| 光谱学与光谱分析 |
|
|
|
|
|
| Quantitative Analysis of Transformer Oil Dissolved Gases Using FTIR |
| ZHAO An-xin1, 2, TANG Xiao-jun1*, WANG Er-zhen1, ZHANG Zhong-hua1, 3, LIU Jun-hua1 |
1. Xi’an Jiaotong University State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an 710049, China
2. Xi’an University of Science and Technology, Xi’an 710054, China
3. National Institute of Metrology, Beijing 100013, China |
|
|
|
|
Abstract For the defects of requiring carrier gas and regular calibration, and low safety using chromatography to on line monitor transformer dissolved gases, it was attempted to establish a dissolved gas analysis system based on Fourier transform infrared spectroscopy. Taking into account the small amount of characteristic gases, many components, detection limit and safety requirements and the difficulty of degasser to put an end to the presence of interference gas, the quantitative analysis model was established based on sparse partial least squares, piecewise section correction and feature variable extraction algorithm using improvement TR regularization. With the characteristic gas of CH4, C2H6, C3H6, and CO2, the results show that using FTIR meets DGA requirements with the spectrum wave number resolution of 1 cm-1 and optical path of 10 cm.
|
|
Received: 2013-01-27
Accepted: 2013-03-27
|
|
|
|
Corresponding Authors:
TANG Xiao-jun
E-mail: xiaojun_tang@mail.xjtu.edu.cn
|
|
[1] Singh J, Sood Y R, Jarial R K, et al. IEEE Electrical Insulation Magazine, 2008, 24(3): 11.
[2] Singh S, Bandyopadhyay M N. IEEE Electrical Insulation Magazine, 2010, 26(6): 41.
[3] SHANG Li-ping，CAO Tie-ze，LIU Xian-yong, et al(尚丽平，曹铁泽，刘先勇, 等). Transformer(变压器), 2004, 41(8)：36.
[4] Chen W G, Liu B J, Hu J X, et al. Journal of Chongqing University(Natural Science Edition), 2011, 34(2): 7.
[5] Chen W G, Liu B J, Huang H X. Sensor Letters, 2011, 9(4): 1511.
[6] ZHAO Xiao-xiao，YUN Yu-xin，CHEN Wei-gen(赵笑笑，云玉新，陈伟根). Power System Protection and Control(电力系统保护与控制), 2009, 37(23): 187.
[7] CHEN Wei-gen，YUN Yu-xin，PAN Chong, et al(陈伟根，云玉新，潘 翀, 等). Automation of Electric Power Systems(电力系统自动化), 2007, 31(15): 94.
[8] LIU Xian-yong，HU Jin-song，ZHOU Fang-jie, et al(刘先勇，胡劲松，周方洁, 等). Transformer(变压器), 2004, 41(10): 33.
[9] BAI Peng，LI Yan，ZHANG Bin, et al(白 鹏，李 彦，张 斌, 等). Acta Photonica Sinica(光子学报), 2008, 37(3): 566.
[10] HAO Hui-min，QIAO Cong-ming，TANG Xiao-jun, et al(郝惠敏，乔聪明，汤晓君, 等). Journal of Infrared and Millimeter Waves(红外与毫米波学报), 2009, 28(2): 115.
[11] TANG Xiao-jun，ZHANG Lei，WANG Er-zhen, et al(汤晓君，张 蕾，王尔珍, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2012, 32(10): 2730.
[12] Bair E, Hastie T, Paul D, et al. Journal of the American Statistical Association, 2006, 101(473): 119.
[13] Allegrini F, Olivieri A C. Analytica Chimica Acta, 2011, 699(1): 18. |
| [1] |
GUO Ya-fei1, CAO Qiang1, YE Lei-lei1, ZHANG Cheng-yuan1, KOU Ren-bo1, WANG Jun-mei1, GUO Mei1, 2*. Double Index Sequence Analysis of FTIR and Anti-Inflammatory Spectrum Effect Relationship of Rheum Tanguticum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 188-196. |
| [2] |
LIU Hao-dong1, 2, JIANG Xi-quan1, 2, NIU Hao1, 2, LIU Yu-bo1, LI Hui2, LIU Yuan2, Wei Zhang2, LI Lu-yan1, CHEN Ting1，ZHAO Yan-jie1*，NI Jia-sheng2*. Quantitative Analysis of Ethanol Based on Laser Raman Spectroscopy Normalization Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3820-3825. |
| [3] |
YANG Wen-feng1, LIN De-hui1, CAO Yu2, QIAN Zi-ran1, LI Shao-long1, ZHU De-hua2, LI Guo1, ZHANG Sai1. Study on LIBS Online Monitoring of Aircraft Skin Laser Layered Paint Removal Based on PCA-SVM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3891-3898. |
| [4] |
LIN Hong-jian1, ZHAI Juan1*, LAI Wan-chang1, ZENG Chen-hao1, 2, ZHAO Zi-qi1, SHI Jie1, ZHOU Jin-ge1. Determination of Mn, Co, Ni in Ternary Cathode Materials With
Homologous Correction EDXRF Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3436-3444. |
| [5] |
HUANG Li, MA Rui-jun*, CHEN Yu*, CAI Xiang, YAN Zhen-feng, TANG Hao, LI Yan-fen. Experimental Study on Rapid Detection of Various Organophosphorus Pesticides in Water by UV-Vis Spectroscopy and Parallel Factor Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3452-3460. |
| [6] |
LI Zhong-bing1, 2, JIANG Chuan-dong2, LIANG Hai-bo3, DUAN Hong-ming2, PANG Wei2. Rough and Fine Selection Strategy Binary Gray Wolf Optimization
Algorithm for Infrared Spectral Feature Selection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3067-3074. |
| [7] |
LIU Shu1, JIN Yue1, 2, SU Piao1, 2, MIN Hong1, AN Ya-rui2, WU Xiao-hong1*. Determination of Calcium, Magnesium, Aluminium and Silicon Content in Iron Ore Using Laser-Induced Breakdown Spectroscopy Assisted by Variable Importance-Back Propagation Artificial Neural Networks[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3132-3142. |
| [8] |
TIAN Ze-qi1, WANG Zhi-yong1, YAO Jian-guo1, GUO Xu1, LI Hong-dou1, GUO Wen-mu1, SHI Zhi-xiang2, ZHAO Cun-liang1, LIU Bang-jun1*. Quantitative FTIR Characterization of Chemical Structures of Highly Metamorphic Coals in a Magma Contact Zone[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2747-2754. |
| [9] |
KONG De-ming1, LIU Ya-ru1, DU Ya-xin2, CUI Yao-yao2. Oil Film Thickness Detection Based on IRF-IVSO Wavelength Optimization Combined With LIF Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2811-2817. |
| [10] |
ZHANG Xiao-xu1, LIN Xiao-xian3, ZHANG Dan2, ZHANG Qi1, YIN Xue-feng2, YIN Jia-lu3, 4, ZHANG Wei-yue4, LI Yi-xuan1, WANG Dong-liang3, 4*, SUN Ya-nan1*. Study on the Analysis of the Relationship Between Functional Factors and Intestinal Flora in Freshly Stewed Bird's Nest Based on Fourier Transform Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2452-2457. |
| [11] |
CHENG Xiao-xiang1, WU Na2, LIU Wei2*, WANG Ke-qing2, LI Chen-yuan1, CHEN Kun-long1, LI Yan-xiang1*. Research on Quantitative Model of Corrosion Products of Iron Artefacts Based on Raman Spectroscopic Imaging[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2166-2173. |
| [12] |
WANG Yu-hao1, 2, LIU Jian-guo1, 2, XU Liang2*, DENG Ya-song2, SHEN Xian-chun2, SUN Yong-feng2, XU Han-yang2. Application of Principal Component Analysis in Processing of Time-Resolved Infrared Spectra of Greenhouse Gases[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2313-2318. |
| [13] |
ZHAO Yu-wen1, ZHANG Ze-shuai1, ZHU Xiao-ying1, WANG Hai-xia1, 2*, LI Zheng1, 2, LU Hong-wei3, XI Meng3. Application Strategies of Surface-Enhanced Raman Spectroscopy in Simultaneous Detection of Multiple Pathogens[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2012-2018. |
| [14] |
CHEN Rui1, WANG Xue1, 2*, WANG Zi-wen1, QU Hao1, MA Tie-min1, CHEN Zheng-guang1, GAO Rui3. Wavelength Selection Method of Near-Infrared Spectrum Based on
Random Forest Feature Importance and Interval Partial
Least Square Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1043-1050. |
| [15] |
DENG Xiao-jun1, 2, MA Jin-ge1, YANG Qiao-ling3, SHI Yi-yin1, HUO Yi-hui1, GU Shu-qing1, GUO De-hua1, DING Tao4, YU Yong-ai5, ZHANG Feng6. Visualized Fast Identification Method of Imported Olive Oil Quality Grade Based on Raman-UV-Visible Fusion Spectroscopy Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1117-1125. |
|
|
|
|
