Abstract:The mechanism of laser paint removal is studied based on emission spectrum and composition analysis by using laser induced breakdown spectroscopy and X-ray energy spectrum technology. The electron density and electron temperature of the plasma was calculated with the LIBS spectrums with different laser parameters. The morphologies of ablated paint surface were analyzed with a scanning electron microscopy while the changes of paint composition before and after ablation were measured with an X-ray spectrometer. The results show that, the plasma electron density, temperature and ablation area gradually increase with the increasing of incident laser energy. The carbon (C) content in paint decreases from 78.25% to 67.07% after the laser irradiation, indicating the occurrence of the ablation in the process of laser paint removal. By comparing the content of titanium (Ti) elements, C element and aluminum (Al), we found that the paint ablation will be more severe at higher laser energy. This paper is important to in-depth study of laser paint removal mechanism.
陈康喜,冯国英*,邓国亮,刘彩飞,王德良 . 基于发射光谱及成分分析的激光除漆机理研究 [J]. 光谱学与光谱分析, 2016, 36(09): 2956-2960.
CHEN Kang-xi, FENG Guo-ying*, DENG Guo-liang, LIU Cai-fei, WANG De-liang . Study on the Mechanism of Laser Paint Removal Based on Emission Spectrum and Composition Analysis. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(09): 2956-2960.
[1] Zapka W, Ziemlich W, Tam A. Applied Physics Letters, 1991, 58(20): 2217. [2] Watkins K, Curran C, Lee J-M. Journal of Cultural Heritage, 2003, 4: 59. [3] Peligrad A, Schmidt M, Li L, et al. Optics & Laser Technology, 2000, 32(1): 49. [4] Schmidt M, Li L, Spencer J. Journal of Materials Processing Technology, 2001, 114(2): 139. [5] Roberts D. Applied Physics A, 2004, 79(4-6): 1067. [6] Chen G, Kwee T, Tan K, et al. Applied Physics A, 2010, 101(2): 249. [7] SHI Shu-dong, DU Peng, LI Wei(施曙东, 杜 鹏, 李 伟). Chinese Journal of Lasers(中国激光), 2012, 39(9): 58. [8] Madhukar Y K, Mullick S, Shukla D K, et al. Applied Surface Science, 2013, 264: 892. [9] Tsunemi A, Hagiwara K, Saito N, et al. Applied Physics A, 1996, 63(5): 435. [10] Kolomenskii A A, Schuessler H, Mikhalevich V, et al. Journal of Applied Physics, 1998, 84(5): 2404. [11] Lu Y F, Song W D, Ye K D, et al. Japanese Journal of Applied Physics, 1997, 36(10A): L1304. [12] Curran C, Watkins K, Lee J. 21st International Congress on Applications of Lasers and Electo-Optics, 2002. [13] Zhou X, Imasaki K, Furukawa H, et al. Surface and Coatings Technology, 2001, 137(2): 170. [14] Brygo F, Semerok A, Oltra R, et al. Applied Surface Science, 2006, 252(23): 8314. [15] SONG Feng, ZOU Wan-fang, TIAN Bin(宋 峰, 邹万芳, 田 彬). Chinese Journal of Lasers(中国激光), 2008, 34(11): 1577. [16] LI Xiao-yin, LIN Zhao-xiang, LIU Yu-yan(李小银, 林兆祥, 刘煜炎). Acta Optica Sinica(光学学报), 2004, 24(8): 1051. [17] Cremers D A, Radziemski L J. Handbook of Laser-Induced Breakdown Spectroscopy. John Wiley & Sons Ltd, 2006. 28. [18] Stark-b. http://stark-b.obspm.fr/index.php/data/ion/6. [19] National Institute of Standards and Technology, Atomic Spectral Datsbase. http://physics.nist.gov/cgi-bin/ASD/lines1.pl.