| 光谱学与光谱分析 |
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| Coordination Bonding Driving Supramolecular Self-assembly of Tetraphenylporphyrinatozinc(Ⅱ) with Imidazolyl Tailed Porphyrinatoiron(Ⅲ) Studied by Fluorescence Spectra and 1H NMR |
| HU Shu-guang, HUANG Jin-wang, MA Li, LUO Hai-ying, JI Liang-nian |
| State Key Laboratory of Optoelectronic Materials and Technologies/School of Chemistry and Chemical Engineering, Zhongshan (Sun Yat-Semi) University，Guangzhou 510275，China |
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Abstract Coordination bonding driving supramolecular self-assembly of Zn(TPP) with Fe(p-ImEPTPP)Cl was investigated by fluorescence spectra and 1H NMR. The results indicate that an obvious fluorescence quenching observed from Zn(TPP) by addition of Fe(p-ImEPTPP)Cl is due to the coordination of the terminal imidazolyl group of Fe(p-ImEQTPP)Cl to Zn2+ of Zn(TPP). The change of fluorescence spectra of Zn(TPP) / Fe(p-ImEPTPP)Cl system by adding some Lewis bases，such as piperidine, imidazole and pyridine，as well as 1H NMR further supported this coordination.
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Received: 2002-04-22
Accepted: 2002-09-08
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Corresponding Authors:
HUANG Jin-wang
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| Cite this article: |
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HU Shu-guang,HUANG Jin-wang,MA Li, et al. Coordination Bonding Driving Supramolecular Self-assembly of Tetraphenylporphyrinatozinc(Ⅱ) with Imidazolyl Tailed Porphyrinatoiron(Ⅲ) Studied by Fluorescence Spectra and 1H NMR [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(03): 381-383.
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http://www.gpxygpfx.com/EN/Y2004/V24/I03/381 |
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