Analysis of 23 Mineral Elements in Tea Samples Collected from China and Japan by Using ICP-AES and ICP-MS Combined with a Closed Decomposition
WANG Xiao-ping1, MA Yi-jin1,Mitso itoh2
1. School of Radioactive Medicine and Public Hygiene, Suzhou University, Suzhou 215007, China 2. Department of Environmental Science, Japan Atomic Energy Research Institute, Ibaraki-ken 319-1195, Japan
Abstract:After a closed decomposition, the concentrations of Al, Ba, Ca, Cd, Ce, Co, Cr, Cs, Cu, Fe, La, Mg, Mn, Na, Ni, Pb, Rb, Sb, Sr, Th, U, Y and Zn in thirteen Chinese tea samples and six Japanese tea samples were analysed by using ICP-AES and ICP-MS, a tea standard reference material (GBW07605) was used to verify the accuracy and the precision of analytical method. It was demonstrated that a closed decomposition can help to get good results for the concentrations of mineral elements in tea samples. Compared with those in Japanese tea samples, the concentrations of Cd, Co, Cr, Cs, Fe, Pb, Rb, Sb, Th, U and Zn in Chinese tea samples are significantly high, which means the atmosphere in China is contaminated by heavy metal particles more severely than that in Japan. Moreover, it was found that the concentrations of many mineral elements in tea samples correlate each other.
王小平1,马以瑾1,伊藤光雄2 . 密封消解ICP-AES和ICP-MS测定中日两国茶叶中23种矿质元素[J]. 光谱学与光谱分析, 2005, 25(10): 1703-1707.
WANG Xiao-ping1, MA Yi-jin1,Mitso itoh2. Analysis of 23 Mineral Elements in Tea Samples Collected from China and Japan by Using ICP-AES and ICP-MS Combined with a Closed Decomposition. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(10): 1703-1707.
[1] ZHOU Lian-jun, LI Huai-na, YOU Jin-mao, et al(周连君, 李怀娜, 尤进茂, 等). Chinese Journal of Analysis Laboratory(分析试验室), 1995, 14(2): 9. [2] HUANG Yuan-ze, WANG Guang-can(黄渊泽, 王光灿). Studies of Trace Elements and Health(微量元素与健康研究), 1997, 14(2): 36. [3] WANG Shu-jun(王淑俊). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1998, 18(2): 227. [4] Mierzwa J, Sun Y C, Chung Y T, et al. Talanta, 1998, 47: 1263. [5] MA Ge, ZHANG Jing-yan, CHEN Wen-ming, HAN Jin-xiu(马 戈, 张景彦, 陈文明, 韩锦秀). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1999, 19(3): 408. [6] WAN Yi-qun, LIU Jiang-lin, CHEN Wei-ling(万益群, 刘江磷, 陈卫玲). Journal of Analytical Science(分析科学学报), 2000, 16(5): 394. [7] Jonah S A, Williams I S. The Science of the Total Environment, 2000, 258: 205. [8] Herrador M àngeles, Gonzàlez A Gustavo. Talanta, 2001, 53: 1249. [9] HAN Li-xin, LI Ran(韩立新,李 冉). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2002, 22(2): 304. [10] WANG Xiao-ping(王小平). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005,25(4):563. [11] WANG Ke-lei, MA Jin-qiu, WU Yue-ying(王克镭, 马锦秋, 吴跃英). Ion Exchange and Adsorption(离子交换与吸附), 1996, 12(5): 385. [12] YANG Tong-zai, MA Jun, LIU Yi-nong, et al(杨通在, 马 浚, 刘亦农, 等). Chinese Journal of Analytical Chemistry(分析化学), 2002, 30(12): 1440. [13] Rahn Kenneth A, Huang Suilou. The Science of the Total Environment, 1999, 232: 79. [14] SHAO Jing, ZHANG Zhao-hui, CHAI Zhi-fang, et al(邵 晶, 张朝晖, 柴之芳, 等). Journal of Nuclear and Radiochemistry(核化学与放射化学), 2002, 24(1): 6. [15] Wang C X, Zhu W, Peng An, et al. Environment International, 2001, 26: 309.