光谱学与光谱分析 |
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In-Situ IR Study of Adsorption and Decomposition of Methanol on γ-Al2O3,CeO2 and Their Supported Pd Catalysts |
YANG Cheng, DONG Qing-nian, REN Jie, SUN Yu-han* |
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China |
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Abstract The adsorption and decomposition of methanol on γ-Al2O3 and CeO2 supports,and Pd/Al2O3 and Pd/CeO2 catalysts were studied by in-situ FTIR technique. The possible pathway of methanol decomposition on Pd/Al2O3 and Pd/CeO2 catalysts was analyzed according to the interaction of Pd and the supports. Methanol was dehydrogenated into DME or decomposed towards CO and H2 over different active phase on Pd/Al2O3 catalyst. A synergistic effect between Pd and CeO2 on the activity of Pd/CeO2 catalyst for methanol decomposition was proved.
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Received: 2002-12-16
Accepted: 2003-05-07
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Corresponding Authors:
SUN Yu-han
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Cite this article: |
YANG Cheng,DONG Qing-nian,REN Jie, et al. In-Situ IR Study of Adsorption and Decomposition of Methanol on γ-Al2O3,CeO2 and Their Supported Pd Catalysts [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(07): 810-812.
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http://www.gpxygpfx.com/EN/Y2004/V24/I07/810 |
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