光谱学与光谱分析 |
|
|
|
|
|
Study on Three-Dimensional Fluorescence Spectra of Phenanthrene |
JIN Dan1, ZHANG Yu-jun1*, LI Guo-gang2, XIAO Xue1, WANG Zhi-gang1, 3, YIN Gao-fang1, LIU Wen-qing1 |
1. Key Laboratory of Environmental Optics & Technology, Anhui Institute of Optics and Fine Mechanics, The Chinese Academy of Sciences, Hefei 230031, China 2. China National Environmental Monitoring Center, Beijing 100029, China 3. University of Science and Technology of China, School of Earth and Space Science, Hefei 230026, China |
|
|
Abstract According to the high fluorescence quantum yields of polycyclic aromatic hydrocarbons (PAHs), the fluorescence spectra of phenanthrene were investigated by three dimensional fluorescence excitation-emission matrix(3DEEM). The results show that the three-dimensional fluorescence spectra of phenanthrene in aqueous solution mainly have two fluorescence peaks. On the basis of three-dimensional fluorescence spectrometry analysis of phenanthrene, the excitation wavelength of 255 nm and emission wavelength of 273 nm were chosen for the quantitative analysis of phenanthrene. The linear range for the determination of phenanthrene was 5.0-250.0 mg·mL-1, its detection limit was 3.88 ng·mL-1, and its relative standard deviation was 4.23% (n=5). It was a good precision. It has been tested satisfactorily for the determination of artificial sample in tap water. The recoveries are in the range of 90%-105%. The method provided basis for the rapid monitoring of trace PAHs in water.
|
Received: 2008-01-08
Accepted: 2008-04-12
|
|
Corresponding Authors:
ZHANG Yu-jun
E-mail: djin@aiofm.ac.cn
|
|
[1] FENG Yue-peng, PENG Hong-jun, LIANG Hong, et al(封跃鹏, 彭鸿俊, 梁 洪, 等). Research of Environmental Sciences(环境科学研究), 1998, 11(6): 39. [2] Tong H Y, Karasek F W. Anal. Chem., 1984, 56: 2129. [3] Beltran J L, Guiteras J, Ferrer R. Anal. Chem., 1998, 70: 1949. [4] Cecil T L, Rutan S C. J. Chromatogr., 1991, 556: 495. [5] Martinez E, Gros M, Lacorte S, et al. J. Chromatogr. A, 2004, 1047 (2): 181. [6] Baker A. Environmental Science & Technology, 2001, 35 (5): 948. [7] YU Tian-zhi, TAO Zu-yi(俞天智, 陶祖贻). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1999, 19(3): 453. [8] SONG Ji-mei, WANG Ling-feng(宋继梅, 王凌峰). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2002, 22(5): 803. [9] Vo-Dinh T. Appl. Spectrosc., 1982, 36: 576. [10] Weiner E R. Anal. Chem., 1978, 50: 1583. [11] CHEN Dong, LIU Wen-qing, ZHANG Yu-jun, et al(陈 东, 刘文清, 张玉钧, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(12): 2283. [12] LI Hong-bin, LIU Wen-qing, ZHANG Yu-jun, et al(李宏斌, 刘文清, 张玉钧, 等). Journal of Atmospheric and Environmental Optics(大气与环境光学学报), 2006, 1(3): 216. [13] SONG Ji-mei, TANG Bi-lian(宋继梅, 唐碧莲). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2000, 20(1): 115. [14] Pullin M J, Cabaniss S E. Environmental Science & Technology, 1995, 29(6): 1460. [15] FU Ping-qing, LIU Cong-qiang, WU Feng-chang(傅平青, 刘丛强, 吴丰昌). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005, 25(12): 2024. [16] LI Hong-bin, LIU Wen-qing, ZHANG Yu-jun, et al(李宏斌, 刘文清, 张玉钧, 等). Optical Technique(光学技术), 2006, 32(01): 27. [17] Warner I M, Christian G D, Davidson E R. Anal. Chem., 1977, 49: 564. [18] Karcher W. Spectral Atlas of Polycyclic Aromatic Compounds. Dordrecht: Kluwer Academic Publishers, 1985. [19] CHEN Guo-zhen, HUANG Xian-zhi, ZHENG Zhu-zi, et al(陈国珍, 黄贤智, 郑朱梓, 等). Fluorescence Analysis Method(Second Edition)(荧光分析法·第2版). Beijing: Science Press(北京: 科学出版社), 1990. [20] ZHANG Yong, HUANG Xian-zhi, XU Jin-gou, et al(张 勇, 黄贤智, 许金钩, 等). Chinese Journal of Analytieal Chemistry(分析化学), 1994, 22(5): 445.
|
[1] |
XING Hai-bo1, ZHENG Bo-wen1, LI Xin-yue1, HUANG Bo-tao2, XIANG Xiao2, HU Xiao-jun1*. Colorimetric and SERS Dual-Channel Sensing Detection of Pyrene in
Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 95-102. |
[2] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
[3] |
GU Yi-lu1, 2,PEI Jing-cheng1, 2*,ZHANG Yu-hui1, 2,YIN Xi-yan1, 2,YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
[4] |
SONG Yi-ming1, 2, SHEN Jian1, 2, LIU Chuan-yang1, 2, XIONG Qiu-ran1, 2, CHENG Cheng1, 2, CHAI Yi-di2, WANG Shi-feng2,WU Jing1, 2*. Fluorescence Quantum Yield and Fluorescence Lifetime of Indole, 3-Methylindole and L-Tryptophan[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3758-3762. |
[5] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
[6] |
XUE Fang-jia, YU Jie*, YIN Hang, XIA Qi-yu, SHI Jie-gen, HOU Di-bo, HUANG Ping-jie, ZHANG Guang-xin. A Time Series Double Threshold Method for Pollution Events Detection in Drinking Water Using Three-Dimensional Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3081-3088. |
[7] |
JIA Yu-ge1, YANG Ming-xing1, 2*, YOU Bo-ya1, YU Ke-ye1. Gemological and Spectroscopic Identification Characteristics of Frozen Jelly-Filled Turquoise and Its Raw Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2974-2982. |
[8] |
YANG Xin1, 2, XIA Min1, 2, YE Yin1, 2*, WANG Jing1, 2. Spatiotemporal Distribution Characteristics of Dissolved Organic Matter Spectrum in the Agricultural Watershed of Dianbu River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2983-2988. |
[9] |
ZHU Yan-ping1, CUI Chuan-jin1*, CHENG Peng-fei1, 2, PAN Jin-yan1, SU Hao1, 2, ZHANG Yi1. Measurement of Oil Pollutants by Three-Dimensional Fluorescence
Spectroscopy Combined With BP Neural Network and SWATLD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2467-2475. |
[10] |
QIU Cun-pu1, 2, TANG Xiao-xue2, WEN Xi-xian4, MA Xin-ling2, 3, XIA Ming-ming2, 3, LI Zhong-pei2, 3, WU Meng2, 3, LI Gui-long2, 3, LIU Kai2, 3, LIU Kai-li4, LIU Ming2, 3*. Effects of Calcium Salts on the Decomposition Process of Straw and the Characteristics of Three-Dimensional Excitation-Emission Matrices of the Dissolved Organic Matter in Decomposition Products[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2301-2307. |
[11] |
ZHU Yu-xuan1, YANG Xiao-yu1, XU Xin-rong1, SUN Ming1*, JIAO Chao1*, CHEN Qian1*, ZHAO Zhen-lu2, CHEN Wei-qiang2, ZHANG Xin2, LIU Hong-xin2. Rotational Spectroscopic Investigation on 9-Fluorenone at C-Band (4~8 GHz)[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1988-1992. |
[12] |
SHI Chuan-qi1, LI Yan2, HU Yu3, YU Shao-peng1*, JIN Liang2, CHEN Mei-ru1. Fluorescence Spectral Characteristics of Soil Dissolved Organic Matter in the River Wetland of Northern Cold Region, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1517-1523. |
[13] |
LI Yuan-jing1, 2, CHEN Cai-yun-fei1, 2, LI Li-ping1, 2*. Spectroscopy Study of γ-Ray Irradiated Gray Akoya Pearls[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1056-1062. |
[14] |
LIU Xia-yan1, CAO Hao-xuan1, MIAO Chuang-he1, LI Li-jun2, ZHOU Hu1, LÜ Yi-zhong1*. Three-Dimensional Fluorescence Spectra of Dissolved Organic Matter in Fluvo-Aquic Soil Profile Under Long-Term Composting Treatment[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 674-684. |
[15] |
ZHU Wei1, 2, YANG Rui-fang1*, ZHAO Nan-jing1*, YIN Gao-fang1, XIAO Xue1, LIU Jian-guo1, LIU Wen-qing1. Study on Small Sample Analysis Method for Identification of Polycyclic Aromatic Hydrocarbons in Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3494-3500. |
|
|
|
|