|
|
|
|
|
|
| Retrieval of Polydisperse Au-Ag Alloy Nanospheres by Spectral Extinction Method |
| ZHENG Yu-xia1, 2, TUERSUN Paerhatijiang1, 2*, ABULAITI Remilai1, 2, CHENG Long1, 2, MA Deng-pan1, 2 |
1. School of Physics and Electronic Engineering, Xinjiang Normal University, Urumqi 830054, China
2. Key Laboratory for Luminescence Minerals and Optical Functional Materials of Xinjiang, Urumqi 830054, China
|
|
|
|
|
Abstract Noble metal nanoparticles have attracted much attention because of their local surface plasmon resonance properties, among which Au-Ag alloy nanoparticles have widespread investigated for their good structural stability, photothermal properties, and potential anticancer efficacy. The properties in many applications are closely related to particle size and concentration. However, the currently used electron microscopy observation method, and dynamic light scattering method cannot obtain both particle size and concentration information, so it is very important to take effective means to measure particle size and concentration. Based on the spectral extinction method, the inversion problem is solved using a non-negative Tikhonov regularization method and the extinction matrix is calculated using the Mie theory. For the noise problem, two cases are adopted to study the inversion of the particle size distribution and concentration of polydisperse Au-Ag alloy nanospheres. In the case of without noise, the inversion error of particle systems Ⅰ is smaller than that of particle systems Ⅱ, and the inversion error is the smallest in the wavelength range of 300～500 nm, where the inversion errors of the mean particle size, the standard deviation of particle size, and the particle number concentration are 0%, -0.03%, and 0%, respectively. In the case of adding random noise, 0.5% and 1.0% random noises were added to the extinction spectrum of particle systems Ⅰ. The inversion error was the smallest in the wavelength range of 200～600 nm. When 0.5% random noise was added, the ranges of particle size distribution, the standard deviation of particle size, and particle number concentration were 79.76～80.15 nm, 5.60～6.61 nm, and 0.995 8×1010～1.005 9×1010 particle·cm-3, respectively; when 1.0% random noise was added, the ranges of particle size distribution, the standard deviation of particle size, and particle number concentration were 78.87～80.27 nm, 5.36～9.00 nm, and 0.992 4×1010～1.027 7×1010 particle·cm-3, respectively. It was found that with the increase of random noise, the variation range of the inversion result also increased significantly (i. e., the relative error of the inversion increases). The mean particle size, the standard deviation of particle size, and the particle number concentration were averaged after 100 random noise sequences were added. When the random noise increases from 0.5% to 1.0%, the relative errors of the inversion results increase, but the relative errors of the particle size distribution, the standard deviation of particle size, and the particle number concentration are less than 6%. It indicates that the inversion results obtained by the algorithm have good stability. This investigation shows that the spectral extinction method provides a simple and rapid characterization means for the inversion of particle size distribution and concentration of polydisperse Au-Ag alloy nanospheres, and also has enlightenment for the investigation of non-spherical nanoparticles.
|
|
Received: 2021-09-15
Accepted: 2021-12-14
|
|
|
|
Corresponding Authors:
TUERSUN Paerhatijiang
E-mail: ptuersun@163.com
|
|
[1] Slepicka P, Kasálková N S, Siegel J, et al. Materials, 2020, 13(1): 1.
[2] Mulvaney P. Langmuir, 1996, 12(3): 788.
[3] Marin I M, Asensio J M, Chaudret B. ACS Nano, 2021, 15(3): 3550.
[4] Biasotto G, Costa J P C, Costa P I, et al. Applied Physics A, 2019, 125(12): 821.
[5] DOU Xin-yi, ZHANG Can, ZHANG Jie(窦心怡, 张 灿, 张 洁). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2021, 41(5): 6.
[6] Jin K T, Yao J Y, Ying X J, et al. Current Topics in Medicinal Chemistry, 2020, 30(2): 2737.
[7] Lin Z, Luo Y, Liu P F, et al. Colloids and Surfaces B: Biointerfaces, 2021, 204: 111831.
[8] Liu B, Januar M, Cheng J C, et al. Nanoscale, 2021, 13(28): 12164.
[9] Xu C J, Tung G A, Sun S H. Chemistry of Materials, 2008, 20(13): 4167.
[10] Chander N, Khan A F, Thouti E, et al. Solar Energy, 2014, 109: 11.
[11] Hinterwirth H, Wiedmer S K, Moilanen M, et al. Journal of Separation Science, 2013, 36(17): 2952.
[12] Lindquist N C, Nagpal P, McPeak K M, et al. Reports on Progress in Physics, 2012, 75(3): 036501.
[13] Su K H, Wei Q H, Zhang X, et al. Nano Letters, 2003, 3(8): 1087.
[14] Tuersun P, Zhu C J, Han X E, et al. Optik, 2020, 204: 163676.
[15] Daimon M, Masumura A. Applied Optics, 2007, 46(18): 3811.
[16] Mie G. Annals of Physics, 1908, 25: 377.
[17] Mroczka J, Szczuczyński D. Applied Optics, 2012, 51(11): 1715.
[18] Rioux D, Vallières S, Besner S, et al. Advanced Optical Materials, 2014, 2(2): 176.
|
| [1] |
ZHU Gui-jun, WANG Gan-zhen, PENG Jun*, TIAN Zong-ping, HOU Zhi-hua. The Mineralogical and Spectroscopic Characteristics of Phosphohedyphane From Chenzhou of Hunan Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3017-3023. |
| [2] |
WANG Xu-yang1, SUN Tao1, ZHU Xin-ping1, TANG Guang-mu2, JIA Hong-tao1*, XU Wan-li2. Phosphorus Species of Biochar Modified by Phosphoric Acid and
Pyrophosphoric Acid Based on Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3084-3090. |
| [3] |
WU Bing, YANG Ke-ming*, GAO Wei, LI Yan-ru, HAN Qian-qian, ZHANG Jian-hong. EC-PB Rules for Spectral Discrimination of Copper and Lead Pollution Elements in Corn Leaves[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3256-3262. |
| [4] |
HU Yu-xia1, CHEN Jie1, SHAO Hui1, YAN Pu1, XU Heng1, SUN Long1, XIAO Xiao1, XIU Lei3, FENG Chun2GAN Ting-ting2, ZHAO Nan-jing2*. Research Progress of Spectroscopy Detection Technologies for Waterborne Pathogens[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2672-2678. |
| [5] |
CHEN Miao, HOU Ming-yu, CUI Shun-li, LI Zhen, MU Guo-jun, LIU Ying-ru, LI Xiu-kun, LIU Li-feng*. Construction of Near-Infrared Model of Peanut Sugar Content in
Different Seed Coat Colors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2896-2902. |
| [6] |
ZHANG Zhen-qing1, 2, 3, DONG Li-juan2*, HUANG Yu4, CHEN Xing-hai4, HUANG Wei5, SUN Yong6. Identification of True and Counterfeit Banknotes Based on Hyperspectral Imaging[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2903-2912. |
| [7] |
YAN Shu-fa, ZHU Yuan-chen, TAO Lei, ZHANG Yong-gang, HU Kai, REN Fu-chen. Spectral Oil Condition Monitoring Data Selection Method for Mechanical Transmission Based on Information Entropy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2637-2641. |
| [8] |
ZHANG Meng-jun1, LIU Li-li1*, YANG Xie-li2, GUO Jing-fang1, WANG Hao-yang1. Multispectral Analysis of Interaction Between Catechins and Egg Yolk Immunoglobulin and the Change of Bacteriostasis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2297-2303. |
| [9] |
YU Zhi-rong, HONG Ming-jian*. Near-Infrared Spectral Quantitative Analysis Network Based on Grouped Fully Connection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1735-1740. |
| [10] |
WANG Yi-ya1, WANG Yi-min1*, GAO Xin-hua2. The Evaluation of Literature and Its Metrological Statistics of X-Ray Fluorescence Spectrometry Analysis in China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1329-1338. |
| [11] |
TAN Yang1, WU Xiao-hong2, 3*, WU Bin4, SHEN Yan-jun1, LIU Jin-mao1. Qualitative Analysis of Pesticide Residues on Chinese Cabbage Based on GK Improved Possibilistic C-Means Clustering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1465-1470. |
| [12] |
TANG Guang-tong1, YAN Hui-bo1, WANG Chao-yang1, LIU Zhi-qiang1, LI Xin1, YAN Xiao-pei1, ZHANG Zhong-nong2, LOU Chun2*. Experimental Investigation on Hydrocarbon Diffusion Flames: Effects of Combustion Atmospheres on Flame Spectrum and Temperature[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1654-1660. |
| [13] |
ZHANG Dian-kai1, LI Yan-hong1*, ZI Chang-yu1, ZHANG Yuan-qin1, YANG Rong1, TIAN Guo-cai2, ZHAO Wen-bo1. Molecular Structure and Molecular Simulation of Eshan Lignite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1293-1298. |
| [14] |
SONG Hong-yan, ZHAO Hang, YAN Xia, SHI Xiao-feng, MA Jun*. Adsorption Characteristics of Marine Contaminant Polychlorinated Biphenyls Based on Surface-Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 704-712. |
| [15] |
ZHOU Jun1, 2, YANG Yang2, YAO Yao2, LI Zi-wen3, WANG Jian3, HOU Chang-jun1*. Application of Mid-Infrared Spectroscopy in the Analysis of Key Indexes of Strong Flavour Chinese Spirits Base Liquor[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 764-768. |
|
|
|
|
