| 光谱学与光谱分析 |
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| Synthesis and Crystal Structure of a Porous Coordination Polymer [Nd2(C6H8O4)3(H2O)2]n·n(4,4’-bpy) |
| ZHOU Qiu-xiang1,WANG Yan-ji1*,SONG Hai-bin2, ZHAO Xin-qiang1, YUE Lin1 |
1. School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China
2. National Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China |
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Abstract A novel porous coordination polymer [Nd2(C6H8O4)3(H2O)2]n·n(4,4’-bpy) was synthesized by hydrothermal synthesis reaction of hexyl acid, 4,4’-bpy with NdCl3·XH2O. The structure was characterized by elemental analysis, thermal gravimetric analysis, IR spectroscopy, and X-ray single crystal analysis. The crystal data are of an orthorhombic crystal system, Pbcn space group. Crystallographic data are: a =2.201 2 nm(6), b=0.777 8 nm(2)，c=1.972 4 nm(5), α=β=γ = 90°, V=337.70 nm(15)3, Z=4, Dc=1.796 g·cm-3, μ= 3.108 mm-1, F(000)=1 800, R1=0.043 0 and wR2=0.056 0. X-ray analysis reveals that three-dimensional porous nets were formed between Nd3+ and Nd3+ by carboxyl of hexyl acid.
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Received: 2003-10-29
Accepted: 2004-03-20
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Corresponding Authors:
WANG Yan-ji
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| Cite this article: |
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ZHOU Qiu-xiang,WANG Yan-ji,SONG Hai-bin, et al. Synthesis and Crystal Structure of a Porous Coordination Polymer [Nd2(C6H8O4)3(H2O)2]n·n(4,4’-bpy)[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(05): 730-733.
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https://www.gpxygpfx.com/EN/Y2005/V25/I05/730 |
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