光谱学与光谱分析 |
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Fe(Ⅲ) Modified Sodium Alginate Beads Based Micro-Extraction in Combination with Hydride Generation-Atomic Fluorescence Spectrometry (HG-AFS) for Speciation Analysis of Inorganic As(Ⅲ) and As(Ⅴ) in Water Samples |
PENG Xiao-li1, XU Fang1*, BIAN Jing1, ZHANG Wen-zhong1, WU Yi2 |
1. School of Environmental Science and Engineering, Shanghai Jiaotong University, Shanghai 200240, China 2. Shanghai Food Research Institute, Shanghai 200235, China |
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Abstract Fe(Ⅲ) modified sodium alginate beads (Fe(Ⅲ) modified Na) were firstly adopted as solid phase for micro-extraction of inorganic arsenic species from water samples. In combination with hydride generation-atomic fluorescent spectrometry (HG-AFS), speciation analysis of inorganic As(Ⅲ) and As(Ⅴ) in water samples could be accomplished because Fe(Ⅲ) modified Na had various micro-extraction behavior for inorganic As(Ⅲ) and As(Ⅴ) respectively. As a result, Fe(Ⅲ) modified Na could be developed into a practical solid phase for speciation analysis of inorganic As(Ⅲ) and As(Ⅴ), with the advantages of being efficient, simple, and environmental-friendly.
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Received: 2012-09-02
Accepted: 2012-12-11
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Corresponding Authors:
XU Fang
E-mail: xufangzh@sjtu.edu.cn
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