| 光谱学与光谱分析 |
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| Synthesis and Photophysical Properties of Two Kinds of Substituted Phthalocyaninatozinc |
| ZHU Xiao-li1,XU Xiu-zhi1,YANG Liang1,LIN Mei-jin1,WANG Jun-dong1,2*,HUANG Jin-ling1,2 |
| 1. College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China2. State Key Laboratory of Structural Chemistry, Fuzhou 350002, China |
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Abstract Two kinds of substituted phthalocyaninatozinc, tetra-β-phthalimidobutoxy phthalocyaninatozinc (1) and tetra-β-phthalimidomethyl phthalocyaninatozinc (2), were synthesized by mix melting method, which bear the same phthalimide substituents but the linking of the substituents to the phthalocyanine ring is different. The substituent linking to the phthalocyanine ring is one methylene in ZnPc (2), while the substituents linking to the phthalocyanine ring is four methylenes and one ather in ZnPc (1), in which ather is near by phthalocyanine ring. The absorption and fluorescence spectra and the abilities of singlet oxygen generation of these two phthalocyanines were compared with respect to the effect of different linked fashions. The magnitude of the redshift of absorption and fluorescence spectra relative to unsubstituded ZnPc is greater for tetra-β-phthalimidobutoxy phthalocyaninatozinc (1) than for tetra-β-phthalimidomethyl phthalocyaninatozinc (2). This result is related to the presence of stronger electron donating peripheral substituents of ZnPc (1), with ФF of (1) is larger than that of (2) and the abilities of singlet oxygen generation of (1) is smaller than that of (2).
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Received: 2005-12-08
Accepted: 2006-03-18
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Corresponding Authors:
WANG Jun-dong
E-mail: wangjd@fzu.edu.cn
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| Cite this article: |
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ZHU Xiao-li,XU Xiu-zhi,YANG Liang, et al. Synthesis and Photophysical Properties of Two Kinds of Substituted Phthalocyaninatozinc [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(05): 953-956.
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| URL: |
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http://www.gpxygpfx.com/EN/Y2007/V27/I05/953 |
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