
[19] Lee J K, Hwang D H, Hwang J, et al. Synth Metals, 2000, 111: 489.
[20] Chung S J, Jin J, Kim K K. Advanced Mater., 1997, 9(7): 551.
[21] Campaigne E, Wesley L. Archer，J. Am. Chem. Soc., 1953, 75(4): 989.
[22] John Boutagy, Richard Thomas. Chem. Rev., 1974, 74(1): 87.
[23] Piechucki C. Synthesis, 1976, (3): 187.
[24] Durantini E N. Synth. Commun., 1999, 29(23): 4201.
[25] Dupin Jee, Chenault J. Synth. Commun., 1985, 15(7): 581.
[26] Angelina Altomare, Carlo Carlini, Mario Panattoni, et al. Macromolecules，1984，17（11）：2207.
[27] Mikolajczyk M, Grzejszczak S, MIDURA W. Synthesis，1976，(6): 396.
[28] Chen Chin-Ti. Chem. Mater., 2004, 16(23): 4389.
[29] LIU Jun-feng, TENG Feng, XU Zheng, et al(刘峻峰, 滕 枫, 徐 征, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(5): 519.
[30] JIN Zheng-neng, LU Jian-mei, XU Qing-feng, et al(金正能，路建美，徐庆峰，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2006，26（9）：1644. |
| [1] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
| [2] |
XIA Ming-ming1, 2, LIU Jia3, WU Meng1, 2, FAN Jian-bo1, 2, LIU Xiao-li1, 2, CHEN Ling1, 2, MA Xin-ling1, 2, LI Zhong-pei1, 2, LIU Ming1, 2*. Three Dimensional Fluorescence Characteristics of Soluble Organic Matter From Different Straw Decomposition Products Treated With Calcium Containing Additives[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 118-124. |
| [3] |
GU Yi-lu1, 2，PEI Jing-cheng1, 2*，ZHANG Yu-hui1, 2，YIN Xi-yan1, 2，YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
| [4] |
HAN Xue1, 2, LIU Hai1, 2, LIU Jia-wei3, WU Ming-kai1, 2*. Rapid Identification of Inorganic Elements in Understory Soils in
Different Regions of Guizhou Province by X-Ray
Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 225-229. |
| [5] |
LIU Wei1, 2, ZHANG Peng-yu1, 2, WU Na1, 2. The Spectroscopic Analysis of Corrosion Products on Gold-Painted Copper-Based Bodhisattva (Guanyin) in Half Lotus Position From National Museum of China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3832-3839. |
| [6] |
WANG Hong-jian1, YU Hai-ye1, GAO Shan-yun1, LI Jin-quan1, LIU Guo-hong1, YU Yue1, LI Xiao-kai1, ZHANG Lei1, ZHANG Xin1, LU Ri-feng2, SUI Yuan-yuan1*. A Model for Predicting Early Spot Disease of Maize Based on Fluorescence Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3710-3718. |
| [7] |
CHENG Hui-zhu1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, MA Qian1, 2, ZHAO Yan-chun1, 2. Genetic Algorithm Optimized BP Neural Network for Quantitative
Analysis of Soil Heavy Metals in XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3742-3746. |
| [8] |
SONG Yi-ming1, 2, SHEN Jian1, 2, LIU Chuan-yang1, 2, XIONG Qiu-ran1, 2, CHENG Cheng1, 2, CHAI Yi-di2, WANG Shi-feng2，WU Jing1, 2*. Fluorescence Quantum Yield and Fluorescence Lifetime of Indole, 3-Methylindole and L-Tryptophan[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3758-3762. |
| [9] |
WANG Zhi-qiang1, CHENG Yan-xin1, ZHANG Rui-ting1, MA Lin1, GAO Peng1, LIN Ke1, 2*. Rapid Detection and Analysis of Chinese Liquor Quality by Raman
Spectroscopy Combined With Fluorescence Background[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3770-3774. |
| [10] |
YI Min-na1, 2, 3, CAO Hui-min1, 2, 3*, LI Shuang-na-si1, 2, 3, ZHANG Zhu-shan-ying1, 2, 3, ZHU Chun-nan1, 2, 3. A Novel Dual Emission Carbon Point Ratio Fluorescent Probe for Rapid Detection of Lead Ions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3788-3793. |
| [11] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
| [12] |
QI Guo-min1, TONG Shi-qian1, LIN Xu-cong1, 2*. Specific Identification of Microcystin-LR by Aptamer-Functionalized Magnetic Nanoprobe With Laser-Induced Fluorescence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3813-3819. |
| [13] |
HE Yan-ping, WANG Xin, LI Hao-yang, LI Dong, CHEN Jin-quan, XU Jian-hua*. Room Temperature Synthesis of Polychromatic Tunable Luminescent Carbon Dots and Its Application in Sensitive Detection of Hemoglobin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3365-3371. |
| [14] |
LIN Hong-jian1, ZHAI Juan1*, LAI Wan-chang1, ZENG Chen-hao1, 2, ZHAO Zi-qi1, SHI Jie1, ZHOU Jin-ge1. Determination of Mn, Co, Ni in Ternary Cathode Materials With
Homologous Correction EDXRF Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3436-3444. |
| [15] |
LI Xiao-li1, WANG Yi-min2*, DENG Sai-wen2, WANG Yi-ya2, LI Song2, BAI Jin-feng1. Application of X-Ray Fluorescence Spectrometry in Geological and
Mineral Analysis for 60 Years[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 2989-2998. |
|
|
|
|
