光谱学与光谱分析 |
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Absorption Spectra Study of Cation Surfactant-[AuI4]- Association Particle System and Its Analytical Application |
LUO Yang-he,JIANG Zhi-liang* |
Department of Resource and Environmental Science, Guangxi Normal University, Guilin 541004 |
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Abstract In 0.01 mol·L-1 HCl medium, there is an absorption peak at 350 nm for [AuI4]-. The association particle system of CTMAB-[AuI4]- exhibits violet-red color. It has a new absorption peak at 520 nm. The CTMAB concentration cCTMAB in the range of 0-7.0×10-5mol·L-1 is linear to the A520 nm value. Its regression equation is A520 nm=0.989×104cCTMAB+0.013 8,regression coefficient is 0.999 5,and the mole absorption coefficient is 1.059×104 L·mol-1·cm-1. A new spectrophotometry has been proposed for the determination of cation surfactant. The resonance scattering spectra show that the CTMAB+ and [AuI4]- combine to form(AuI4-CTMAB) association molecule with hydrophobicity by means of attraction forces. The association molecules automatically aggregate to form(AuI4-CTMAB)n association particles. So, the particles exhibit two resonance scattering peaks at 580 and 470 nm, and the system exhibits violet-red.
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Received: 2003-03-08
Accepted: 2003-08-06
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Corresponding Authors:
JIANG Zhi-liang
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Cite this article: |
LUO Yang-he,JIANG Zhi-liang. Absorption Spectra Study of Cation Surfactant-[AuI4]- Association Particle System and Its Analytical Application[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(12): 1630-1633.
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URL: |
https://www.gpxygpfx.com/EN/Y2004/V24/I12/1630 |
[1] Richmond J M. Surfactant Science Series,Cationic Surfactants:Organic Chemistry. New York:Marcel Dekker Inc.,1990. 34. [2] XU Yan-li(徐燕莉). The Function of Surfactant(表面活性剂的功能). Beijing: Chemical Industry Press(北京:化学工业出版社),2000. [3] GUO Xiang-feng, JIA Li-hua(郭祥峰,贾丽华). The Cation Surfactant and Its Appication(阳离子表面活性剂及应用). Beijing: Chemical Industry Press(北京:化学工业出版社),2002. 136. [4] JIANG Zhi-liang, FENG Zhong-wei, LI Ting-sheng et al. Science in China, Series B,2001,44:175. [5] JIANG Zhi-liang, LIU Shao-pu, LIU Qing-ye(蒋治良, 刘绍璞, 刘庆业). Chin. J. Appl. Chem.(应用化学),2002,19(1):22. [6] Jiang Zhi-liang, Liu Shao-pu, Liu Qing-ye. Spectrochimica Acta, 2002, 58:2759. [7] JIANG Zhi-liang, LIU Shao-pu, ZHAO Bo-gang,CHEN Sa, LI Jian(蒋治良,刘绍璞,赵保刚,陈 飒,李 键). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2002,22(4):615. [8] LIN Shao-ming, JIANG Zhi-liang, BI Xian-shu,YI Xiang-hui(凌绍明,蒋治良,闭献树,义祥辉). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2001,21(6): 819.
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