Study on the Identification of Dangguitou and Dangguiwei by Two-dimensional Infrared Correlation Spectroscopy
Lü Guang-hua1,SUN Su-qin2, LEUNG Hi-wun1, CHAN Kelvin K C1
1. Research and Development Division, School of Chinese Medicine, Hong Kong Baptist University, Hong Kong, China 2. Department of Chemistry, Tsinghua University, Beijing 100084, China
Abstract:Fourier transform infrared spectroscopy (FTIR) combined with two-dimensional correlation spectroscopy was used to identify the different parts of Danggui in this paper. Guitou and Guiwei are two parts of the same officinal plant, and similar to each other in normal. FTIR spectra revealed the comparabilities of these two parts in herbal characters, organizing structure and alkaloid components. However, variance in amino acids and naphtha contents, which is aroused by the different parts of the angelica, could be identified easily and clearly in 2D FTIR spectra. Thus the fast and accurate property of 2D FTIR spectroscopy makes it a powerful and new approach to evaluating the medicinal herbs impersonally.
吕光华1,孙素琴2*,梁曦云1,陈金泉1* . 归头和归尾二维相关红外光谱法的鉴别研究 [J]. 光谱学与光谱分析, 2004, 24(03): 311-314.
Lü Guang-hua1,SUN Su-qin2, LEUNG Hi-wun1, CHAN Kelvin K C1 . Study on the Identification of Dangguitou and Dangguiwei by Two-dimensional Infrared Correlation Spectroscopy . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(03): 311-314.
[1] Pharmacopiea Committee of the Ministry of Public Health(国家药典委员会编). The Chinese Pharmacopeia(中华人民共和国药典). Beijing: Chemical Industry Press(北京:化学工业出版社),2000. 89. [2] SUN Su-qin, ZHANG Xuan, QIN Zhu et al(孙素琴,张 宣,秦 竹等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),1999,19(4):542. [3] SUN Su-qin, YU Jian-yuan, HU Xin-yao(孙素琴,郁鉴源,胡鑫尧). Spectroscopy and Spectral Analysis(光谱学与光谱分析),1999,19(6):841. [4] ZHOU Qun, SUN Su-qin, DU De-guo et al(周 群,孙素琴,杜德国等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2000,20(2):195. [5] SUN Su-qin, ZHOU Qun, YU Jian-yuan et al(孙素琴,周 群,郁鉴源等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2000, 20(2): 199. [6] SUN Su-qin, ZHOU Qun, ZHANG Xuan et al(孙素琴,周 群,张 宣等). Chinese Journal of Analytical Chemistry(分析化学),2000,28(2):211. [7] DU De-guo, SUN Su-qin, ZHOU Qun et al(杜德国,孙素琴,周 群等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2000, 20(4): 474. [8] SUN Su-qin, DU De-guo, LEUNG Hi-wun et al(孙素琴,杜德国,梁曦云等). Chinese Journal of Analytical Chemistry(分析化学),2001,29(3):309. [9] SUN Su-qin, LEUNG Hi-wun, YANG Xian-rong(孙素琴,梁曦云,杨 显荣). Chinese Journal of Analytical Chemistry(分析化学),2001,29(5):552. [10] WANG Zhao, SUN Su-qin, LI Xiao-bo et al(王 钊,孙素琴,李晓波等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2001, 21(3): 311. [11] SUN Su-qin, WANG Mi-qu, LEUNG Hi-wun et al(孙素琴,王米渠,梁曦云等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2001, 21(6): 787. [12] SUN Su-qin, LIU Jun, ZHOU Qun(孙素琴,刘 军,周 群). Chinese Journal of Analytical Chemistry(分析化学),2002,30(2):140. [13] Sun S Q, Huang H, Xu Y Q. Anal. Sci., 2001, 17(Suppl.): A451. [14] Sun S Q, Du D G, Zhou Q et al. Anal. Sci., 2001, 17(Suppl.): A445. [15] Zhou Q, Cai S Q, Wang J H et al. Anal Sci., 2001, 17(Suppl.): A443. [16] Zuo L, Sun S Q, Tang J M. Anal. Sci., 2001, 17(Suppl.): A447. [17] Noda I. J. Amer. Chem. Soc., 1989, 111(21): 8116. [18] Noda I. Appl. Spectrosc., 1993, 47: 1329. [19] Noda I. Appl. Spectrosc., 2000, 54: 994. [20] Tian G, Wu Q, Sun S Q et al. Appl. Spectrosc., 2001, 55(7): 888. [21] Wu Q, Tian G, Sun S Q et al. J. Appl. Polym. Sci., 2001, 82(4): 934. [22] XU Yong-qun, SUN Su-qin, ZHOU Qun et al(徐永群,孙素琴,周 群等). Chinese Journal of Light Scattering(光散射学报),2001,13(2):91. [23] ZUO Lin, SUN Su-qin, TANG Jun-ming(左 林,孙素琴,汤俊明). Computers and Applied Chemistry(计算机与应用化学),2002,19(2):95. [24] Tian G, Wu Q, Sun S Q et al. J. Polym. Sci. Pol. Phys., 2002, 40(7): 649.