| 光谱学与光谱分析 |
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| The Synthesis and Luminescence Measurement of YAG∶Ce3+ Phosphors by High Temperature Solid Phase Method |
| TONG Yi-ping, CHEN Teng |
| Department of Chemical Engineering, Huizhou University, Huizhou 516007, China |
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Abstract YAG∶Ce3+ luminescence materials were prepared by a high-temperature solid state method. Different influencing factors, e.g., the doping amount of Ce3+, sintering temperature, and sintering time, were investigated by the orthogonal experiment method. The results showed that: (1) the influence of three factors on light-emitting intensity of YAG∶Ce3+ phosphors is in the following order, sintering temperature>>sintering time>the doping amount of Ce3+; (2) the optimum conditions for YAG∶Ce3+ phosphors are: sintering temperature 1 600 ℃, the doping amount of Ce3+ 0.10 mol, and sintering time 4 h. Under these conditions, the light-emitting intensity of YAG∶Ce3+ phosphors prepared is the largest. Furthermore, another optimum conditions are: sintering temperature 1 600 ℃, the doping amount of Ce3+ 0.08 mol, and sintering time 4 h, and the YAG∶Ce3+ phosphors prepared are also excellent based on them. The transition properties and spectral features of excitation and luminescence spectra of these synthesized phosphors were analyzed in detail and assigned as Ce3+ 4f—5d transition.
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Received: 2013-01-24
Accepted: 2013-04-15
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Corresponding Authors:
TONG Yi-ping
E-mail: typ2469@163.com
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[1] Pan Y, Wu M, Su Q. Journal of Physics and Chemistry of Solids, 2004, 65: 845.
[2] WU Hao, PAN Yue-xiao, GUO Chong-feng, et al(吴 昊, 潘跃晓, 郭崇峰, 等). Chinese Journal of Luminescence(发光学报), 2006, 27(2): 201.
[3] Jiao H, Ma Q, He L, et al. Powder Technology, 2010, 198(2): 229.
[4] Purwanto A, Wang W N, Ogi T, et al. Journal of Alloys and Compounds, 2008, 463(1–2): 350.
[5] WANG Hai-bo, ZHU Xian-zhong, REN Ju-guang(王海波, 朱宪忠, 任巨光). China Light & Lighting(中国照明电器), 2004, (5): 1.
[6] Kang Y C, Lenggoro I W, Park S B, et al. Materials Research Bulletin, 2000, 35: 789.
[7] Yamada M, Narukawa Y, Tamaki H, et al. Ieice Trans. Electron., 2005, E88-C(9): 1860.
[8] ZHOU Zhou, FENG Shi-wei, GUO Chun-sheng, et al(周 舟，冯士维，郭春生，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2012, 32(10): 2611.
[9] ZHANG Xu-dong, XU Guo-gang, WU Zuo-gui, et al(张旭东, 徐国纲, 吴作贵, 等). Rare Metal Materials and Engineering(稀有金属材料与工程), 2009, 38: 75.
[10] LI Xia, LIU Hong, WANG Ji-yang, et al(李 霞, 刘 宏, 王继扬, 等). Journal of Inorganic Materials(无机材料学报), 2004, 19(5): 1169.
[11] Gao W, Hu Y, Zhuang W, et al. Journal of Rare Earths, 2009, 27(6): 886.
[12] Hassanzadeh-Tabrizi S A. Advanced Powder Technology, 2012, 23(3): 324.
[13] Zhang L, Lu Z, Zhu J, et al. Journal of Rare Earths, 2012, 30(4): 289.
[14] MU Zhong-fei, WANG Yin-hai, HU Yi-hua, et al(牟中飞, 王银海, 胡义华, 等). Acta Phys. Sin.(物理学报), 2011, 60(1): 013201-1.
[15] Wu Z, Zhang X, He W, et al. Journal of Alloys and Compounds, 2009, 468(1-2): 571.
[16] Luo Y, Guo S P, Maksimov O, et al. Applied Physics Letters, 2000, 77(26): 4259. |
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