| 光谱学与光谱分析 |
|
|
|
|
|
| Determination of Trace Arsenic and Mercury in Antimony Concentrates by Hydride Generation Atomic Fluorescence Spectrometry |
| YUAN Ai-ping1, TANG Yan-xia1, HUANG Yu-long1, WANG Jing-ling1, QIN Ran1, WU Jian-ling2, MENG Wen-fei2 |
1. Guangxi Entry-Exit Inspection and Quarantine Bureau, Nanning 530021, China
2. Guangxi University, Nanning 530004, China |
|
|
|
|
Abstract A method for the determination of trace arsenic and mercury in antimony concentrates by hydride generation atomic fluorescence spectrometry was investigated. The method of dissolving sample and the effect of concomitant ion were studied. It was found that aqua regia can be used to dissolve the sample completely, with maximum quantities of dissolved arsenic and mercury. The interference of chemical elements in antimony concentrates was avoided by adding thiourea-Vc. The matrix of antimony was vaporized with tartaric acid during sample pre-treatment. Trace arsenic and mercury were determined in real samples. The detection limits of 0.220 ng·mL-1 and 0.002 ng·mL-1 were obtained, the relative standard deviations(RSD%=11) are 1.47% and 0.52%, and the recoveries are 94.0%-103.0% and 98.7%-102.8% for As and Hg respectively. This method has proved rapid, accurate and highly sensitive.
|
|
Received: 2005-03-28
Accepted: 2005-06-26
|
|
|
|
Corresponding Authors:
YUAN Ai-ping
|
|
| Cite this article: |
|
YUAN Ai-ping,TANG Yan-xia,HUANG Yu-long, et al. Determination of Trace Arsenic and Mercury in Antimony Concentrates by Hydride Generation Atomic Fluorescence Spectrometry [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(08): 1553-1556.
|
|
|
|
| URL: |
|
https://www.gpxygpfx.com/EN/Y2006/V26/I08/1553 |
[1] ZHANG Yan(张 炎). China Nonferrous Metals Industry(有色金属工业)，2002，(11): 20.
[2] GB/T 15080.1～915080.9-1994. Methods for Chemical Analysis of Antimony Concentates(锑精矿化学分析方法).
[3] LIU Wei-li, ZHOU Zheng-xiang(刘维理, 周正祥). PTCA Part B Chemical Analysis(理化检验：化学分册), 1999，35(12)：540.
[4] LIANG Yi-lun(梁奕伦). Chinese Journal of Spectrum Laboratory(光谱实验室), 1995，12(5): 52.
[5] LIANG Yu-sheng(梁云生). Yunnan Metallurgy(云南冶金), 1996，25(5)：47.
[6] LI Guang-ming, SONG Xue-ling, GU Wei-guo, et al(李广明，宋雪玲，谷维国，等). PTCA Part B Chemical Analysis(理化检验：化学分册), 2001，37(8)：378.
[7] LIU Xi-guang, YU Hua-hua, ZHAO Zeng-qin, et al(刘希光，于华华，赵增芹，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2005，25(6)：964.
[8] HUANG Ru-jin, ZHUANG Zhi-xia, WEI Jin-feng, et al(黄汝锦，庄峙厦，魏金锋，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2005，25(10): 1708.
|
| [1] |
GUO Wei1, CHANG Hao2*, XU Can3, ZHOU Wei-jing2, YU Cheng-hao1, JI Gang2. Effect of Continuous Laser Irradiation on Scattering Spectrum
Characteristics of GaAs Cells[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3674-3681. |
| [2] |
LI Hui-ji1, LI Yan-wen1, YU Wei-wei2, HUANG Ru-meng1, SUN Hai-jie1*, PENG Zhi-kun3*. Theoretical Study on the Structures and IR Spectra of Hydration of Arsenates and Iron Arsenates[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2090-2094. |
| [3] |
WANG Xue-mei1, 2, YUMITI Maiming1, HUANG Xiao-yu1, 2, LI Rui1, 2, LIU Dong1, 2. Estimation of Arsenic Content in Soil Based on Continuous Wavelet
Transform[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 206-212. |
| [4] |
WANG Lu1, SUN Feng1, 2*, WANG Ruo-su1, LIANG Ya-xin1, YAO Xue3, ZHAO Fan4. Analysis and Research on Color Paints for Cliff Statues in Qionglai Caves[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3198-3202. |
| [5] |
YU Xin, ZHOU Wei*, XIE Dong-cai, XIAO Feng, LI Xin-yu. The Study of Digital Baseline Estimation in CVAFS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2392-2396. |
| [6] |
NI Zi-yue1, CHENG Da-wei2, LIU Ming-bo2, YUE Yuan-bo2, HU Xue-qiang2, CHEN Yu2, LI Xiao-jia1, 2*. The Detection of Mercury in Solutions After Thermal Desorption-
Enrichment by Energy Dispersive X-Ray Fluorescence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1117-1121. |
| [7] |
WAN Xiao-ming1, 2, ZENG Wei-bin1, 2, LEI Mei1, 2, CHEN Tong-bin1, 2. Micro-Distribution of Elements and Speciation of Arsenic in the Sporangium of Pteris Vittata[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 478-482. |
| [8] |
LI Zhi-yuan1,2, DENG Fan1*, HE Jun-liang2, WEI Wei1. Hyperspectral Estimation Model of Heavy Metal Arsenic in Soil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2872-2878. |
| [9] |
LI Hui-ji1, SUN Hai-jie1, LIU Na1, PENG Zhi-kun2*, LI Yong-yu1, YAN Dan3. Theoretical Study on the Structures and IR Spectra of Hydration of Arsenates and Iron Arsenates[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2071-2076. |
| [10] |
JULDEZ Nurlan1，2，3, SHEN Jian1，2，3, LENG Xiao-ting3, CHAI Yi-di1，2，3, WANG Shi-feng3, HU Yuan3, CUI Hao-yue3, WU Jing1，2，3*. Study on Measurement of Mercury Ion in Water by Thiamine-Fluorescence Excitation-Emission Matrix[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1846-1851. |
| [11] |
NI Zi-yue1, CHENG Da-wei2, LIU Ming-bo2, HU Xue-qiang2, LIAO Xue-liang2, YUE Yuan-bo2, LI Xiao-jia1,2, CHEN Ji-wen3. The Rapid Detection of Trace Mercury in Soil With EDXRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 734-738. |
| [12] |
CHEN Hai-jie1, 2, MA Na1, 2, BO Wei1, 2, ZHANG Ling-huo1, 2, BAI Jin-feng1,2, SUN Bin-bin1, 2, ZHANG Qin1, 2, YU Zhao-shui1, 2*. Research on the Valence State Analysis Method of Selenium in Soil and Stream Sediment[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 871-874. |
| [13] |
OU Li-juan, AN Xue-zhong, LUO Jian-xin, WANG Ling-yun, BO Heng, SUN Ai-ming, CHEN Lan-lan. High-Sensitive and Rapid Fluorescencet Detection of Hg2+ Based on Poly(adenine)-Templated Gold Nanoclusters[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 164-167. |
| [14] |
LI Peng1, LI Zhi2, XU Can2, FANG Yu-qiang2. Research on the Scattering Spectrum of GaAs-Based Triple-Junction Solar Cell Based on Thin-Film Interference Theory[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3092-3097. |
| [15] |
ZHANG Hai-yang1, GAO Bai1, 2*, FAN Hua3 , SHEN Wei1, LIN Cong-ye1. Mechanism of Fluoride and Arsenic Removal by Ce/γ-Al2O3 Based on XRD and FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2869-2874. |
|
|
|
|
