光谱学与光谱分析 |
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Determination of Trace Manganese in Mongolian Medicine by Methylthymol Blue-Mn(Ⅱ)-H2O2 Catalytic System |
WU Yun, LI Jing-feng, Garidi |
Department of Chemistry, Inner Mongolia Normal University, Huhhot 010022, China |
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Abstract A new catalytic kinetic spectrophotometry method for the determination of trace manganese based on the oxidation reaction of H2O2 with methylthymol blue in Na2B4O7-NaOH medium has been developed. The range of the determination range was 0.20-40.00 μg·L-1. The apparent activation energy and apparent rate constant were 73.24 kJ·mol-1 and 5.62×10-4·s-1, respectively, and the detection limit was 6.4×10-10 g·mL-1. The method has been used to determine trace manganese in Mongolian medicine with satisfactory result.
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Received: 2003-07-25
Accepted: 2003-12-22
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Corresponding Authors:
WU Yun
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Cite this article: |
WU Yun,LI Jing-feng,Garidi. Determination of Trace Manganese in Mongolian Medicine by Methylthymol Blue-Mn(Ⅱ)-H2O2 Catalytic System [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(12): 1652-1654.
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URL: |
https://www.gpxygpfx.com/EN/Y2004/V24/I12/1652 |
[1] DAI An-bang(戴安邦). Coordination Chemistry(配位化学). Beijing: Science Press(北京: 科学出版社), 1987. 689. [2] WU He-zhou,ZHENG Zhao-sheng, DING Chun-ling et al(吴和舟, 郑肇声, 丁春令等). Chinese J. Anal. Chem.(分析化学), 1996, 24(9): 1085. [3] ZHOU Jian-yong(周坚勇). Chinese J. of Physical and Chemical Analysis, Chemical Analysis, Part B(理化检验), 1996, 32(1): 51. [4] ZHOU Hua-fang, ZHANG Ming-zhu, WANG Zhen-pu et al(周华方, 张明珠, 王镇蒲等). Chinese Chemistry Bulletin(化学通报), 1994, (4): 42. [5] XIA Chang-bin, HE Xiang-zhu(夏畅斌, 何相柱). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2001,21(1):90. [6] Central China Normal University et al(华中师范大学等). Analytical Chemistry(分析化学·下册). Beijing: Higher Education Press(北京: 高等教育出版社), 2002. 6.
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