| 光谱学与光谱分析 |
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| Spectral Properties of the Association Particle System of Quinine-[PtI6]2- and Its Analytical Application |
| JIANG Zhi-liang1，ZOU Jie-ming2，KANG Cai-yan1，WANG Li-sheng2 |
1. Department of Resource and Environmental Science, Guangxi Normal University，Guilin 541004, China
2. Guilin Sanjin Pharmaceutical Group，Guilin 541004, China |
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Abstract In 0.01 mol·L-1 HCl medium, red color [PtI6]2- and quinine combine to form association molecule. The molecules aggregate automatically owing to strong hydrophobic and molecular forces. And PtI6-quinine association particles with violet-red color formed. It exhibits three resonance scattering peaks at 310 nm, 400 nm and 610 nm, and a Rayleigh scattering peak at 470 nm. The absorption values all increase in the wavelength range of 350-740 nm, and the fluorescence peak at 450 nm was quenched. Under the conditions chosen, the quinine concentration in the range of 0-40×10-6 mol·L-1 is linear to the A620 nm value. The mole absorption coefficient ε620 nm is 1.31×104 L·mol-1·cm-1. The results show that the association particles produce the resonance scattering effect, fluorescence quenching and the violet-red color.
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Received: 2003-03-28
Accepted: 2003-08-08
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Corresponding Authors:
JIANG Zhi-liang
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| Cite this article: |
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JIANG Zhi-liang,ZOU Jie-ming,KANG Cai-yan, et al. Spectral Properties of the Association Particle System of Quinine-[PtI6]2- and Its Analytical Application [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(12): 1634-1636.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2004/V24/I12/1634 |
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