| 光谱学与光谱分析 |
|
|
|
|
|
| Study on the Spectra of NTO and Its Rubidium Salt in Aqueous Solution |
| XIA Shu-ping1, 2, HU Man-cheng1, GAO Shi-yang1, 2,JIANG Yu-cheng1 |
1. College of Chemistry and Material Science, Shaanxi Normal University, Xi'an 710063, China
2. Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xi'an 710043, China |
|
|
|
|
Abstract In this paper, the Raman and difference FTIR spectra of NTO crystal, NTO solutions at different pH and saturated aqueous solution of Rb(NTO)·H2O have been studied. The determined structure of crystal suggests that the metal ion with oxygen and nitrogen atoms of CN, CNO2, CO and H2O formed bonds. The highest characterization peaks of Raman and FTIR spectra show that CNO2, CO and CN of NTO- formed week coordination bonds. The vibration spectra of saturation solution basically accord with those of the crystal. The bonds of saturation solution of the coordination compound have not changed. Therefore, the different vibration spectra of the saturation water solution of Rb(NTO)·H2O can be explicated by the formation of the bonds in crystal. The coordination compound formation mechanism of metal ion with NTO in alkali aqueous solution is discussed.
|
|
Received: 2003-09-23
Accepted: 2004-04-05
|
|
|
|
Corresponding Authors:
XIA Shu-ping
|
|
| Cite this article: |
|
XIA Shu-ping,HU Man-cheng,GAO Shi-yang, et al. Study on the Spectra of NTO and Its Rubidium Salt in Aqueous Solution [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(05): 734-738.
|
|
|
|
| URL: |
|
https://www.gpxygpfx.com/EN/Y2005/V25/I05/734 |
[1] Lee K Y, Chapman L B, Coburn M D. J. Energetic Materials, 1987, 5: 27.
[2] ZHANG Tong-lai(张同来). Preparation, Structure Characterization, Thermal Decomposition Mechanisms and Reaction Non-Isothermal Dynamics of Metal Salts of NTO(NTO金属盐的制备，结构表征，热分解机理和非等温反应动力学的研究). PH.D Thesis of Nanjing University of Technology(南京理工大学博士学位论文), 1993.
[3] SONG Ji-rong(宋纪蓉). Study on Metal Coordination Compounds of NTO(NTO金属配合物的研究). Beijing: Chemistry Industry Publishing Company(北京: 化学工业出版社)，1998.
[4] Singh Gurdip, Felu Pren. J. Hazardous Materials, 2002, A90: 1.
[5] HU Man-chang, GＡＯ Shi-yang, LＩＵ Zhi-hong et al. Chinica Sinica Buttetin, 2001, 46(1)：45.
[6] HＵ Man-chang, GＡＯ Shi-yang, LＩＵ Zhi-hong，XIA Shu-ping(胡满成，高世扬，刘志宏，夏树屏). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001，21(2): 197.
[7] Gao Shiyang, Hu Manchang, Xia Shuping et al. Journal of Molecular Structure, 2003, 664(1-3): 181.
[8] Prabhakaran K V, Naidu S R et al. Thermo Chimica Acta, 1994, 241: 199.
[9] ZHU Zhun-wu(朱准武). Organic Spectral Analysis(有机光谱分析). Guiyang: Guizhou Education Press(贵阳：贵州教育出版社), 1997. 67.
[10] SHENG De-yan(沈德言). Infrared Spectral Analysis in the Application of Study for Macromolecular Chemistry(红外光谱法在高分子研究中的应用). Beijing: Science Press(北京：科学出版社), 1982. 300, 382.
[11] XIA Shu-ping, HU Man-cheng, GAO Shi-yang et al(夏树屏, 胡满成, 高世扬等). Journal of Fudan University·Natural Science(复旦大学学报·自然科学版), 2003，42(6): 851.
[12] Gurdip Singh, Kapoor I P S. J. Hazardous Materials, 1999, A68: 155.
[13] Cromer D T, Hall J H, Lee K Y et al. Acta Cryst., 1988, C44: 1144.
|
| [1] |
XU Qi-lei, GUO Lu-yu, DU Kang, SHAN Bao-ming, ZHANG Fang-kun*. A Hybrid Shrinkage Strategy Based on Variable Stable Weighted for Solution Concentration Measurement in Crystallization Via ATR-FTIR Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1413-1418. |
| [2] |
WU Run-min1, XIE Fei1, SONG Xu-dong1*, BAI Yong-hui1, WANG Jiao-fei1, SU Wei-guang1, YU Guang-suo1, 2. The Mechanism of Hydrocarbon Flame Soot Formation in Spectral
Diagnosis: A Review[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 1-8. |
| [3] |
WANG Zhuo1, 2, SU Bo-min1, 2*, YU Zong-ren1, 2, SHUI Bi-wen1, 2, ZHAO Jin-li1, 2, CUI Qiang1, 2, SHAN Zhong-wei1, 2, LI Qian3. In-Situ Non-Invasive FTIR Analysis of Conservation Materials on the Surface of Mural Paintings in Prince Shi’s Palace of the Taiping Heavenly Kingdom[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(02): 356-361. |
| [4] |
LI Jing1, TIAN Hong-xiang1*, SUN Yun-ling1, MING Ting-feng1, SHENG Chen-xing2, 3. Application of FTIR Spectrum in Quantitatively Monitoring Oil Contaminants[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(11): 3459-3464. |
| [5] |
DONG Jia-lin1, HONG Ming-jian1, 3*, ZHENG Xiang-quan2, 3, XU Yi2, 3. Discrimination of Human, Dog and Rabbit Blood Using Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 459-466. |
| [6] |
ZHANG Bao-yong1,2，ZHOU Hong-ji1,2，WU Qiang1,2，GAO Xia3. Raman Spectra Characteristics of Gas Hydrate Growth with Different Driving Forces[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2768-2773. |
| [7] |
YE Song1，ZHANG Bing-ke1, 2，YANG Hui-hua1，ZHANG Wen-tao1，DONG Da-ming2*. Identification of Beef Spoilage Processes Using the Infrared Spectrum of Volatiles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2751-2755. |
| [8] |
WU Cheng-ling1, GUO Jun-hong1, 2, YAO Heng-bin1, PAN Ling-nan1, WANG Fei1, WU Wen-qi1, JI Tong1, HU Fang-ren1, 2*. Study on the Photoluminescence Properties of ZnO Single Crystal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1700-1702. |
| [9] |
XU Dong-mei1, PAN Kun1, LIU Xu-wei1, WANG Xue-jin1*, WANG Wen-zhong2, LIANG Chun-jun3, WANG Zhi2 . Raman and Visible-Near Infrared Spectra of Cu(InGa)Se2 Films [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(10): 3197-3201. |
| [10] |
WANG Guo-xiang1, WANG Hai-yan2, WANG Hu1, ZHANG Zheng-yong2, LIU Jun1 . Study on the Recognition of Liquor Age of Gujing Based on Raman Spectra and Support Vector Regression[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(03): 729-735. |
| [11] |
LIU Na, WEI Xiu-li*, GAO Min-guang, XU Liang . A Quantitative Analysis Method of Water-Soluble Inorganic Ions with ATR-FTIR Spectroscopy [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(12): 3364-3368. |
| [12] |
JIANG Ling1, LI Miao1, LI Chun1, SUN Hai-jun2, XU Li2, LIU Yun-fei* . Terahertz Spectroscopy of Biotin and Pyridoxine [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(10): 2946-2951. |
| [13] |
ZHANG Bao-yong1, 2, YU Yue1, 2*, WU Qiang1, 2, GAO Xia3 . Quantitative Analysis of the Hydration Process of Mine Gas Mixture Based on Raman Spectroscopy [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(07): 1912-1916. |
| [14] |
LI Tao, TANG Yan-lin*, LING Zhi-gang, LONG Zheng-wen . Study on the Frontier Orbital and Raman Spectra of Aflatoxin B1 and Isomer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(08): 2122-2125. |
| [15] |
LI Jing1, MAO Shi-de1*, ZHENG Hai-fei2,3 . Raman Spectroscopic Quantitative Study of NaCl-CaCl2-H2O System at High Temperatures and Pressures[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(07): 1747-1753. |
|
|
|
|
