光谱学与光谱分析 |
|
|
|
|
|
Study of Direct Fluorophotometric and Flow-Injection Fluorophotometric Methods Based on the Inhibitory Effect for the Determination of Trace Formaldehyde |
OUYANG Xiao-qing,XIE Zeng-hong*,GUO Zu-feng,LIN Xu-cong,GUO Liang-qia |
Department of Chemistry,Fuzhou University,Fuzhou 350002, China |
|
|
Abstract Sulfite reacts with o-phthalaldehude in the presence of ammonium forming the highly fluorescing isoindole-1-sulfonate in neutral or weakly acid solution, and formaldehyde has inhibitory effect on it. Based on this principle, the authors developed the direct fluorophotometric and flow-injection fluorophotometric methods for the determination of trace formaldehyde. The maximum excitation wavelength and the maximum emission wavelength are 320 and 390 nm respectively. With the direct fluorophotometric method, formaldehyde in the concentration range of 0.10-1.60 μg·mL-1 can be determined with a detection limit of 0.046 μg·mL-1. With the flow-injection fluorophotometric method, formaldehyde in the concentration range of 0.10-2.00 μg·mL-1 can be determined with a detection limit of 0.085 μg·mL-1. The methods were applied respectively to the analysis of river water with satisfactory results.
|
Received: 2003-12-22
Accepted: 2004-05-08
|
|
Corresponding Authors:
XIE Zeng-hong
|
|
Cite this article: |
OUYANG Xiao-qing,XIE Zeng-hong,GUO Zu-feng, et al. Study of Direct Fluorophotometric and Flow-Injection Fluorophotometric Methods Based on the Inhibitory Effect for the Determination of Trace Formaldehyde [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(11): 1395-1399.
|
|
|
|
URL: |
http://www.gpxygpfx.com/EN/Y2004/V24/I11/1395 |
[1] GB13197—91, 水质 甲醛的测定 乙酰丙酮分光光度法. [2] Miksch Robert R, Anthon Dougias W et al. Anal. Chem., 1981, 53(13):2118. [3] Jones S Bart, Terry Christopher M, Lister Tedd E et al. Anal. Chem., 1999, 71(18):4030. [4] Helaleh Murad I H, Kumemura Momoko, Korenaga Takashi et al. Analyst, 2001, 126:104. [5] Lazrus Allan L, Fong Laren L,Lind John A. Anal. Chem., 1988, 60(10):1074. [6] Maeda Yasuaki, Hu Xincheng, Itou Shigenao et al. Analyst, 1994, 119:2237. [7] Lu Xiaohu, Lu Minggang,Yin Fang. Anal. Lett., 1992, 25(11):2073. [8] Velikonja S, Jarc I,Marsel J et al. J. Chromatogr. A, 1995, 704:449. [9] Gromping A H J,Cammann K. Chromatogr., 1993, 35(3):142. [10] Mana Hasson,Spohn Uwe. Anal. Chem., 2001, 73(13):3187. |
[1] |
LIU Guo-hua, LI Qi-hua*, OU Jin-ping, XU Heng, ZHU Peng-cheng, LIU Hao-ran. Passive Spectrum Measurement of HCHO in Chongqing Area Based on MAX-DOAS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 243-247. |
[2] |
HE Qi-xin, LI Jia-kun, FENG Qi-bo*. Development of a Mid-Infrared Cavity Enhanced Formaldehyde Detection System[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2077-2081. |
[3] |
ZHENG Pei-chao, ZHONG Chao, WANG Jin-mei*, LUO Yuan-jiang, LAI Chun-hong, WANG Xiao-fa, MAO Xue-feng. Evaluation of Flow Injection-Solution Cathode Glow Discharge With an Interference Filter Wheel for Spectral Discrimination[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 842-847. |
[4] |
YANG Chuan-xiao, GONG Wei-bin, TANG Fan, SUN Xiang-ying. Determination of Sodium Hexametaphosphate by Ratiometric Fluorescence Method Based on Formaldehyde Functionalized Polyethyleneimine/Eosin Y System[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 454-459. |
[5] |
ZHANG Hao1,2, GAO Qing1, HAN Xiang-xiang1, RUAN Gao-yang1, LIU Xiu-yu1. Mechanism Analysis of Formaldehyde Degradation by Hot Braised Slag Modified Activated Carbon Based on XRF and XRD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(05): 1447-1451. |
[6] |
ZHANG Hao1, 2, 3, ZHANG Lei3, LONG Hong-ming1, 2*. Spectroscopic Analysis of Preparation of Ecological Activated Carbon Based on Electric Furnace Slag Ultrafine Powder Modified Biomass Waste Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(03): 861-866. |
[7] |
WEI Min-hong1,2, LIU Cheng2*, LI Su-wen1, CHEN Zheng-hui1, MOU Fu-sheng1. Measurement of Tropospheric HCHO by MAX-DOAS Based on QDOAS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(08): 2332-2336. |
[8] |
CAO Si-min, LIU Yang-yi, ZHOU Zhong-neng, CHEN Jin-quan, XU Jian-hua*. Study on Spectral Characteristics of a Novel Formaldehyde Probe Based on Fluoral-P Derivatives[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(03): 828-833. |
[9] |
WANG Zhong-yuan1, ZHANG Hong-kang2*, NI Zhi-xin1, LIU Jing-qin1, CHEN Xin1, LI Sheng-yong1, YANG Qi-jin2, ZHANG Can1. FI-KR-FAAS Twice Gas Isolation Elution Method for the Determination of Trace Lead in Marine Biological Samples[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3578-3582. |
[10] |
LIU Xing-bin, WANG Yue*, HAN Xiao-ri*, MA Bin. Feasibility of Rapid Evaluation of Urea-Formaldehyde Fertilizer by Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 750-755. |
[11] |
AN Xue-jing, LUO Yun-jing*, ZHANG Chen-yang. Research on the Reaction Dynamics between Peroxynitrite and Tyrosine Catalyzed with Mimic Enzyme through Flow Injection Analyzer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(12): 4052-4057. |
[12] |
SHEN Shi-liang1, WANG Shan-shan1*, ZHOU Bin2 . Investigation of Atmospheric Formaldehyde and Glyoxal Based on Differential Optical Absorption Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(08): 2384-2390. |
[13] |
LI Jia-jia, LI Rui, MA Xue, FAN Ting-ting, LIN Yi-qing, SONG Yu-ting, HAN Jing-qi, LI Xia* . Fluorescence Properties and the Detection of Benzaldehyde of Lanthanide Complex with 2-Sufoterephthalalic Acid [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(02): 345-348. |
[14] |
ZHENG Zhi-yuan1, 2, 3, DU Yu-zhi1, 2, ZHANG Ming1, 2, 3, YU Ming-jie1, 2, 3, LI Cen1, 2, 3, YANG Hong-xia1, 2, ZHAO Jing1, 2, 3, XIA Zheng-hua1, 2, 3, WEI Li-xin1, 2*. Study on Content Determination of Lead and Arsenic in Four Traditional Tibetan Medicine Prescription Preparations by Wet Digestion Flow Injection-Hydride Generation-Atomic Absorption Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(04): 1037-1042. |
[15] |
CAO Jun-tao1, WANG Hui1, CHEN Yong-hong2, LIU Yan-ming1* . Sensitive Determination of Hemoglobin in Human Blood and Serum by Flow Injection Coupled with Chemiluminescence Detection [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(01): 241-245. |
|
|
|
|