|
|
|
|
|
|
| Fluorescence Spectrum Characteristics of Fulvic Acid in Black Soil Under Different Ratios of Organic-Inorganic Fertilizers Combined Application |
| LI Yan1, BAI Yang1, WEI Dan1,2*, WANG Wei3, LI Yu-mei3, XUE Hong4, HU Yu1, CAI Shan-shan5 |
1. College of Resources and Environment, Northeast Agricultural University, Harbin 150030, China
2. Institute of Plant Nutrition, Resources and Environment, Beijing Academy of Agriculture and Forestry Sciences, Beijing 100097, China
3. Institute of Soil, Fertilizer and Environmental Resources, Heilongjiang Academy of Agricultural Sciences, Harbin 150086, China
4. Keshan Branch of Heilongjiang Academy of Agricultural Sciences, Qiqihar 161000, China
5. College of Land and Environment, Shenyang Agricultural University, Shenyang 110866, China |
|
|
|
|
Abstract Fulvic acid (FA) is an important component of soil humus. As an intermediate substance in soil humification, the structural characteristics of FA play an important role in indicating the improvement of soil organic matter. The combined organic and inorganic fertilizers are an effective measure for soil fertility improvement, straw resource utilization and inorganic fertilizer reduction. In order to explore the effect of straw organic fertilizer instead of inorganic fertilizer (nitrogenous fertilizer) on soil FA in the black soil region of Heilongjiang Province, six treatments were set up, including no fertilization (CK), a single application of inorganic fertilizer (NPK), 25% of organic nitrogen fertilizer (NPKM1), 50% (NPKM2), 75% (NPKM3), and 100% (NPKM4). The contents of soil organic carbon (SOC) and FA were determined. The source of soil FA was characterized by fluorescence index (FI) and biological index (BIX), and the degree of soil humification was analyzed by humification index (HIX). Three-dimensional fluorescence spectrum parallel factor analysis method was used to analyze the fluorescence components and maximum fluorescence intensity (Fmax) of soil FA, and redundancy analysis (RDA) was used to explore the response relationships among fluorescence intensity, soil organic carbon and different treatments. The results showed that compared with NPK treatment, the contents of SOC and soil FA increased significantly in the treatments of combined application of organic and inorganic fertilizers, the greatest impact on NPKM2 treatment, SOC and soil FA content increased by 8.06% and 13.84%. Soil FA was affected by both autochthonous and terrestrial sources (FI>1.4, 0.8Fmax values of fulvic-acid-like and humic-acid-like first increased and then decreased, and the Fmax value of protein-like gradually decreased. The Fmax values of fulvic-acid-like and humic-acid-like were the highest, and the relative percentage of humic-acid-like was the highest. The results of RDA showed that NPKM2 treatment had the greatest effect on the content of SOC and soil FA. Therefore, based on the analysis of soil FA fluorescence spectrum characteristics, in order to improve the content of soil organic matter, increase straw utilization rate and reduce the application of inorganic fertilizer, the treatment of straw organic fertilizer replacing inorganic nitrogen fertilizer by 50% was the best organic-inorganic fertilizer ratio.
|
|
Received: 2020-12-07
Accepted: 2021-04-06
|
|
|
|
Corresponding Authors:
WEI Dan
E-mail: wd2087@163.com
|
|
[1] Yang Q L, Zheng F X, Jia X C, et al. Journal of Soils and Sediments, 2020，20（5）：2395.
[2] ZHANG Wei-li, Kolbe H, ZHANG Ren-lian(张维理, Kolbe H, 张认连). Scientia Agricultural Sinica (中国农业科学), 2020, 53(2): 317.
[3] Lehmann J, Kleber M. Nature, 2015, 528(7580): 60.
[4] Zhang P, Huang P, Xu X J, et al. Science of the Total Environment, 2020, 708：134619.
[5] ZHANG Jiu-ming, LIU Yi-dan, ZHANG Yi-wen, et al(张久明, 刘亦丹, 张一雯, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2020, 40(7): 2194.
[6] GU Si-yu, HE Xin, NIE Yan-long, et al(谷思玉, 何 鑫, 聂艳龙, 等). Research of Environmental Sciences(环境科学研究), 2016, 29(5): 724.
[7] Rubén L S, Guillermo G C, Rigoberto E V, et al. Revista Mexicana de Ciencias Agrícolas, 2014, 5: 1397.
[8] MA Lian-gang, XIAO Bao-hua(马连刚, 肖保华). Bulletin of Mineralogy, Petrology and Geochemistry (矿物岩石地球化学通报), 2011, 30(4): 465.
[9] Li S Y, Li M, Wang G X, et al. Chemical and Biological Technologies in Agriculture, 2019, 6(1): 20.
[10] Gao X T, Tan W B, Zhao Y, et al. Environmental Science and Technology. 2019, 53: 3653.
[11] Gu N T, Song Q B, Yang X L, et al. Environmental Pollution，2020, 258: 113807.
[12] Li W T, Chen S Y, Xu Z X, et al. Environmental Science and Technology, 2014, 48(5): 2603.
[13] He W, Hur J. Water Research, 2015, 83: 217.
[14] ZHANG Bo, WANG Shu-hang, JIANG Xia, et al(张 博, 王书航, 姜 霞, 等). Journal of Lake Sciences(湖泊科学), 2018, 30(1): 102.
[15] QIAN Cheng, GUI Xiao-fan, PENG Yu-mei, et al(钱 承, 桂晓凡, 彭玉梅, 等). Auhui Agricultural Science Bulletin(安徽农学通报), 2020, 26(17): 123.
[16] Song F H, Wu F C, Feng W Y, et al. Journal of Environmental Sciences, 2018, 74(12): 116.
[17] DOU Sen(窦 森). Soil Organic Matter(土壤有机质). 1st ed. Beijing: Science Press(北京: 科学出版社), 2010.
[18] Wei Z M, Wang X Q, Zhao X Y, et al. International Biodeterioration and Biodegradation, 2016, 113: 187. |
| [1] |
ZHANG Yu-yang, CHEN Mei-hua*, YE Shuang, ZHENG Jin-yu. Research of Geographical Origin of Sapphire Based on Three-Dimensional Fluorescence Spectroscopy: A Case Study in Sri Lanka and Laos Sapphires[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1508-1513. |
| [2] |
YANG Xin1, 2, WU Zhi-hang3, YE Yin1, 2*, CHEN Xiao-fang1, 2, YUAN Zi-ran1, 2, WANG Jing1, 2. Parallel Factor Analysis of Fluorescence Excitation Emission Matrix Spectroscopy of DOM in Waters of Agricultural Watershed of Dianbu River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 978-983. |
| [3] |
SHI Chuan-qi1, 2, LI Yan3, 4, YU Shao-peng1*, HU Bao-zhong1, 2, WANG Hui1, JIN Liang4. Study on the Effect of Foundation Pit Drainage on Water Dissolved Organic Matter in Urban River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 498-504. |
| [4] |
WU Yan-han, CHEN Quan-li*, ZHAO An-di, LI Xuan, BAO Pei-jin. Study on the Gemmological Characteristics of Filled Morganite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 575-581. |
| [5] |
LIU Tian-shun1, 2, LI Peng-fa1, 2, LI Gui-long1, 2, WU Meng1, LIU Ming1, LIU Kai1, 2, LI Zhong-pei1, 2*. Using Three-Dimensional Excitation-Emission Matrix to Study the Compositions of Dissolved Organic Matter in the Rhizosphere Soil of Continuous Cropping Peanuts With Different Health States[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 634-641. |
| [6] |
LOU Meng-han1, 2, JIN Hong-mei2, 3, 4*, LIANG Dong2, 3, ZHU Yan-yun2, 3, ZHU Ning2, 3, 4, LI Dan-yang2, 3. Fluorescence Spectra Characteristics of Dissolved Organic Matter in Mesophilic Anaerobic Digestion of Pig and Dairy Manure Slurries[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 141-146. |
| [7] |
CHENG Cheng1,2,3, QIAN Yu-ting4, HUANG Zhen-rong4, JIANG Jing4, SHAO Li4, WANG Zhong-xi4, LÜ Wei-ming4, WU Jing1,2,3*. Fluorescence Excitation Emission Matrix Properties of the Effluents From the Wastewater Treatment Plants in Jiangyin City, Jiangsu Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3791-3796. |
| [8] |
TAN Yang, JIANG Qi-gang*, LIU Hua-xin, LIU Bin, GAO Xin, ZHANG Bo. Estimation of Organic Matter, Moisture, Total Iron and pH From Back Soil Based on Multi Scales SNV-CWT Transformation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3424-3430. |
| [9] |
KONG De-ming1, CHEN Hong-jie1, CHEN Xiao-yu2*, DONG Rui1, WANG Shu-tao1. Research on Oil Identification Method Based on Three-Dimensional Fluorescence Spectroscopy Combined With Sparse Principal Component Analysis and Support Vector Machine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3474-3479. |
| [10] |
WANG Si-yuan1, ZHANG Bao-jun1, WANG Hao1, GOU Si-yu2, LI Yu1, LI Xin-yu1, TAN Ai-ling1, JIANG Tian-jiu2, BI Wei-hong1*. Concentration Monitoring of Paralytic Shellfish Poison Producing Algae Based on Three Dimensional Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3480-3485. |
| [11] |
CHEN Xiao-yu1, ZHANG kun1, KONG De-ming2*. Three-Dimensional Fluorescence Partial Derivative Spectroscopy Combined With Parallel Factor Algorithm for Detection of Mixed Oil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3506-3511. |
| [12] |
SHEN Yi-jun1, YANG Zi-chen2，3, WANG Ting-yu2，3, WANG Cheng-wei2，3, LI Lei2,3, CHEN Guo-qing2，3*. Study on Fluorescence and Raman Spectral Characteristics of Lipstick[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2665-2669. |
| [13] |
LI Yan1,2, WEI Dan1, 2*, WANG Wei3, JIN Liang2, DING Jian-li2, CAI Shan-shan4, HU Yu1, BAI Yang1. Fluorescence Spectroscopy Characteristics of Dissolved Organic Matter Analysis of Straw-Cow Dung Fermentation in Different Proportion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2846-2852. |
| [14] |
DAI Yuan1, XIE Ji-zheng1, YUAN Jing1, SHEN Wei1, GUO Hong-da1, SUN Xiao-ping1, WANG Zhi-gang2*. Application of Excitation-Emission Matrix (EEM) Fluorescence Combined With Linear SVM in Organic Pollution Monitoring of Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2839-2845. |
| [15] |
XIAO You-gan1, CHEN Hong-jing1, WEI Zhong-qing1, CHEN Shou-bin1, SHANGGUAN Hai-dong1, LIN Hui2, LI Zhong-sheng2, LIN Ze-ying3, FAN Gong-duan2*. Three-Dimensional Fluorescence Characteristics Analysis of DOM in the Process of Treatment of Brackish Water by Ultrafiltration-Nanofiltration Double Membrane Process[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2518-2523. |
|
|
|
|
