The Application of Trace Element Analysis to the Study of Provenance of Copper Minerals in Ancient Bronzes
LI Qing-lin1,2,ZHU Jun-xiao3,QIN Ying4,MAO Zhen-wei4, WANG Chang-sui4*,CHEN Jian-li5
1. Center of Scientific and Technological Archaeology, Wuhan University, Wuchang 430072, China 2. History School of Wuhan University, Wuchang 430072, China 3. History College of Zhengzhou University, Zhengzhou 450052, China 4. United Key Laboratory on Archaeometry, USTC, Hefei 230036, China 5. Department of Archaeometry and Conservation, Peking University, Beijing 100871, China
Abstract:The simulated smelting and founding experiment of bronze showed that the copper minerals from different regions could be distinguished clearly by using the multi-statistical analysis based on choosing the chalcophile elements determined by ICP-AES. In the present paper, the data of trace elements in bronzes from Panlongcheng Site and Ezhou, which were determined by NAA, were tried to be processed. The analytical result showed that the bronzes from Panlongcheng and Ezhou could be divided clearly, just like the results of the former simulated smelting and founding experiment of bronze. So, the feasibility of trace element analysis for the study of provenance of copper minerals in ancient bronzes was proved again.
Key words:ICP-AES;Bronze;Provenance of copper minerals;Chalcophile elements;Multi-statistical analysis
李清临1,2,朱君孝3,秦 颍4,毛振伟4,王昌燧4*,陈建立5 . 微量元素示踪法在古代青铜器铜矿料来源研究中的应用[J]. 光谱学与光谱分析, 2005, 25(10): 1700-1702.
LI Qing-lin1,2,ZHU Jun-xiao3,QIN Ying4,MAO Zhen-wei4, WANG Chang-sui4*,CHEN Jian-li5 . The Application of Trace Element Analysis to the Study of Provenance of Copper Minerals in Ancient Bronzes . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(10): 1700-1702.
[1] Rapp George Jr,Eiler Henrickson,Michael Miller,et al. Journal of Metals,1980,32:35. [2] Gale N H, Stos-Gale Z A. Science,1982,216(15-17):11. [3] Barnes I L,Chase W T, Joel E C. Shang Ritual Bronzes in the A. M. Sackler Collection. Boston: Harvard University Press. 1987. 558. [4] Stos-Gale Z A,Malitois G,Gale N H,et al. Archaeometry,1997,39(1):83. [5] Niederschlag E,Pernicka E,Th Seifert,et al. Archaeometry,2003,45(1):61. [6] PENG Zi-cheng,WAN Fu-bin,YAO Shun-an (彭子成,万辅彬,姚舜安). Chinese Science Bulletin(科学通报),1988,33(5):360. [7] LU Ji-yi,PENG Zi-cheng,WAN Fu-bin(鲁冀邕,彭子成,万辅彬). Cultural Relics(文物),1990,(1):79. [8] LI Xiao-cen,LI Zhi-chao,ZHANG Bing-lun, et al(李晓岑,李志超,张秉伦, 等). Archaeology(考古),1992,34(5):464. [9] JIN Zheng-yao,Chase W T,Mabuch Hisao,et al(金正耀,马渊久夫,等). Cultural Relics(文物),1993,(8):80. [10] QIN Ying,WANG Chang-sui,ZHANG Guo-mao,et al(秦 颍,王昌燧,张国茂,等). Cultural Relics(文物),2002,(5):78. [11] LI Qing-lin,ZHU Jun-xiao,QIN Ying,et al(李清临,朱君孝,秦 颍,等). Sciences of Conservation and Archaeology(文物保护与考古科学),待发表. [12] Hubei Provincial Institute of Archaeology(湖北省文物考古研究所编). Excavation Report of Panlongcheng Site,1963—1994(盘龙城—1963~1994年发掘报告). Beijing:Cultural Relics Press(北京:文物出版社),2000. 559. [13] LING Xue, MAO Zhen-wei, FENG Min, et al(凌 雪,毛振伟,冯 敏,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005,25(7):1145.