光谱学与光谱分析 |
|
|
|
|
|
Determination of Nine Mineral Elements in Hulless Barley by Ultraviolet Spectrophotometry and Flame Atomic Absorption Spectrometry |
LIU Jin1, 2,ZHANG Huai-gang1* |
1. Northwest Institute of Plateau Biology,Chinese Academy of Sciences,Xining 810001,China 2. Graduate University of Chinese Academy of Sciences,Beijing 100049,China |
|
|
Abstract The contents of nine mineral elements, including sulphur, zinc, calcium, magnesium, potassium, sodium, iron, copper and manganese in five hulless barley (Hordeum vulgare L. var. nudum Hook. f.) lines were determined by ultraviolet spectrophotometry and flames atomic absorption spectrometry (FAAS). For the determination of sulphur, the samples were dissolved by magnesia and anhydrous sodium carbonate at 250 ℃ for 0.5 h and at 550 ℃ for 3 h in the muffle furnace, and then a certain amount of barium chloride was put into the sample solution for colorimetry of the UV-Vs spectrophotometer. For the determination of other eight mineral elements, all of the samples were dissolved by a kind of incinerating method: first, the sample was put into the muffle furnace at 250 ℃ for 0.5 h and at 550 ℃ for 2.5 h, then two droplets of 50%HNO3 were distributed into each sample, and the last step was putting the sample into the muffle furnace at 550 ℃ for 0.5 h. And then all of the ash was dissolved by 50%HNO3 to 50 milliliter and determined by flames atomic absorption spectrometry. The precision, accuracy, repeatability and stability of the method were discussed too. The results showed that the relative standard deviations (RSD) were between 1.2% and 3.7%; The average recoveries were 97.44%-101.52% and the relative standard deviations (RSD) of sample determination were 1.3%-3.8%. The repeatability experiment showed that the relative standard deviations (RSD) were 2.6%-6.1%. And the content of each mineral element was the same after 24 hours; All these showed that the method has a good precision, accuracy, repeatability and stability. In all the hulless barley samples, the average contents were in the order of K>S>Mg>Ca>Fe>Na>Zn>Mn>Cu,and the contents of zinc, iron and manganese closely related to people’s health were relatively higher than other crops. The data of the experiment could provide an accurate and credible evidence for the deeper exploitation of the hulless barley.
|
Received: 2009-05-06
Accepted: 2009-08-09
|
|
Corresponding Authors:
ZHANG Huai-gang
E-mail: hgzhang@nwipb.ac.cn
|
|
[1] XIE Zong-wan(谢宗万). Colorplate of Compendium of Materia Medica(本草纲目药物彩色图鉴). Beijing:People’s Medical Publishing House(北京:人民卫生出版社),2001. 221. [2] XIAO Gu-qing(肖谷清). Chinese Journal of Spectroscopy Laboratory(光谱实验室),2006,23(3):493. [3] ZHANG Yuan,ZHANG Lu-da,BAI Qi-lin,et al(张 愿,张录达,白琪林, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2009,29(3):686. [4] WANG De-kai,PEI Ke-mei,LIU He-qin(王得凯,裴克梅,刘合芹). Chinese Journal of Spectroscopy Laboratory(光谱实验室),2008,25(1):1. [5] LIN Jian-yuan,HUANG Wei(林建原,黄 炜). Guangdong Trace Elements Science(广东微量元素科学),2008,15(4):52. [6] Nardi E P,Evangelista F S,Tormen L,et al. Food Chemistry,2009,112(3):727. [7] Ferreiraa H S,Santosa A C N,Portugal L A,et al. Talanta,2008,77 (1):73. [8] Araujo R G O,Dias F S,Macedo S M,et al. Food Chemistry,2007,101(1):397. [9] Biljana S,Antonije O. Food Control,2007,18(4):338. [10] LI Zeng-ning,MA Li,HE Yan,et al(李增宁,马 莉,何 燕,等). Chinese Journal of Health Laboratory Technology(中国卫生检验杂志),2007,17(4):660. [11] Cubadda F, Raggi A, Marconi E,et al. Microchemical Journal,2005,79(1-2):97. [12] Frost H L,Ketchum Jr L H. Advances in Environmental Research,2000,4(4):347. [13] Saracoglu S,Saygi K O,Uluozlu O D,et al. Food Chemistry,2007,105(1):280. [14] Coudray C,Levrat-Verny M A,Tressol J C,et al. Journal of Trace Elements in Medicine and Biology,2001,15(2-3):131. [15] Tuna A L,Kaya C,Higgs D,et al. Environmental and Experimental Botany,2008,62(1):10. [16] ZHANG Ying-hua,ZHOU Shun-li,ZHANG Kai,et al(张英华,周顺利,张 凯,等). Acta Agronomica Sinica(作物学报),2008,34(9):1629.
|
[1] |
JI Rong-hua1, 2, ZHAO Ying-ying2, LI Min-zan2, ZHENG Li-hua2*. Research on Prediction Model of Soil Nitrogen Content Based on
Encoder-CNN[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1372-1377. |
[2] |
FU Yan-hua1, LIU Jing2*, MAO Ya-chun2, CAO Wang2, HUANG Jia-qi2, ZHAO Zhan-guo3. Experimental Study on Quantitative Inversion Model of Heavy Metals in Soda Saline-Alkali Soil Based on RBF Neural Network[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1595-1600. |
[3] |
YANG Xu, LU Xue-he, SHI Jing-ming, LI Jing, JU Wei-min*. Inversion of Rice Leaf Chlorophyll Content Based on Sentinel-2 Satellite Data[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 866-872. |
[4] |
TANG Yu-zhe, HONG Mei, HAO Jia-yong, WANG Xu, ZHANG He-jing, ZHANG Wei-jian, LI Fei*. Estimation of Chlorophyll Content in Maize Leaves Based on Optimized Area Spectral Index[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 924-932. |
[5] |
WANG Yi-heng1, SUN Kun1, WEN Zhe1, SUO Ying-bo2, ZHANG Qu1, WANG Ge-rong1, WEI Jin-hua1*. Prediction of Conifer Pigment Content Based on Color Parameters and Hyperspectral Characteristics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 537-543. |
[6] |
QIAO Lu, WANG Song-lei*, GUO Jian-hong, HE Xiao-guang. Combination of Spectral and Textural Informations of Hyperspectral Imaging for Predictions of Soluble Protein and GSH Contents in Mutton[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 176-183. |
[7] |
ZHU Hai-jun1, FU Hong-yu1, 2, WANG Xue-hua1*, CUI Guo-xian1, 2*,SHI Ai-long1, XUE Wei-chun3. Preliminary Study on the Intertemporal Predictability of the Physiological Index of Early Rice Based on Hyperspectral[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 170-175. |
[8] |
JIANG Jing1, 2, ZHAO Zi-wei1, 2, CAI Chang1, 2, ZHANG Jin-song3, CHENG Zhi-qing1, 2*. Hyperspectral Estimation of Tea Leaves Water Content Under the Influence of Dust Retention[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3532-3537. |
[9] |
LI Xue, LIN Jing-song, GUO Yi-tong, HUO Wei-gang*, WANG Yu-xin, XIA Yang. Studies on the Electrical and Spectrum Characteristics in Atmospheric Dielectric Barrier Discharge in Helium-Argon Mixture[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3602-3606. |
[10] |
LI Li-jie1,2, YUE Yan-bin2, WANG Yan-cang3, ZHAO Ze-ying2, LI Rui-jun2, NIE Ke-yan2, YUAN Ling1*. The Quantitative Study on Chlorophyll Content of Hylocereus polyrhizus Based on Hyperspectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3538-3544. |
[11] |
YANG Bao-hua, GAO Zhi-wei, QI Lin, ZHU Yue, GAO Yuan. Prediction Model of Soluble Solid Content in Peaches Based on Hyperspectral Images[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3559-3564. |
[12] |
SUN Di1, 2, LI Meng-ting1, MU Mei-rui1, ZHAO Run1*, ZHANG Ke-qiang1*. Rapid Determination of Nitrogen and Phosphorus in Dairy Farm Slurry Via Near-Mid Infrared Fusion Spectroscopy Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3092-3098. |
[13] |
ZHANG Zi-han1, YAN Lei1,2, LIU Si-yuan1, FU Yu1, JIANG Kai-wen1, YANG Bin3, LIU Sui-hua4, ZHANG Fei-zhou1*. Leaf Nitrogen Concentration Retrieval Based on Polarization Reflectance Model and Random Forest Regression[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2911-2917. |
[14] |
LIU Tan1, 2, XU Tong-yu1, 2*, YU Feng-hua1, 2, YUAN Qing-yun1, 2, GUO Zhong-hui1, XU Bo1. Chlorophyll Content Estimation of Northeast Japonica Rice Based on Improved Feature Band Selection and Hybrid Integrated Modeling[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2556-2564. |
[15] |
ZOU Jin-ping1, ZHANG Shuai2, DONG Wen-tao2, ZHANG Hai-liang2*. Application of Hyperspectral Image to Detect the Content of Total Nitrogen in Fish Meat Volatile Base[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2586-2590. |
|
|
|
|