光谱学与光谱分析 |
|
|
|
|
|
Realtime Analysis of Volatile Organic Compounds in Source Water by Membrane Inlet/Time-of-Flight Mass Spectrometry |
YU Bo-fan1, 2, WEN Li-li2, SONG Yong-hui2*, LIU Hong-liang1, 2, LI Hai-yang3, CUI Hua-peng3, XIE Bin-yu2, SI Ji-hong2 |
1. School of Environment, Beijing Normal University, Beijing 100875, China2. Chinese Research Academy of Environmental Sciences, Beijing 100012, China3. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China |
|
|
Abstract To establish an early-warning system for source water pollution accident, a membrane inlet / time-of-flight mass spectrometry technology was applied to a series of pollution scenarios as an online monitoring method for typical volatile organic compounds such as BTEX (benzene, toluene, ethylbenzene and xylene), substituted benzenes, and halogenated aliphatic hydrocarbons. It was shown that this technology can adequately meet the requirements of realtime analysis with short response time to the target organic pollutants (30~70 s for BTEX and 30 s for halogenated aliphatic hydrocarbons) in a linear detecting range of 3~4 magnitudes; the detection limits of BTEX and chlorobenzene were less than 10 μg·L-1. The results of 52 simulated water pollution accidents in a 30-days’ continuous monitoring indicated that the monitoring system was stable with the relative standard deviation less than 5%; the accuracy was acceptable and could be reduced to within 10% by periodical calibrations. Membrane inlet/time-of-flight mass spectrometry technology was proven to be available for the remote monitoring and early-warning of source water pollution accident.
|
Received: 2010-10-09
Accepted: 2011-02-16
|
|
Corresponding Authors:
SONG Yong-hui
E-mail: songyh@craes.org.cn
|
|
[1] Rathbun R E. Critical Reviews in Environmental Science and Technology, 2000, 30(2): 129. [2] ZHANG Yong, WANG Dong-yu, YANG Kai(张 勇,王东宇,杨 凯). Journal of Safety and Environment(安全与环境学报), 2006, 6(2): 79. [3] WANG Dong-yu, ZHANG Yong(王东宇,张 勇). Journal of Safety and Environment(安全与环境学报), 2007, 7(6): 150. [4] QU Jiu-hui(曲久辉). Principals and Technologies for Safe Drinking Water Assuring and Provision(饮用水安全保障技术原理). Beijing: Science Press(北京:科学出版社), 2007. 606. [5] LIU Jing-yun, SUN Bao-sheng, ZHANG Hai-feng(刘景允,孙宝盛,张海丰). Chemical Industry and Engineering Progress(化工进展), 2008, 27(5): 648. [6] Kuribayashi S, Yamakoshi H, Danno M, et al. Analytical Chemistry, 2005, 77(4): 1007. [7] Streibel T, Hafner K, Mühlberger F, et al. Applied Spectroscopy, 2006, 60(1): 72. [8] Mühlberger F, Saraji-Bozorgzad M, Gonin M, et al. Analytical Chemistry, 2007, 79(21): 8118. [9] Zimmermann R, Mühlberger F, Fuhrer K, et al. Journal of Material Cycles and Waste Management, 2008, 10(1): 24. [10] Panariello M, Apicella B, Armenante M, et al. Rapid Communications in Mass Spectrometry, 2008, 22(4): 573. [11] HOU Ke-yong, DONG Can, ZHANG Na-zhen, et al(侯可勇,董 璨,张娜珍,等). Chinese Journal of Analytical Chemistry(分析化学), 2006, 34(12): 1807. [12] YIN Xue-feng, LI Xiao-dong, LU Sheng-yong, et al(尹雪峰,李晓东,陆胜勇,等). Proceedings of the CSEE(中国电机工程学报), 2007, 27(17): 29. [13] Boscaini E, Alexander M L, Prazeller P, et al. International Journal of Mass Spectrometry, 2004, 239(2-3): 171. [14] Cotte-Rodríguez I, Handberg E, Noll R J, et al. The Analyst, 2005, 130: 679. [15] Janfelt C, Frandsen H, Lauritsen F R. Rapid Communications in Mass Spectrometry, 2006, 20(9): 1441. [16] Thompson A J, Creba A S, Ferguson R M, et al. Rapid Communications in Mass Spectrometry, 2006, 20(13): 2000. [17] VanHassel E, Bier M E. Rapid Communications in Mass Spectrometry, 2007, 21(3): 413. [18] HOU Ke-yong, CHEN Xin-hua, DONG Can, et al(侯可勇,陈新华,董 璨,等). Chemical Journal of Chinese Universities(高等学校化学学报), 2007, 28(7): 1240. [19] ZHOU Wen-min, FU De-qian, SUN Zong-guang(周文敏,傅德黔,孙宗光). Research of Environmental Sciences(环境科学研究), 1991, 4(6): 9. [20] LaPack M A, Tou J C, Enke C G. Analytical Chemistry, 1990, 62(13): 1265. [21] Tsai G J, Austin G D, Syu M J, et al. Analytical Chemistry, 1991, 63(21): 2460. [22] Ketola R A, Ojala M, Sorsa H, et al. Analytica Chimica Acta, 1997, 349(1-3): 359. |
[1] |
YUE Bao-wang, DING Wei-jie . Detection System for VOCs Concentration Based on Improved Photo-Elastic Modulator[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(01): 232-235. |
[2] |
Lü Qing1, XU Shi-qin1, GU Jun-qiang1, WANG Shi-feng2, WU Jing2*, CHENG Cheng2, TANG Jiu-kai2 . Pollution Source Identification of Water Body Based on Aqueous Fingerprint-Case Study[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(08): 2590-2595. |
[3] |
SHI Lei1,LIU Jia2,GAO Wu1,ZHANG Qian-xuan1,WANG Wei1. The Design of an ATR Probe for Online Monitoring of Biological Process[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(06): 1954-1958. |
[4] |
LI Dan1, FENG Wei-wei2*, CHEN Ling-xin2, ZHANG Jun1* . An On-Line Monitoring System for Nitrate in Seawater Based on UV Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(02): 442-444. |
[5] |
WANG Shi-feng1, 2, WU Jing2*, CHENG Cheng2, YANG Lin2, ZHAO Yu-fei2, Lü Qing3, FU Xin-mei1 . Aqueous Fingerprint of Printing and Dyeing Wastewater [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(12): 3440-3443. |
[6] |
XIE Fei, WU Qiong-shui*, ZENG Li-bo* . Biological Process Oriented Online Fourier Transform Infrared Spectrometer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(08): 2357-2361. |
[7] |
ZHAO Yu1, WANG Xian-pei1, HU Hong-hong2, DAI Dang-dang1, LONG Jia-chuan1, TIAN Meng1, ZHU Guo-wei1, HUANG Yun-guang3. Early Warning for Various Internal Faults of GIS Based on Ultraviolet Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(02): 438-442. |
[8] |
QIU He, LIU Ming-jun, TIAN Xiao-feng . Pre-Alarming Apparatus for Earthquake Based on Mid-Infrared Trace Methane Detection [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(06): 1524-1527. |
[9] |
XIE Chao-bo1, WU Jing1*, CAO Zhi-ping1, YANG Lin1, QIAN Yi1, Lü Qing2, ZHANG Ren-quan2 . 3-D Fluorescence Properties of River with Great Flow Rate [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(03): 695-697. |
[10] |
ZHAO An-xin1, 2, TANG Xiao-jun1*, WANG Er-zhen1, ZHANG Zhong-hua1, 3, LIU Jun-hua1 . Quantitative Analysis of Transformer Oil Dissolved Gases Using FTIR [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(09): 2407-2410. |
[11] |
HOU Di-bo1, ZHANG Jian1, CHEN Lin2, HUANG Ping-jie1, ZHANG Guang-xin1 . Water Quality Analysis by UV-Vis Spectroscopy: A Review of Methodology and Application[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(07): 1839-1844. |
[12] |
DAI Chun-yan1, WU Jing1*, XIANG Xi1, XIE Chao-bo1, YIN Dan-dan1, CAO Zhi-ping1, Lü Qing2 . Fluorescence Properties of Municipal Wastewater with Industrial Wastewater as Major Components[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(02): 414-417. |
[13] |
ZHAO You-quan1, 2, ZOU Rui-jie1, CHEN Yu-bang3, FANG Yan-jun4 . Research on Detection of Oil in Water Based on Near-Infrared Scattering Method [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(05): 1213-1216. |
[14] |
YANG Hui-hua1, GUO Tuo2, MA Jin-fang3, TANG Tian-biao2, LIANG Qiong-lin4, WANG Yi-ming4, LUO Guo-an4 . A Novel Online Process Monitoring Method Based on Near Infrared Spectroscopy and Its Application to the Column Chromatographic Separation for Traditional Chinese Medicine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(05): 1247-1250. |
[15] |
LI Hu1,3, NIU Wen-qi2, WANG Hong-mei1, HUANG Chao-qun1, JIANG Hai-he1, CHU Yan-nan1* . Photoionization Ion Mobility Spectrometry (UV-IMS) for the Isomeric Volatile Organic Compounds [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(01): 29-32. |
|
|
|
|